Citation: Guangrui Si, Xiangjing Kong, Tao He, Wei Wu, Linhua Xie, Jianrong Li. A stable Co(II)-based metal-organic framework with dual-functional pyrazolate-carboxylate ligand: Construction and CO₂ selective adsorption and fixation[J]. Chinese Chemical Letters, ;2021, 32(2): 918-922. doi: 10.1016/j.cclet.2020.07.023 shu

A stable Co(II)-based metal-organic framework with dual-functional pyrazolate-carboxylate ligand: Construction and CO₂ selective adsorption and fixation

Beijing Key Laboratory for Green Catalysis and Separation and Department of Environmental Chemical Engineering, Beijing University of Technology, Beijing 100124, China

jrli@bjut.edu.cn

Received Date: 9 June 2020
Revised Date: 9 July 2020
Accepted Date: 13 July 2020
Available Online: 15 July 2020

Figures(3)

By taking the functional advantages of both pyrazolate and carboxylate ligands, a unique dual-functional pyrazolate-carboxylate ligand acid, 4-(3,6-di(pyrazol-4-yl)-9-carbazol-9-yl)benzoic acid (H₃PCBA) was designed and synthesized. Using it, a new Co(II)-based metal-organic framework (MOF), Co₃(PCBA)₂(H₂O)₂ (BUT-75) has been constructed. It revealed a (3,6)-connected net based on the 6-connected linear trinuclear metal node, and showed good chemical stability in a wide pH range from 3 to 12 at room temperature, as well as in boiling water. Due to the presence of rich exposed Co(II) sites in pores, BUT-75 presented high selective CO₂ adsorption capacity over N₂ at 298 K. Simultaneously, it demonstrated fine catalytic performance for the cycloaddition of CO₂ with epoxides into cyclic carbonates under ambient conditions. This work has not only enriched the MOF community through integrating diverse functionalities into one ligand but also contributed a versatile platform for CO₂ fixation, thereby pushing MOF chemistry forward by stability enhancement and application expansion.
- Metal-organic framework (MOF),
- Pyrazolate-carboxylate ligand,
- Construction,
- CO₂ selective adsorption,
- CO₂ fixation
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A stable Co(II)-based metal-organic framework with dual-functional pyrazolate-carboxylate ligand: Construction and CO2 selective adsorption and fixation

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通讯作者: 陈斌, bchen63@163.com

A stable Co(II)-based metal-organic framework with dual-functional pyrazolate-carboxylate ligand: Construction and CO₂ selective adsorption and fixation