Citation: Pengbo Ye, Xuan Liu, Gang Wang, Lei Liu. Nickel(Ⅱ)-catalyzed asymmetric alkylation of acyclic oxocarbenium ions with carboxylic acid derivatives[J]. Chinese Chemical Letters, ;2021, 32(3): 1237-1240. doi: 10.1016/j.cclet.2020.08.034 shu

Nickel(Ⅱ)-catalyzed asymmetric alkylation of acyclic oxocarbenium ions with carboxylic acid derivatives

School of Chemistry and Chemical Engineering, Shandong University, Ji'nan 250100, China

leiliu@sdu.edu.cn

Received Date: 21 June 2020
Revised Date: 6 August 2020
Accepted Date: 21 August 2020
Available Online: 8 September 2020

Figures(6)

A nickel(Ⅱ)-catalyzed asymmetric alkylation of acyclic oxocarbenium ions generated in situ from corresponding acetals with carboxylic acid derivatives to prepare β-alkoxyl carbonyl moieties with diverse α-substituents has been disclosed. The method exhibited broad scope of acetals and carboxylic acid derivatives with excellent enantioselectivity and good functional group compatibility, and can be conducted in a gram-scale without obvious loss of efficiency.
- Oxocarbenium ion,
- Acyclic,
- Nickel,
- Asymmetric catalysis,
- Alkylation
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