Citation: Xiaokang Li, Jianqiao Li, Chunyu Ma, Chen Chen, Siqi Zhang, Bin Tu, Wubiao Duan, Qingdao Zeng. Selective adsorption behaviors of guest molecules COR in the hexamer host networks at liquid/solid interface[J]. Chinese Chemical Letters, ;2021, 32(3): 1077-1080. doi: 10.1016/j.cclet.2020.07.049 shu

Selective adsorption behaviors of guest molecules COR in the hexamer host networks at liquid/solid interface

Xiaokang Li ^{a, b} ,
Jianqiao Li ^{a, b} ,
Chunyu Ma ^{a, b} ,
Chen Chen ^{a, b} ,
Siqi Zhang ^{a, b} ,
Bin Tu ^{a, *,} ,
Wubiao Duan ^{b, **,} ,
Qingdao Zeng ^{a, c, *,}

a.
CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology (NCNST), Beijing 100190, China
b.
Department of Chemistry, School of Science, Beijing Jiaotong University, Beijing 100044, China
c.
Center of Materials Science and Optoelectonics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

^**

Received Date: 1 June 2020
Revised Date: 22 July 2020
Accepted Date: 27 July 2020
Available Online: 29 July 2020

Figures(4)

Here, the selective adsorption behaviors of guest molecule COR in two hexamer host grids were investigated by means of scanning tunnelling microscope (STM). The assembled structures of small functional organic molecules TTBTA and TATBA were thermodynamically stable. Interestingly, the introduction of the guest molecule COR destroyed the original hexamer structure of TTBTA and combined with it to form a new triangular host-guest system. Different from TTBTA, the introduction of the guest molecule COR did not affect the six-membered ring structure of TATBA. Furthermore, the co-assembly structure of TTBTA/TATBA/COR was established and the guest molecule COR showed preferential adsorption to the TATBA host grid. Density functional theory (DFT) calculations had been performed to disclose the mechanism of the involved assemblies.
- Scanning probemicroscopy (STM),
- Selective adsorption,
- Host-guest chemistry,
- Supramolecular chemistry,
- Aromatic carboxylic acid
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