Citation: Chang Ma, Yahui Mo, Lei Liu, Yifeng Yu, Aibing Chen. ZIF-derived mesoporous carbon materials prepared by activation via Na₂SiO₃ for supercapacitor[J]. Chinese Chemical Letters, ;2021, 32(4): 1485-1490. doi: 10.1016/j.cclet.2020.08.041 shu

ZIF-derived mesoporous carbon materials prepared by activation via Na₂SiO₃ for supercapacitor

Chang Ma ^a ,
Yahui Mo ^a ,
Lei Liu ^a ,
Yifeng Yu ^a ,
Aibing Chen ^{a, b, *,}

a.
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
b.
CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

chen_ab@163.com

Received Date: 19 June 2020
Revised Date: 17 August 2020
Accepted Date: 25 August 2020
Available Online: 27 August 2020

Figures(5)

Metal organic frameworks (MOFs) derived carbonaceous materials have a wide range of applications in the fields of energy storage, catalysis, adsorption and separation, etc. Especially, zeolitic imidazolate framework-8 (ZIF-8) is an excellent candidate to synthesize porous carbon due to the large surface area and high nitrogen content. However, the dominated microporous structure of ZIF-8-derived carbon significantly hinders ionic mass transfer, limiting the improvement of performance. Herein, MOF-derived mesoporous carbon was prepared using ZIF-8 as carbon precursor and cheap sodium silicate (Na₂SiO₃) as activator. The introduction of Na₂SiO₃ created rich mesoporous structure and increased specific surface area, as well as the effects of pyrolysis temperature and Na₂SiO₃ dosage on performance was also investigated. The obtained ZIF-derived porous carbon exhibits good electrochemical performance with specific capacitance of 263 F/g at 1 A/g and excellent cycle life (96.07% after 10,000 GCD cycles) in supercapacitor. The use of cheap Na₂SiO₃ activator provides a new orientation for the preparation of MOF-derived carbons with rich pores, high surface area, and facilitates the large-scale application of MOF-derived carbons.
- ZIF-8,
- Mesoporous carbon,
- Na₂SiO₃,
- Activation,
- Supercapacitors
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ZIF-derived mesoporous carbon materials prepared by activation via Na2SiO3 for supercapacitor

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ZIF-derived mesoporous carbon materials prepared by activation via Na₂SiO₃ for supercapacitor