Citation: Shaoxin Deng, Cheng-Xing Cui, Lu Liu, Lingyao Duan, Jichao Wang, Yuping Zhang, Lingbo Qu. A facile and controllable one-pot synthesis approach to amino-functionalized hollow silica nanoparticles with accessible ordered mesoporous shells[J]. Chinese Chemical Letters, ;2021, 32(3): 1177-1180. doi: 10.1016/j.cclet.2020.09.002 shu

A facile and controllable one-pot synthesis approach to amino-functionalized hollow silica nanoparticles with accessible ordered mesoporous shells

Shaoxin Deng ^{a, b} ,
Cheng-Xing Cui ^{b, c} ,
Lu Liu ^b ,
Lingyao Duan ^b ,
Jichao Wang ^b ,
Yuping Zhang ^{b, *,} ,
Lingbo Qu ^{a, c, **,}

a.
Postdoctoral Station of Food Science and Engineering, College of Food Science and Engineering, Henan University of Technology, Zhengzhou 450001, China
b.
Postdoctoral Research Base, School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China
c.
College of Chemistry, and Institute of Green Catalysis, Zhengzhou University, Zhengzhou 450001, China

^**

zhangyuping@hist.edu.cn

qulingbo@zzu.edu.cn

Received Date: 13 July 2020
Revised Date: 13 August 2020
Accepted Date: 3 September 2020
Available Online: 5 September 2020

Figures(4)

The development of a practical synthetic method to functionalize hollow mesoporous silica with organic groups is of current interest for selective adsorption and energy storage applications. Herein, a facile and controllable one-pot approach for the synthesis of monodisperse amino-functionalized hollow mesoporous silica nanoparticles is presented. A novel solid-to-hollow structural transformation procedure of the silica nanoparticles is presented. The structural transformation is easily designed, as observed through transmission electron microscopy, by tailoring the HCl and N-lauroylsarcosine sodium molar ratio and the water content in the sol-gel. Ordered and radially oriented in situ amino-functionalized mesochannels were successfully introduced into the shells of the hollow silica nanoparticles. A formation mechanism for the hollow mesoporous silica materials is discussed.
- Hollow silica,
- One-pot approach,
- Solid-to-hollow transformation,
- Ordered mesoporous shell,
- Amino functionalization
1. [1]
  J. Qin, B.S. Li, D.P. Yan, Cryst. 7(2017) 89-99. doi: 10.3390/cryst7040089
2. [2]
  T. Zhao, P.P. Qiu, Y.C. Fan, et al., Adv. Sci. 6(2019) 1902008. doi: 10.1002/advs.201902008
3. [3]
  T.F. Gao, A. Kumar, Z.C. Shang, et al., Chin. Chem. Lett. 30(2019) 2274-2278. doi: 10.1016/j.cclet.2019.07.028
4. [4]
  T. Zhao, Y. Ren, G.Y. Jia, et al., Chin. Chem. Lett. 30(2019) 2032-2038. doi: 10.1016/j.cclet.2019.05.006
5. [5]
  P.P. Qiu, T. Zhao, J. Khim, et al., J. Materiomics 6(2020) 45-53. doi: 10.1016/j.jmat.2019.11.003
6. [6]
  R.Z. Liang, R. Tian, Z.H. Liu, D.P. Yan, M. Wei, Chem. Asian J. 9(2014) 1161-1167. doi: 10.1002/asia.201301590
7. [7]
  W.H. He, Y. Yang, L.R. Wang, et al., ChemSusChem 8(2015) 1568-1576. doi: 10.1002/cssc.201403294
8. [8]
  M. Arif, G. Yasin, L. Luo, et al., Appl. Catal. B 265(2020) 118559. doi: 10.1016/j.apcatb.2019.118559
9. [9]
  J. Hu, M. Chen, X.S. Fang, L.M. Wu, Chem. Soc. Rev. 40(2011) 5472-5491. doi: 10.1039/c1cs15103g
10. [10]
  L. Yu, X.Y. Yu, X.W. Lou, Adv. Mater. 30(2018) 1800939. doi: 10.1002/adma.201800939
11. [11]
  E.M. Schneider, S. Taniguchi, Y. Kobayashi, et al., ACS Sustainable Chem. Eng. 5(2017) 4941-4947. doi: 10.1021/acssuschemeng.7b00338
12. [12]
  L.L. Fu, S.F. Zhao, Y. Chen, Z.G. Liu, Chem. Commun. 52(2016) 5577-5580. doi: 10.1039/C6CC00907G
13. [13]
  A. Yildirim, M. Bayindir, J. Mater. Chem. A 3(2015) 3839-3846. doi: 10.1039/C4TA06222A
14. [14]
  X.W. Liu, G.G. Qian, Z. Jiao, M.H. Wu, H.J. Zhang, Chem. Eur. J. 23(2017) 8066-8072. doi: 10.1002/chem.201701140
15. [15]
  W.P. Fan, N. Lu, Z.Y. Shen, et al., Nat. Commun. 10(2019), doi:http://dx.doi.org/10.1038/s41467-019-09158-1. doi: 10.1038/s41467-019-09158-1
16. [16]
  N. Ma, Y.Q. Deng, W.T. Liu, et al., Chem. Commun. 52(2016) 3544-3547. doi: 10.1039/C5CC10106A
17. [17]
  J.J. Wang, W. Xiao, J.Q. Wang, J.M. Lu, J.H. Yang, Mater. Lett. 142(2015) 269-272. doi: 10.1016/j.matlet.2014.11.092
18. [18]
  J.G. Wang, F. Li, H.J. Zhou, et al., Chem. Mater. 21(2009) 612-620. doi: 10.1021/cm803124a
19. [19]
  J. Hu, X. Wang, L.Q. Liu, L.M. Wu, J. Mater. Chem. A 2(2014) 19771-19777. doi: 10.1039/C4TA03856H
20. [20]
  Y.Y. Sun, M. Chen, L.M. Wu, J. Mater. Chem. A 6(2018) 12323-12333. doi: 10.1039/C8TA02569J
21. [21]
  K.S.W. Sing, D.H. Everett, R.A.W. Haul, et al., Pure Appl. Chem. 57(1985) 603-619. doi: 10.1351/pac198557040603
22. [22]
  B. Tan, H.J. Lehmler, S.M. Vyas, B.L. Knuston, S.E. Rankin, Adv. Mater. 17(2005) 2368-2371. doi: 10.1002/adma.200500344
23. [23]
  S. Che, A.E. Garcia-Bennett, T. Yokoi, et al., Nat. Mater. 2(2003) 801-805. doi: 10.1038/nmat1022
24. [24]
  H. Wang, J.G. Wang, H.J. Zhou, et al., Chem. Commun. 47(2011) 7680-7682. doi: 10.1039/c1cc12823j
1. [1]
  Jiaxu Wang , Jinxie Zhang , Xiuping Wang , Jingying Wang , Lina Chen , Jiahui Cao , Wei Cao , Siyu Liang , Ping Luan , Ke Zheng , Xiao-Kun Ouyang , Li Gao , Xiaowen Ou , Fan Zhang , Meitong Ou , Lin Mei . CaCO₃-coated hollow mesoporous silica nanoparticles for pH-responsive fungicides release. Chinese Chemical Letters, 2024, 35(12): 109697-. doi: 10.1016/j.cclet.2024.109697
2. [2]
  Yu Pang , Min Wang , Ning-Hua Yang , Min Xue , Yong Yang . One-pot synthesis of a giant twisted double-layer chiral macrocycle via [4 + 8] imine condensation and its X-ray structure. Chinese Chemical Letters, 2024, 35(10): 109575-. doi: 10.1016/j.cclet.2024.109575
3. [3]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
4. [4]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
5. [5]
  Zhaomin Tang , Qian He , Jianren Zhou , Shuang Yan , Li Jiang , Yudong Wang , Chenxing Yao , Huangzhao Wei , Keda Yang , Jiajia Wang . Active-transporting of charge-reversal Cu(Ⅱ)-doped mesoporous silica nanoagents for antitumor chemo/chemodynamic therapy. Chinese Chemical Letters, 2024, 35(7): 109742-. doi: 10.1016/j.cclet.2024.109742
6. [6]
  Jichun Li , Zhengren Wang , Yu Deng , Hongxiu Yu , Yonghui Deng , Xiaowei Cheng , Kaiping Yuan . Construction of mesoporous silica-implanted tungsten oxides for selective acetone gas sensing. Chinese Chemical Letters, 2024, 35(11): 110111-. doi: 10.1016/j.cclet.2024.110111
7. [7]
  Zhefei Hu , Jingwen Liao , Jiawen Zhou , Lulu Zhao , Yanjuan Liu , Yuefei Zhang , Wei Chen , Sheng Tang . A new green approach to synthesizing MIP-202@porous silica microspheres for positional isomer/enantiomer/hydrophilic separation. Chinese Chemical Letters, 2025, 36(1): 109985-. doi: 10.1016/j.cclet.2024.109985
8. [8]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
9. [9]
  Wantong Zhang , Zixing Xu , Guofei Dai , Zhijian Li , Chunhui Deng . Removal of Microcystin-LR in lake water sample by hydrophilic mesoporous silica composites under high-throughput MALDI-TOF MS detection platform. Chinese Chemical Letters, 2024, 35(5): 109135-. doi: 10.1016/j.cclet.2023.109135
10. [10]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
11. [11]
  Linjie Ju , Zhongxi Huang , Qian Shen , Chan Fu , Shuanghe Li , Wenjie Duan , Chenfeng Xu , Weizhen An , Zhiqiang Zhai , Jifu Wei , Changmin Yu , Guoren Zhou . Glutathione depletion based Pt(Ⅳ) hybrid mesoporous organosilica delivery system to conquer cisplatin chemoresistance: A “one stone three birds” strategy. Chinese Chemical Letters, 2024, 35(10): 109450-. doi: 10.1016/j.cclet.2023.109450
12. [12]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
13. [13]
  Chuan-Zhi Ni , Ruo-Ming Li , Fang-Qi Zhang , Qu-Ao-Wei Li , Yuan-Yuan Zhu , Jie Zeng , Shuang-Xi Gu . A chiral fluorescent probe for molecular recognition of basic amino acids in solutions and cells. Chinese Chemical Letters, 2024, 35(10): 109862-. doi: 10.1016/j.cclet.2024.109862
14. [14]
  Chong Liu , Ling Li , Jiahui Gao , Yanwei Li , Nazhen Zhang , Jing Zang , Cong Liu , Zhaopei Guo , Yanhui Li , Huayu Tian . The study of antibacterial activity of cationic poly(β-amino ester) regulating by amphiphilic balance. Chinese Chemical Letters, 2025, 36(2): 110118-. doi: 10.1016/j.cclet.2024.110118
15. [15]
  Guanxiong Yu , Chengkai Xu , Huaqiang Ju , Jie Ren , Guangpeng Wu , Chengjian Zhang , Xinghong Zhang , Zhen Xu , Weipu Zhu , Hao-Cheng Yang , Haoke Zhang , Jianzhao Liu , Zhengwei Mao , Yang Zhu , Qiao Jin , Kefeng Ren , Ziliang Wu , Hanying Li . Key progresses of MOE key laboratory of macromolecular synthesis and functionalization in 2023. Chinese Chemical Letters, 2024, 35(11): 109893-. doi: 10.1016/j.cclet.2024.109893
16. [16]
  Chengcheng Xie , Chengyi Xiao , Hongshuo Niu , Guitao Feng , Weiwei Li . Mesoporous organic solar cells. Chinese Chemical Letters, 2024, 35(11): 109849-. doi: 10.1016/j.cclet.2024.109849
17. [17]
  Ningxiang Wu , Huaping Zhao , Yong Lei . Nanomaterials with highly ordered nanostructures: Definition, influence and future challenge. Chinese Journal of Structural Chemistry, 2024, 43(11): 100392-100392. doi: 10.1016/j.cjsc.2024.100392
18. [18]
  Jiaxuan Wang , Tonghe Liu , Bingxiang Wang , Ziwei Li , Yuzhong Niu , Hou Chen , Ying Zhang . Synthesis of polyhydroxyl-capped PAMAM dendrimer/silica composites for the adsorption of aqueous Hg(II) and Ag(I). Chinese Chemical Letters, 2024, 35(12): 109900-. doi: 10.1016/j.cclet.2024.109900
19. [19]
  Tong Zhang , Xiaojing Liang , Licheng Wang , Shuai Wang , Xiaoxiao Liu , Yong Guo . An ionic liquid assisted hydrogel functionalized silica stationary phase for mixed-mode liquid chromatography. Chinese Chemical Letters, 2025, 36(1): 109889-. doi: 10.1016/j.cclet.2024.109889
20. [20]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(810)
HTML views(113)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142