Citation: Xin Deng, Rongrong Qian, Hongwei Zhou, Lei Yu. Organotellurium-catalyzed oxidative deoximation reactions using visible-light as the precise driving energy[J]. Chinese Chemical Letters, ;2021, 32(3): 1029-1032. doi: 10.1016/j.cclet.2020.09.012 shu

Organotellurium-catalyzed oxidative deoximation reactions using visible-light as the precise driving energy

Xin Deng ^{a, b} ,
Rongrong Qian ^c ,
Hongwei Zhou ^{b, *,} ,
Lei Yu ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
b.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 314001, China
c.
Jiangsu College of Tourism, Yangzhou 225127, China

zhouhw@zju.edu.cn

yulei@yzu.edu.cn

Received Date: 29 July 2020
Revised Date: 28 August 2020
Accepted Date: 8 September 2020
Available Online: 28 September 2020

Figures(1)

Irradiated by visible light, the recyclable (PhTe)₂-catalyzed oxidative deoximation reaction could occur under mild conditions. In comparison with the thermo reaction, the method employed reduced catalyst loading (1 mol% vs. 2.5 mol%), but afforded elevated product yields with expanded substrate scope. This work demonstrated that for the organotellurium-catalyzed reactions, visible light might be an even more precise driving energy than heating because it could break the Te-Te bond accurately to generate the active free radical catalytic intermediates without damaging the fragile substituents (e.g., heterocycles) of substrates. The use of O₂ instead of explosive H₂O₂ as oxidant affords safer reaction conditions from the large-scale application viewpoint.
- Photocatalysis,
- Tellurium,
- Deoximation,
- Sustainable energy,
- Ketone
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