Citation: Nimai Silang, Zhang Heng, Wu Zelin, Li Naiwen, Lai Bo. Efficient degradation of sulfamethoxazole by acetylene black activated peroxydisulfate[J]. Chinese Chemical Letters, ;2020, 31(10): 2657-2660. doi: 10.1016/j.cclet.2020.08.008 shu

Efficient degradation of sulfamethoxazole by acetylene black activated peroxydisulfate

Nimai Silang ^a,b ,
Zhang Heng ^a,c ,
Wu Zelin ^a,c ,
Li Naiwen ^a,b,*, ,
Lai Bo ^a,c,*,

a.
State Key Laboratory of Hydraulics and Mountain River Engineering, College of Architecture and Environment, Sichuan University, Chengdu 610065, China
b.
College of Hydraulic and Hydroelectric Engineering, Sichuan University, Chengdu 610065, China
c.
Sino-German Centre for Water and Health Research, Sichuan University, Chengdu 610065, China

linaiwen@scu.edu.cn

laibo@scu.edu.cn

Received Date: 18 June 2020
Revised Date: 18 July 2020
Accepted Date: 6 August 2020
Available Online: 8 August 2020

Figures(5)

Acetylene black (AB), as a kind of carbon material with large specific surface area, low density, strong electron transferability, is supposed to have great potential for application in advanced oxidation processes (AOPs). In this study, AB was utilized as a peroxydisulfate (PDS) activator for the catalytic degradation of sulfamethoxazole (SMX) in aqueous media. Scanning electron microscopy (SEM), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) techniques, zeta potential and Raman spectra were employed to characterize the features of AB. To verify the excellent performance of AB/PDS systems, a series of control experiments were carried out. Compared to graphite/PDS and biochar/PDS system, AB/PDS system could complete degradation of SMX within 15 min. Besides, the effects of key factors including AB dosage, PDS dosage, initial pH and SMX concentration on SMX degradation in AB/PDS system were elucidated systematically. Furthermore, through the radical quenching experiments, it was proved that singlet oxygen (¹O₂) was dominantly responsible for the degradation of SMX. Finally, based on the experiment results and comprehensive analysis, a probable reaction mechanism of AB/PDS system for SMX degradation was proposed. This work suggests that AB has a good potential for tackling the hazardous pollutants in environmental remediation.
- Sulfamethoxazole (SMX),
- Acetylene black (AB),
- Peroxydisulfate (PDS),
- Reaction mechanism
1. [1]
  R.F. Service, Science 313(2006) 1088-1090. doi: 10.1016/j.cej.2019.122497
2. [2]
  C.J. Vorosmarty, P.B. McIntyre, M.O. Gessner, et al., Nature 467(2010) 555-561. doi: 10.1016/j.cattod.2017.11.003
3. [3]
  M.A. Shannon, P.W. Bohn, M. Elimelech, et al., Nature 452(2008) 301-310. doi: 10.1016/j.cej.2017.11.174
4. [4]
  J. Li, S. Li, X. Wang, et al., Chin. Chem. Lett. 30(2019) 239-242.
5. [5]
  M. Nystrom, L. Kaipia, S. Luque, J. Membr. Sci. 98(1995) 249-262. doi: 10.1016/j.envint.2017.10.016
6. [6]
  K.L. Cho, A.J. Hill, F. Caruso, S.E. Kentish, Adv. Mater. 27(2015) 2791-2796. doi: 10.1016/j.cej.2019.121908
7. [7]
  G.M. Geise, H.B. Park, A.C. Sagle, B.D. Freeman, J.E. McGrath, J. Membr. Sci. 369(2011) 130-138. doi: 10.1021/es404118q
8. [8]
  J. Abraham, K.S. Vasu, C.D. Williams, et al., Nat. Nanotech. 12(2017) 546-550. doi: 10.1016/j.cej.2019.03.178
9. [9]
  L. Chen, G. Shi, J. Shen, et al., Nature 550(2017) 380-383. doi: 10.1016/S0304-3894(02)00282-0
10. [10]
  K. Goh, W. Jiang, H.E. Karahan, et al., Adv. Funct. Mater. 25(2015) 7348-7359. doi: 10.1016/j.cej.2017.07.132
11. [11]
  A. Morelos-Gomez, R. Cruz-Silva, H. Muramatsu, et al., Nat. Nanotechnol. 12(2017) 1083-1088. doi: 10.1016/j.apcatb.2015.07.024
12. [12]
  K.H. Thebo, X. Qian, Q. Zhang, et al., Nat. Commun. 9(2018) 1486. doi: 10.1016/j.apcatb.2020.119136
13. [13]
  C.N. Yeh, K. Raidongia, J. Shao, Q.H. Yang, J. Huang, Nat. Chem. 7(2015) 166-170. doi: 10.1016/j.cclet.2019.01.025
14. [14]
  S. Zheng, Q. Tu, J.J. Urban, S. Li, B. Mi, ACS Nano 11(2017) 6440-6450. doi: 10.1016/j.cej.2016.04.028
15. [15]
  Y. Wei, Y. Zhang, X. Gao, et al., Carbon 139(2018) 964-981. doi: 10.1016/j.cclet.2020.01.017
16. [16]
  W. Wu, J. Su, M. Jia, et al., J. Mater. Chem. A 7(2019) 13007-13011. doi: 10.1016/j.chemosphere.2019.124979
17. [17]
  H. Liu, H. Wang, X. Zhang, Adv. Mater. 27(2015) 249-254. doi: 10.1016/j.cej.2020.124456
18. [18]
  Y. Zhang, S. Zhang, T.S. Chung, Environ. Sci. Technol. 49(2015) 10235-10242. doi: 10.1016/j.cclet.2019.04.057
19. [19]
  W. Li, W. Wu, Z. Li, ACS Nano 12(2018) 9309-9317. doi: 10.1016/j.cej.2019.122234
20. [20]
  Y. Liu, K. Ai, L. Lu, Chem. Rev. 114(2014) 5057-5115. doi: 10.1021/acs.est.5b03595
21. [21]
  Y. Zhang, M. Qi, R. Fu, Chin. Chem. Lett. 27(2016) 88-90. doi: 10.1016/j.watres.2017.02.016
22. [22]
  H. Lee, S.M. Dellatore, W.M. Miller, P.B. Messersmith, Science 318(2007) 426-430. doi: 10.1016/j.apcatb.2017.11.051
23. [23]
  Y. Qian, C. Zhou, A. Huang, Carbon 136(2018) 28-37. doi: 10.1016/j.cej.2019.02.211
24. [24]
  J. Wang, T. Huang, L. Zhang, Q.J. Yu, L. Hou, Environ. Technol. 39(2018) 3055-3065. doi: 10.1016/j.cej.2019.01.040
25. [25]
  K. Xu, B. Feng, C. Zhou, A. Huang, Chem. Eng. Sci. 146(2016) 159-165. doi: 10.1016/j.cclet.2019.08.020
26. [26]
  Y. Xu, M. Wu, S. Yu, et al., J. Membr. Sci. 586(2019) 15-22. doi: 10.1039/C9TA02931A
27. [27]
  E. Yang, C.M. Kim, J. Song, et al., Carbon 117(2017) 293-300. doi: 10.1016/j.cclet.2019.12.023
28. [28]
  W. Wu, Z. Li, Y. Chen, W. Li, Environ. Sci. Technol. 53(2019) 3764-3772. doi: 10.1039/C7TA08472B
29. [29]
  X.Q. Cheng, C. Zhang, Z.X. Wang, L. Shao, J. Membr. Sci. 499(2016) 326-334. doi: 10.1016/j.micromeso.2014.03.020
30. [30]
  H. Lee, J. Rho, P.B. Messersmith, Adv. Mater. 21(2009) 431-434. doi: 10.1016/j.carbon.2018.05.039
31. [31]
  C. Zhang, Y. Lv, W.Z. Qiu, A. He, Z.K. Xu, ACS Appl. Mater. Interfaces 9(2017) 14437-14444. doi: 10.1021/cm0101069
32. [32]
  H. Huang, Y. Mao, Y. Ying, et al., Chem. Commun. 49(2013) 5963-5965. doi: 10.1016/j.jhazmat.2018.04.021
33. [33]
  X.Q. Cheng, Z.X. Wang, Y. Zhang, et al., J. Membr. Sci. 554(2018) 385-394. doi: 10.1016/j.apcatb.2017.07.064
34. [34]
  Y. Han, Z. Xu, C. Gao, Adv. Funct. Mater. 23(2013) 3693-3700. doi: 10.1016/j.apcatb.2019.118160
35. [35]
  Y. Li, S. Shi, H. Cao, et al., J. Membr. Sci. 566(2018) 44-53. doi: 10.1016/j.cej.2017.07.042
36. [36]
  H.M. Hegab, A. ElMekawy, T.G. Barclay, et al., Desalination 385(2016) 126-137. doi: 10.1016/j.cej.2019.123361
37. [37]
  W. Choi, J. Choi, J. Bang, J.H. Lee, ACS Appl. Mater. Interfaces 5(2013) 12510-12519. doi: 10.1016/j.carbon.2016.09.064
38. [38]
  H. Ruan, Z. Zheng, J. Pan, et al., J. Membr. Sci. 550(2018) 427-435. doi: 10.1016/j.molstruc.2007.04.021
39. [39]
  Y. Zhang, S. Ni, X. Wang, et al., Chem. Eng. J. 372(2019) 82-91. doi: 10.1021/acs.est.5b05974
1. [1]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
2. [2]
  Qin Cheng , Ming Huang , Qingqing Ye , Bangwei Deng , Fan Dong . Indium-based electrocatalysts for CO₂ reduction to C1 products. Chinese Chemical Letters, 2024, 35(6): 109112-. doi: 10.1016/j.cclet.2023.109112
3. [3]
  Tingting Liu , Pengfei Sun , Wei Zhao , Yingshuang Li , Lujun Cheng , Jiahai Fan , Xiaohui Bi , Xiaoping Dong . Magnesium doping to improve the light to heat conversion of OMS-2 for formaldehyde oxidation under visible light irradiation. Chinese Chemical Letters, 2024, 35(4): 108813-. doi: 10.1016/j.cclet.2023.108813
4. [4]
  Chunxiu Yu , Zelin Wu , Hongle Shi , Lingyun Gu , Kexin Chen , Chuan-Shu He , Yang Liu , Heng Zhang , Peng Zhou , Zhaokun Xiong , Bo Lai . Insights into the electron transfer mechanisms of peroxydisulfate activation by modified metal-free acetylene black for degradation of sulfisoxazole. Chinese Chemical Letters, 2024, 35(8): 109334-. doi: 10.1016/j.cclet.2023.109334
5. [5]
  Fengrui Yang , Debing Wang , Xinying Zhang , Jie Zhang , Zhichao Wu , Qiaoying Wang . Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways. Chinese Chemical Letters, 2024, 35(10): 109599-. doi: 10.1016/j.cclet.2024.109599
6. [6]
  Qian Huang , Zhaowei Li , Jianing Zhao , Ao Yu . Quantum Chemical Calculations Reveal the Details Below the Experimental Phenomenon. University Chemistry, 2024, 39(3): 395-400. doi: 10.3866/PKU.DXHX202309018
7. [7]
  Ling Fan , Meili Pang , Yeyun Zhang , Yanmei Wang , Zhenfeng Shang . Quantum Chemistry Calculation Research on the Diels-Alder Reaction of Anthracene and Maleic Anhydride: Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 133-139. doi: 10.3866/PKU.DXHX202309024
8. [8]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
9. [9]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
10. [10]
  Yong Wang , Yingying Zhao , Boshun Wan . Analysis of Organic Questions in the 37th Chinese Chemistry Olympiad (Preliminary). University Chemistry, 2024, 39(11): 406-416. doi: 10.12461/PKU.DXHX202403009
11. [11]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
12. [12]
  Shaoming Dong , Yiming Niu , Yinghui Pu , Yongzhao Wang , Bingsen Zhang . Subsurface carbon modification of Ni-Ga for improved selectivity in acetylene hydrogenation reaction. Chinese Chemical Letters, 2024, 35(12): 109525-. doi: 10.1016/j.cclet.2024.109525
13. [13]
  Bharathi Natarajan , Palanisamy Kannan , Longhua Guo . Metallic nanoparticles for visual sensing: Design, mechanism, and application. Chinese Journal of Structural Chemistry, 2024, 43(9): 100349-100349. doi: 10.1016/j.cjsc.2024.100349
14. [14]
  Shuo Li , Xinran Liu , Yongjie Zheng , Jun Ma , Shijie You , Heshan Zheng . Effective peroxydisulfate activation by CQDs-MnFe₂O₄@ZIF-8 catalyst for complementary degradation of bisphenol A by free radicals and non-radical pathways. Chinese Chemical Letters, 2024, 35(5): 108971-. doi: 10.1016/j.cclet.2023.108971
15. [15]
  Yuan Dong , Mutian Ma , Zhenyang Jiao , Sheng Han , Likun Xiong , Zhao Deng , Yang Peng . Effect of electrolyte cation-mediated mechanism on electrocatalytic carbon dioxide reduction. Chinese Chemical Letters, 2024, 35(7): 109049-. doi: 10.1016/j.cclet.2023.109049
16. [16]
  Hongxia Li , Xiyang Wang , Du Qiao , Jiahao Li , Weiping Zhu , Honglin Li . Mechanism of nanoparticle aggregation in gas-liquid microfluidic mixing. Chinese Chemical Letters, 2024, 35(4): 108747-. doi: 10.1016/j.cclet.2023.108747
17. [17]
  Yixin Zhang , Ting Wang , Jixiang Zhang , Pengyu Lu , Neng Shi , Liqiang Zhang , Weiran Zhu , Nongyue He . Formation mechanism for stable system of nanoparticle/protein corona and phospholipid membrane. Chinese Chemical Letters, 2024, 35(4): 108619-. doi: 10.1016/j.cclet.2023.108619
18. [18]
  Jia Fu , Shilong Zhang , Lirong Liang , Chunyu Du , Zhenqiang Ye , Guangming Chen . PEDOT-based thermoelectric composites: Preparation, mechanism and applications. Chinese Chemical Letters, 2024, 35(9): 109804-. doi: 10.1016/j.cclet.2024.109804
19. [19]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
20. [20]
  Wenzhong Zhang , Zirui Yan , Lingcheng Chen , Yi Xiao . Sn-fused perylene diimides: Synthesis, mechanism, and properties. Chinese Chemical Letters, 2024, 35(10): 109582-. doi: 10.1016/j.cclet.2024.109582

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(566)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142