Citation: Liu Juan, Zeng Liqiang, Liao Su, Liao Xiaofeng, Liu Jun, Mao Jinshui, Chen Yunnen, Qiu Tingsheng, Ren Sili. Highly efficient enrichment and adsorption of rare earth ions (yttrium(Ⅲ)) by recyclable magnetic nitrogen functionalized mesoporous expanded perlite[J]. Chinese Chemical Letters, ;2020, 31(10): 2849-2853. doi: 10.1016/j.cclet.2020.08.017 shu

Highly efficient enrichment and adsorption of rare earth ions (yttrium(Ⅲ)) by recyclable magnetic nitrogen functionalized mesoporous expanded perlite

Liu Juan ^a,b ,
Zeng Liqiang ^a ,
Liao Su ^a ,
Liao Xiaofeng ^a ,
Liu Jun ^a ,
Mao Jinshui ^a ,
Chen Yunnen ^a ,
Qiu Tingsheng ^a ,
Ren Sili ^a,*

a.
Jiangxi Key Laboratory of Mining Engineering, School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
b.
School of Chemical Engineering and Materials, Changzhou Institute of Technology, Changzhou 213000, China

sili_ren@163.com

Received Date: 21 May 2020
Revised Date: 7 August 2020
Accepted Date: 13 August 2020
Available Online: 15 August 2020

Figures(4)

A magnetic mesoporous expanded perlite-based (EP_d-APTES@Fe₃O₄) composite was designed and synthesized as a novel adsorbent for enrichment of rare earth ions in aqueous solution. Effect of various factors including the pH of solution, contact time and adsorbent dosage on the adsorption behaviors of yttrium(Ⅲ) by the EP_d-APTES@Fe₃O₄ nano-material composites from aqueous solution was investigated. The maximum adsorption capacity of the as-prepared materials for yttrium(Ⅲ) ions was 383.2 mg/g. Among the various isotherm models, the Freundlich isotherm model could well described for the adsorption of the rare earth ions at pH 5.5 and 298.15 K. The kinetic analysis indicated that the adsorption process followed the pseudo-second order kinetics model, and the rate-determining step might be chemical adsorption. Thermodynamic parameters declared that the adsorption process was endothermic. In addition, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and the quantum chemical calculation indicated that the yttrium(Ⅲ) ions were captured on the EP_d-APTES@Fe₃O₄ surface mainly by coordination with functional group of -NH₂. More importantly, the adsorption-desorption studies indicated that the EP_d-APTES@Fe₃O₄ nano-material composites had a high stability and good recyclability.
- Rare earth ions,
- Yttrium(Ⅲ) ions,
- Magnetic mesoporous expanded perlite,
- Enrichment,
- Adsorption
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