Citation: Ye Jinmei, Wen Jie, Zhao Dongdong, Zhang Peilun, Li Airong, Zhang Lianhong, Zhang Hui, Wu Mengqi. Macroporous 3D carbon-nitrogen (CN) confined MoO_x catalyst for enhanced oxidative desulfurization of dibenzothiophene[J]. Chinese Chemical Letters, ;2020, 31(10): 2819-2824. doi: 10.1016/j.cclet.2020.08.004 shu

Macroporous 3D carbon-nitrogen (CN) confined MoO_x catalyst for enhanced oxidative desulfurization of dibenzothiophene

Ye Jinmei ^a,1 ,
Wen Jie ^a,*, ,
Zhao Dongdong ^a,1 ,
Zhang Peilun ^b ,
Li Airong ^a ,
Zhang Lianhong ^a ,
Zhang Hui ^a,*, ,
Wu Mengqi ^a

a.
Center for Computational Chemistry and Molecular Simulation, College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China
b.
Department of Chemical and Biological Engineering, Case Western Reserve University, Cleveland, OH 44120, United States

wenjie@swpu.edu.cn

zhanghuiswpu@163.com

Received Date: 21 May 2020
Revised Date: 6 July 2020
Accepted Date: 5 August 2020
Available Online: 7 August 2020

Figures(3)

Macroporous 3D carbon doped with nitrogen confined Mo catalyst (MoO_x@CN) had been prepared by a facile one-step pyrolysis technique using silica as a template and was employed for oxidative desulfurization (ODS) of dibenzothiophene (DBT) in model fuel with H₂O₂ as oxidant. The effect of different operating conditions (i.e., reaction temperature and time, catalyst dosage, H₂O₂/DBT (O/S) molar ratio) were also systematic investigated. Under the optimal reaction condition, MoO_x@CN catalyst exhibited highly excellent ODS performance toward DBT, the highest sulfur removal efficiency can be up to 99.9% and sulfur content was wiped out from 800 ppm to 10 ppm. Due to the robust 3D structure promoting rapid transfer, in addition to the increased number of active sites induced by the Mo vacancies, the catalyst, prepared using chitosan and ammonium heptamolybdate in a mass ratio of 1:0.5, displayed rapid kinetics and low activation energy in the oxidation of dibenzothiophene. Moreover, it exhibited excellent recyclability after five cycles without any obvious decrease in catalytic activity for the oxidative desulfurization reaction.
- Oxidation desulfurization,
- Carbon-nitrogen confined MoO_x,
- Mo vacancies,
- Dibenzothiophene,
- Nanoparticles
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Macroporous 3D carbon-nitrogen (CN) confined MoOx catalyst for enhanced oxidative desulfurization of dibenzothiophene

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通讯作者: 陈斌, bchen63@163.com

Macroporous 3D carbon-nitrogen (CN) confined MoO_x catalyst for enhanced oxidative desulfurization of dibenzothiophene