Citation: Qin Li, Jin Niu, Meiling Dou, Zhengping Zhang, Feng Wang. Porous microtubes of nickel-cobalt double oxides as non-enzymatic hydrogen peroxide sensors[J]. Chinese Chemical Letters, ;2021, 32(3): 1181-1185. doi: 10.1016/j.cclet.2020.07.045 shu

Porous microtubes of nickel-cobalt double oxides as non-enzymatic hydrogen peroxide sensors

Qin Li ^{a, b} ,
Jin Niu ^{a, b} ,
Meiling Dou ^{a, b} ,
Zhengping Zhang ^{a, b, *,} ,
Feng Wang ^{a, b, *,}

a.
State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China
b.
Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

zhangzhengping@mail.buct.edu.cn

wangf@mail.buct.edu.cn

Received Date: 15 May 2020
Revised Date: 10 June 2020
Accepted Date: 26 July 2020
Available Online: 29 July 2020

Figures(5)

Non-enzymatic electrochemical sensors for the determination of hydrogen peroxide (H₂O₂) have attracted more and more concerns. A series of nickel and cobalt double oxides (Ni_xCo_y-DO) with the different ratios of Ni/Co have been prepared by a polyol-mediated solvothermal method for H₂O₂ detection. The obtained products exhibit honeycomb-like open porous microtubes constituted with the low-dimensional nanostructured Ni_xCo_y-DO blocks after the calcination treatment. Compared with nickel oxides, the introduced Co ions in Ni_xCo_y-DO can induce the production of surficial oxygen vacancies, and further enhance the electrode surface activity. In particular, the NiCo-DO sample (with an atomic ratio of Ni/Co = 4:3) shows the richest surficial oxygen vacancies and presents the highest H₂O₂ detection activity among all the as-prepared samples, demonstrating an excellent sensitivity of 698.60 μA L mmol^-1 cm^-2 (0 ~ 0.4 mmol/L), low detection limit (0.28 μmol/L, S/N = 3), as well as long stability, high selectivity and good reproducibility. This work lends a new impetus to the potential application of double metal oxides for the next generation of non-enzymatic sensors.
- Double metal oxides,
- Porous microtubes,
- Oxygen vacancies,
- Hydrogen peroxide detection,
- Electrochemical sensors
1. [1]
  W. Liu, C.J. Lei, H.X. Zhang, et al., Chin. Chem. Lett. 28(2017) 1306-1311. doi: 10.1016/j.cclet.2017.04.032
2. [2]
  H.Y. Liu, H. Ma, H.H. Xu, et al., Anal. Bioanal. Chem. 411(2019) 129-137. doi: 10.1007/s00216-018-1423-x
3. [3]
  M. Zhang, Z.Z. Huang, G.Y. Zhou, et al., Anal. Method 7(2015) 8439-8444. doi: 10.1039/C5AY01399B
4. [4]
  Y.G. Qin, Y.J. Sun, Y.J. Li, et al., Chin. Chem. Lett. 31(2020) 774-778. doi: 10.1016/j.cclet.2019.09.016
5. [5]
  K.L. Wu, B.C. Yang, X.X. Zhu, et al., New J. Chem. 42(2018) 18749-18758. doi: 10.1039/C8NJ04647F
6. [6]
  F. Vetr, Z. Moradi-Shoeili, S. Özkar, Appl. Organometal. Chem. 32(2018) 1-10. doi: 10.1016/j.inoche.2018.10.024
7. [7]
  A.S. Ivanova, A.D. Merkuleva, S.V. Andreev, K.A. Sakharov, Food Chem. 283(2019) 431-436. doi: 10.1016/j.foodchem.2019.01.051
8. [8]
  R.C. Matos, E.O. Coelho, C.F. Souza, F.A. Guedes, M.A.C. Matos, Talanta 69(2006) 1208-1214. doi: 10.1016/j.talanta.2005.12.044
9. [9]
  J.W. Nai, S.Q. Wang, Y. Bai, L. Guo, Small 9(2013) 3147-3152. doi: 10.1002/smll.201203076
10. [10]
  X.B. Lu, G.F. Zou, J.H. Li, et al., J. Mater. Chem. 17(2007) 1427-1432. doi: 10.1039/b615467k
11. [11]
  T. Xiao, J.S. Huang, D.W. Wang, T. Meng, X. Yang, Talanta 206(2020) 120210. doi: 10.1016/j.talanta.2019.120210
12. [12]
  Z.H. Wen, S.Q. Ci, J.H. Li, J. Phys. Chem. C 113(2009) 13482-13487. doi: 10.1021/jp902830z
13. [13]
  W. Chen, S. Cai, Q.Q. Ren, W. Wen, Y.D. Zhao, Analyst 137(2012) 49-58. doi: 10.1039/C1AN15738H
14. [14]
  S. Daemi, S. Ghasemi, A. Akbar Ashkarran, J. Colloid Interface Sci. 550(2019) 180-189. doi: 10.1016/j.jcis.2019.04.091
15. [15]
  A.M. Fekry, M. Shehata, S.M. Azab, A. Walcarius, Sens. Actuator B-Chem. 302(2020) 1-11.
16. [16]
  Y. Shu, Y. Yan, J.Y. Chen, et al., ACS Appl. Mater. Interfaces 9(2017) 22342-22349. doi: 10.1021/acsami.7b07501
17. [17]
  P. Salazar, V. Rico, A.R. González-Elipe, Electrochim. Acta 235(2017) 534-542. doi: 10.1016/j.electacta.2017.03.087
18. [18]
  Z.Y. Yu, H.J. Li, X.M. Zhang, N.K. Liu, X. Zhang, Talanta 144(2015) 1-5. doi: 10.1016/j.talanta.2015.05.070
19. [19]
  W. Liu, H.X. Zhang, B. Yang, et al., Electroanal Chem. 749(2015) 62-67. doi: 10.1016/j.jelechem.2015.04.037
20. [20]
  A.A. Ezhilarasi, J.J. Vijaya, K. Kaviyarasu, et al., J. Photochem. Photobiol. B 164(2016) 352-360. doi: 10.1016/j.jphotobiol.2016.10.003
21. [21]
  S. Veeralingam, S. Priya, S. Badhulika, Chem. Eng. J. 389(2020) 124415. doi: 10.1016/j.cej.2020.124415
22. [22]
  H. Zhang, S. Liu, Sens. Actuator. B: Chem. 238(2017) 788-794. doi: 10.1016/j.snb.2016.07.126
23. [23]
  L.Y. Yan, X.F. Wang, Q.T. Li, et al., Croat. Chem. Acta 89(2016) 331-337.
24. [24]
  Y. Zhou, X. Ni, Z. Ren, et al., RSC Adv. 7(2017) 45177-45184. doi: 10.1039/C7RA07582K
25. [25]
  X.Y. Zhao, J. Meng, Z.H. Yan, F.G. Cheng, J. Chen, Chin. Chem. Lett. 30(2019) 319-323. doi: 10.1016/j.cclet.2018.03.035
26. [26]
  T. Cai, J. Yuan, L. Zhang, et al., Catal. Sci. Technol. 8(2018) 5416-5427. doi: 10.1039/C8CY01062E
27. [27]
  Y.X. Bao, P. Liu, J.X. Zhang, et al., J. Am. Ceram. Soc. (2020) 1-10.
28. [28]
  X.Y. Liu, Y.Q. Zhang, X.H. Xia, et al., J. Power Sources 239(2013) 157-163. doi: 10.1016/j.jpowsour.2013.03.106
29. [29]
  Y.N. Li, T. Wu, K.D. Jiang, et al., J. Mater. Chem. C 4(2016) 7119-7129. doi: 10.1039/C6TC01900E
30. [30]
  B. Liu, S.H. Yu, L.J. Li, et al., Angew. Chem. Int. Ed. 43(2004) 4745-4750. doi: 10.1002/anie.200460090
31. [31]
  P. Zhou, Y.Y. Wang, C. Xie, et al., ChemComm. 53(2017) 11778-11781.
32. [32]
  S.R. Chen, M. Xue, Y.Q. Li, et al., J. Mater. Chem. A 3(2015) 20145-20152. doi: 10.1039/C5TA02557E
33. [33]
  C.X. Huang, Y.H. Ding, C. Hao, et al., Chem. Eng. J. 378(2019) 122202. doi: 10.1016/j.cej.2019.122202
34. [34]
  Q. Li, W.B. Gao, X.P. Zhang, et al., RSC Adv. 8(2018) 13401-13407. doi: 10.1039/C8RA01313F
35. [35]
  A. Alshahrie, Superlattice. Microst. 96(2016) 75-81. doi: 10.1016/j.spmi.2016.05.022
36. [36]
  Z.J. Liu, Z.H. Xiao, G. Luo, et al., Small 15(2019) 1904903. doi: 10.1002/smll.201904903
37. [37]
  J.W. Nai, H.J. Yin, T.T. You, et al., Adv. Energy Mater. 5(2015) 1401880. doi: 10.1002/aenm.201401880
38. [38]
  T.H. Lim, S.J. Cho, H.S. Yang, M.H. Engelhard, D.H. Kim, Appl. Catal. A-Gen. 505(2015) 62-69. doi: 10.1016/j.apcata.2015.07.040
39. [39]
  D.D. Wang, Z.X. Cuo, S.D. Li, M. Zhang, Y.F. Chen, CrystEngComm 22(2020) 2371-2379. doi: 10.1039/D0CE00095G
40. [40]
  Z.P. Zhang, Y.S. Qin, M.L. Dou, Nano Energy 30(2016) 426-433. doi: 10.1016/j.nanoen.2016.10.035
41. [41]
  N.H. Al-Hardan, M.A. Abdul Hamid, R. Shamsudin, N.K. Othman, L.K. Keng, Sensors 16(2016) 1-8. doi: 10.1109/JSEN.2016.2616227
42. [42]
  D.Z. Chen, D. Pang, S.P. Zhang, et al., Electrochim. Acta 330(2020) 1-11.
1. [1]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
2. [2]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
3. [3]
  Chenghao Liu , Xiaofeng Lin , Jing Liao , Min Yang , Min Jiang , Yue Huang , Zhizhi Du , Lina Chen , Sanjun Fan , Qitong Huang . Carbon dots-based dopamine sensors: Recent advances and challenges. Chinese Chemical Letters, 2024, 35(12): 109598-. doi: 10.1016/j.cclet.2024.109598
4. [4]
  Jincheng Zhang , Mengjie Sun , Jiali Ren , Rui Zhang , Min Ma , Qingzhong Xue , Jian Tian . Oxygen vacancies-rich molybdenum tungsten oxide nanowires as a highly active nitrogen fixation electrocatalyst. Chinese Chemical Letters, 2025, 36(1): 110491-. doi: 10.1016/j.cclet.2024.110491
5. [5]
  Huizhong Wu , Ruiheng Liang , Ge Song , Zhongzheng Hu , Xuyang Zhang , Minghua Zhou . Enhanced interfacial charge transfer on Bi metal@defective Bi₂Sn₂O₇ quantum dots towards improved full-spectrum photocatalysis: A combined experimental and theoretical investigation. Chinese Chemical Letters, 2024, 35(6): 109131-. doi: 10.1016/j.cclet.2023.109131
6. [6]
  Mengxiang Zhu , Tao Ding , Yunzhang Li , Yuanjie Peng , Ruiping Liu , Quan Zou , Leilei Yang , Shenglei Sun , Pin Zhou , Guosheng Shi , Dongting Yue . Graphene controlled solid-state growth of oxygen vacancies riched V₂O₅ catalyst to highly activate Fenton-like reaction. Chinese Chemical Letters, 2024, 35(12): 109833-. doi: 10.1016/j.cclet.2024.109833
7. [7]
  Jianing He , Xiao Wang , Zijian Wang , Ruize Jiang , Ke Wang , Rui Zhang , Huilin Wang , Baokang Geng , Hongyi Gao , Shuyan Song , Hongjie Zhang . Investigation on Cu promotion effect on Ce-based solid solution-anchored Rh single atoms for three-way catalysis. Chinese Chemical Letters, 2025, 36(2): 109640-. doi: 10.1016/j.cclet.2024.109640
8. [8]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
9. [9]
  Jie Zhou , Chuanxiang Zhang , Changchun Hu , Shuo Li , Yuan Liu , Zhu Chen , Song Li , Hui Chen , Rokayya Sami , Yan Deng . Electrochemical aptasensor based on black phosphorus-porous graphene nanocomposites for high-performance detection of Hg²⁺. Chinese Chemical Letters, 2024, 35(11): 109561-. doi: 10.1016/j.cclet.2024.109561
10. [10]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
11. [11]
  Bei Li , Zhaoke Zheng . In situ monitoring of the spatial distribution of oxygen vacancies at the single-particle level. Chinese Journal of Structural Chemistry, 2024, 43(10): 100331-100331. doi: 10.1016/j.cjsc.2024.100331
12. [12]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
13. [13]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
14. [14]
  Zhipeng Wan , Hao Xu , Peng Wu . Selective oxidation using in-situ generated hydrogen peroxide over titanosilicates. Chinese Journal of Structural Chemistry, 2024, 43(6): 100298-100298. doi: 10.1016/j.cjsc.2024.100298
15. [15]
  Peng Zhou , Ziang Jiang , Yang Li , Peng Xiao , Feixiang Wu . Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance. Chinese Chemical Letters, 2024, 35(8): 109467-. doi: 10.1016/j.cclet.2023.109467
16. [16]
  Yi Zhou , Yanzhen Liu , Yani Yan , Zonglin Yi , Yongfeng Li , Cheng-Meng Chen . Enhanced oxygen reduction reaction on La-Fe bimetal in porous N-doped carbon dodecahedra with CNTs wrapping. Chinese Chemical Letters, 2025, 36(1): 109569-. doi: 10.1016/j.cclet.2024.109569
17. [17]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
18. [18]
  Fabrice Nelly Habarugira , Ducheng Yao , Wei Miao , Chengcheng Chu , Zhong Chen , Shun Mao . Synergy of sodium doping and nitrogen defects in carbon nitride for promoted photocatalytic synthesis of hydrogen peroxide. Chinese Chemical Letters, 2024, 35(8): 109886-. doi: 10.1016/j.cclet.2024.109886
19. [19]
  Tiantian Li , Ruochen Jin , Bin Wu , Dongming Lan , Yunjian Ma , Yonghua Wang . A novel insight of enhancing the hydrogen peroxide tolerance of unspecific peroxygenase from Daldinia caldariorum based on structure. Chinese Chemical Letters, 2024, 35(4): 108701-. doi: 10.1016/j.cclet.2023.108701
20. [20]
  Mengyuan Li , Xitong Ren , Yanmei Gao , Mengyao Mu , Shiping Zhu , Shufang Tian , Minghua Lu . Constructing bifunctional magnetic porous poly(divinylbenzene) polymer for high-efficient removal and sensitive detection of bisphenols. Chinese Chemical Letters, 2024, 35(12): 109699-. doi: 10.1016/j.cclet.2024.109699

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(858)
HTML views(137)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142