Citation: Qiu Hai-Bin, Guo Pu-Can, Yuan Li, Sheng Guo-Ping. Different non-radical oxidation processes of persulfate and peroxymonosulfate activation by nitrogen-doped mesoporous carbon[J]. Chinese Chemical Letters, ;2020, 31(10): 2614-2618. doi: 10.1016/j.cclet.2020.08.014 shu

Different non-radical oxidation processes of persulfate and peroxymonosulfate activation by nitrogen-doped mesoporous carbon

CAS Key Laboratory of Urban Pollutant Conversion, Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026, China

ly2016@ustc.edu.cn

gpsheng@ustc.edu.cn

Received Date: 18 June 2020
Revised Date: 14 July 2020
Accepted Date: 11 August 2020
Available Online: 13 August 2020

Figures(3)

Activated persulfate oxidation is an emerging advanced oxidation process for organic pollutant degradation. Own to different molecular structures and oxidation potentials, persulfate (PDS) and peroxymonosulfate (PMS) may show different degradation performances due to various catalytic mechanisms even by the same catalysts. In this study, the nitrogen-doped mesoporous carbon (N-OMC) was applied to activate PDS and PMS for degrading a model organic pollutant phenol to reveal their activation mechanisms. Results show that both PDS and PMS could be efficiently activated by N-OMC. The degradation of phenol fitted well with pseudo-first-order kinetics, whose kinetic constants increased with the increase of pH, PDS/PMS dosage, and N-OMC dosage. Based on quenching experiments and electron spin resonance spin-trapping technique, the N-OMC was found to activate PDS and PMS via non-radical process of electron transfer and singlet oxygen formation, respectively, instead of the commonly observed radical process. This work will be useful to understand the activation processes of PDS and PMS, and benefit for the development of catalysts for pollutant degradation.
- Nitrogen-doped mesoporous carbon,
- Persulfate,
- Peroxymonosulfate,
- Non-radical process,
- Electron transfer,
- Singlet oxygen formation
1. [1]
  B.C. Hodges, E.L. Cates, J.H. Kim, Nat. Nanotechnol. 13 (2018) 642-650. doi: 10.1038/s41565-018-0216-x
2. [2]
  D.B. Miklos, C. Remy, M. Jekel, et al., Water Res. 139 (2018) 118-131. doi: 10.1016/j.watres.2018.03.042
3. [3]
  A. Tsitonaki, B. Petri, M. Crimi, et al., Crit. Rev. Environ. Sci. Technol. 40 (2010) 55-91. doi: 10.1080/10643380802039303
4. [4]
  J. Wang, S. Wang, Chem. Eng. J. 334 (2018) 1502-1517. doi: 10.1016/j.cej.2017.11.059
5. [5]
  C.D. Qi, G. Yu, J. Huang, et al., Chem. Eng. J. 353 (2018) 490-498. doi: 10.1016/j.cej.2018.07.056
6. [6]
  H. Zhang, Q. Ji, L. Lai, G. Yao, B. Lai, Chin. Chem. Lett. 30 (2019) 1129-1132. doi: 10.1016/j.cclet.2019.01.025
7. [7]
  M. Ma, L. Chen, J. Zhao, et al., Chin. Chem. Lett. 30 (2019) 2191-2195. doi: 10.1016/j.cclet.2019.09.031
8. [8]
  L.D. Lai, H.Y. Zhou, B. Lai, Chem. Eng. J. 349 (2018) 633-645. doi: 10.1016/j.cej.2018.05.134
9. [9]
  E.T. Yun, H.Y. Yoo, H. Bae, H.I. Kim, J. Lee, Environ. Sci. Technol. 51 (2017) 10090-10099. doi: 10.1021/acs.est.7b02519
10. [10]
  L. Liu, Y.P. Zhu, M. Su, et al., ChemCatChem 7 (2015) 11878-11886.
11. [11]
  X. Duan, H. Sun, Y. Wang, J. Kang, S. Wang, ACS Catal. 5 (2014) 553-559.
12. [12]
  H. Lee, H.J. Lee, J. Jeong, et al., Chem. Eng. J. 266 (2015) 28-33. doi: 10.1016/j.cej.2014.12.065
13. [13]
  W. Ren, G. Nie, P. Zhou, et al., Environ. Sci. Technol. 54 (2020) 6438-6447. doi: 10.1021/acs.est.0c01161
14. [14]
  L. Tang, Y. Liu, J. Wang, et al., Appl. Catal. B:Environ. 231 (2018) 1-10. doi: 10.1016/j.apcatb.2018.02.059
15. [15]
  H. Lee, H.I. Kim, S. Weon, et al., Environ. Sci. Technol. 50 (2016) 10134-10142. doi: 10.1021/acs.est.6b02079
16. [16]
  Y. Zhou, J. Jiang, Y. Gao, et al., Environ. Sci. Technol. 49 (2015) 12941-12950. doi: 10.1021/acs.est.5b03595
17. [17]
  G. Fang, J. Gao, D.D. Dionysiou, C. Liu, D. Zhou, Environ. Sci. Technol. 47 (2013) 4605-4611. doi: 10.1021/es400262n
18. [18]
  P. Hu, H. Su, Z. Chen, et al., Environ. Sci. Technol. 51 (2017) 11288-11296. doi: 10.1021/acs.est.7b03014
19. [19]
  S.H. Ho, Y.D. Chen, R. Li, et al., Water Res. 159 (2019) 77-86. doi: 10.1016/j.watres.2019.05.008
20. [20]
  Y. Gao, Z. Chen, Y. Zhu, T. Li, C. Hu, Environ. Sci. Technol. 54 (2020) 1232-1241. doi: 10.1021/acs.est.9b05856
21. [21]
  D. Zhao, J. Feng, Q. Huo, et al., Science 279 (1997) 548-552.
22. [22]
  R. Silva, A.V. Biradar, L. Fabris, T. Asefa, J. Phys. Chem. C 115 (2011) 22810-22817. doi: 10.1021/jp206824h
23. [23]
  G.V. Buxton, C.L. Greenstock, W.P. Helman, A.B. Ross, J. Phys. Chem. Ref. Data 17 (1988) 513-886. doi: 10.1063/1.555805
24. [24]
  H.E. Gsponer, C.M. Previtali, N.A. García, Toxicol. Environ. Chem. 16 (1987) 23-37.
25. [25]
  J. Moan, E. Wold, Nature 279 (1979) 450-451. doi: 10.1038/279450a0
26. [26]
  C.D. Qi, X.T. Liu, J. Ma, et al., Chemosphere 151 (2016) 280-288. doi: 10.1016/j.chemosphere.2016.02.089
27. [27]
  Y. Yang, G. Banerjee, G.W. Brudvig, J.H. Kim, J.J. Pignatello, Environ. Sci. Technol. 52 (2018) 5911-5919. doi: 10.1021/acs.est.8b00735
28. [28]
  W. Zhu, W.T. Ford, J. Org. Chem. 56 (1991) 7022-7026. doi: 10.1021/jo00025a014
29. [29]
  A. Lawrence, C.M. Jones, P. Wardman, M.J. Burkitt, J. Biol. Chem. 278 (2003) 29410-29419. doi: 10.1074/jbc.M300054200
30. [30]
  B. Song, G. Wang, M. Tan, J. Yuan, J. Am. Chem. Soc. 128 (2006) 13442-13450. doi: 10.1021/ja062990f
31. [31]
  H. Kim, W. Kim, Y. Mackeyev, et al., Environ. Sci. Technol. 46 (2012) 9606-9613. doi: 10.1021/es301775k
32. [32]
  J. Lee, S. Hong, Y. Mackeyev, et al., Environ. Sci. Technol. 45 (2011) 10598-10604. doi: 10.1021/es2029944
33. [33]
  T. Zhang, Y. Chen, Y. Wang, et al., Environ. Sci. Technol. 48 (2014) 5868-5875. doi: 10.1021/es501218f
1. [1]
  Yun-Xin Huang , Lin-Qian Yu , Ke-Yu Chen , Hao Wang , Shou-Yan Zhao , Bao-Cheng Huang , Ren-Cun Jin . Biochar with self-doped N to activate peroxymonosulfate for bisphenol-A degradation via electron transfer mechanism: The active edge graphitic N site. Chinese Chemical Letters, 2024, 35(9): 109437-. doi: 10.1016/j.cclet.2023.109437
2. [2]
  Yu Yao , Jinqiang Zhang , Yantao Wang , Kunsheng Hu , Yangyang Yang , Zhongshuai Zhu , Shuang Zhong , Huayang Zhang , Shaobin Wang , Xiaoguang Duan . Nitrogen-rich carbon for catalytic activation of peroxymonosulfate towards green synthesis. Chinese Chemical Letters, 2024, 35(11): 109633-. doi: 10.1016/j.cclet.2024.109633
3. [3]
  Mengmeng Ao , Jian Wei , Chuan-Shu He , Heng Zhang , Zhaokun Xiong , Yonghui Song , Bo Lai . Insight into the activation of peroxymonosulfate by N-doped copper-based carbon for efficient degradation of organic pollutants: Synergy of nonradicals. Chinese Chemical Letters, 2025, 36(1): 109882-. doi: 10.1016/j.cclet.2024.109882
4. [4]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
5. [5]
  Cunjun Li , Wencong Liu , Xianlei Chen , Liang Li , Shenyu Lan , Mingshan Zhu . Adsorption and activation of peroxymonosulfate on BiOCl for carbamazepine degradation: The role of piezoelectric effect. Chinese Chemical Letters, 2024, 35(10): 109652-. doi: 10.1016/j.cclet.2024.109652
6. [6]
  Shili Wang , Mamitiana Roger Razanajatovo , Xuedong Du , Shunli Wan , Xin He , Qiuming Peng , Qingrui Zhang . Recent advances on decomplexation mechanisms of heavy metal complexes in persulfate-based advanced oxidation processes. Chinese Chemical Letters, 2024, 35(6): 109140-. doi: 10.1016/j.cclet.2023.109140
7. [7]
  Supphachok Chanmungkalakul , Syed Ali Abbas Abedi , Federico J. Hernández , Jianwei Xu , Xiaogang Liu . The dark side of cyclooctatetraene (COT): Photophysics in the singlet states of “self-healing” dyes. Chinese Chemical Letters, 2024, 35(8): 109227-. doi: 10.1016/j.cclet.2023.109227
8. [8]
  Chunxiu Yu , Zelin Wu , Hongle Shi , Lingyun Gu , Kexin Chen , Chuan-Shu He , Yang Liu , Heng Zhang , Peng Zhou , Zhaokun Xiong , Bo Lai . Insights into the electron transfer mechanisms of peroxydisulfate activation by modified metal-free acetylene black for degradation of sulfisoxazole. Chinese Chemical Letters, 2024, 35(8): 109334-. doi: 10.1016/j.cclet.2023.109334
9. [9]
  Ming-Zhen Li , Yang Zhang , Kun Li , Ya-Nan Shang , Yi-Zhen Zhang , Yu-Jiao Kan , Zhi-Yang Jiao , Yu-Yuan Han , Xiao-Qiang Cao . In situ regeneration of catalyst for Fenton-like degradation by photogenerated electron transportation: Characterization, performance and mechanism comparison. Chinese Chemical Letters, 2025, 36(1): 109885-. doi: 10.1016/j.cclet.2024.109885
10. [10]
  Kexin Yin , Jingren Yang , Yanwei Li , Qian Li , Xing Xu . Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation. Chinese Chemical Letters, 2024, 35(12): 109847-. doi: 10.1016/j.cclet.2024.109847
11. [11]
  Dong Cheng , Youyou Feng , Bingxi Feng , Ke Wang , Guoxin Song , Gen Wang , Xiaoli Cheng , Yonghui Deng , Jing Wei . Polyphenol-mediated interfacial deposition strategy for supported manganese oxide catalysts with excellent pollutant degradation performance. Chinese Chemical Letters, 2024, 35(5): 108623-. doi: 10.1016/j.cclet.2023.108623
12. [12]
  Yan Wang , Jiaqi Zhang , Xiaofeng Wu , Sibo Wang , Masakazu Anpo , Yuanxing Fang . Elucidating oxygen evolution and reduction mechanisms in nitrogen-doped carbon-based photocatalysts. Chinese Chemical Letters, 2025, 36(2): 110439-. doi: 10.1016/j.cclet.2024.110439
13. [13]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2024.100199
14. [14]
  Jiahao Xie , Jin Liu , Bin Liu , Xin Meng , Zhuang Cai , Xiaoqin Xu , Cheng Wang , Shijie You , Jinlong Zou . Yolk shell-structured pyrite-type cobalt sulfide grafted by nitrogen-doped carbon-needles with enhanced electrical conductivity for oxygen electrocatalysis. Chinese Chemical Letters, 2024, 35(7): 109236-. doi: 10.1016/j.cclet.2023.109236
15. [15]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
16. [16]
  Quanyou Guo , Yue Yang , Tingting Hu , Hongqi Chu , Lijun Liao , Xuepeng Wang , Zhenzi Li , Liping Guo , Wei Zhou . Regulating local electron transfer environment of covalent triazine frameworks through F, N co-modification towards optimized oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(1): 110235-. doi: 10.1016/j.cclet.2024.110235
17. [17]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2023.100332
18. [18]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
19. [19]
  Tianyi Yang , Fangxi Su , Dehuan Shi , Shenghong Zhong , Yalin Guo , Zhaohui Liu , Jianfeng Huang . Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix. Chinese Chemical Letters, 2025, 36(2): 110444-. doi: 10.1016/j.cclet.2024.110444
20. [20]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(563)
HTML views(84)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142