Citation: He Wenjie, Wu Xingxing, Li Yifei, Xiong Jing, Tang Zhiling, Wei Yuechang, Zhao Zhen, Zhang Xiao, Liu Jian. Z-scheme heterojunction of SnS₂-decorated 3DOM-SrTiO₃ for selectively photocatalytic CO₂ reduction into CH₄[J]. Chinese Chemical Letters, ;2020, 31(10): 2774-2778. doi: 10.1016/j.cclet.2020.07.019 shu

Z-scheme heterojunction of SnS₂-decorated 3DOM-SrTiO₃ for selectively photocatalytic CO₂ reduction into CH₄

He Wenjie ^a,b ,
Wu Xingxing ^a ,
Li Yifei ^a,b ,
Xiong Jing ^a,b ,
Tang Zhiling ^a,b ,
Wei Yuechang ^a,b,*, ,
Zhao Zhen ^a ,
Zhang Xiao ^a ,
Liu Jian ^a

a.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
b.
Key Laboratory of Optical Detection Technology for Oil and Gas, China University of Petroleum, Beijing 102249, China

weiyc@cup.edu.cn

Received Date: 11 May 2020
Revised Date: 22 June 2020
Accepted Date: 8 July 2020
Available Online: 9 July 2020

Figures(4)

The rapid recombination of photoinduced electron-hole pairs as well as the deficiency of high-energy carriers restricted the redox ability and products selectivity. Herein, the heterojunction of SnS₂-decorated three-dimensional ordered macropores (3DOM)-SrTiO₃ catalysts were in-situ constructed to provide transmit channel for high-energy electron transmission. The suitable band edges of SnS₂ and SrTiO₃ contribute to the Z-scheme transfer of photogenerated carrier. The 3DOM structure of SrTiO₃-based catalyst possesses the slow light effect for enhancing light adsorption efficiency, and the surface alkalis strontium is benefit to the boosting adsorption for CO₂. The in-situ introduced SnS₂ decorated on the macroporous wall surface of 3DOM-SrTiO₃ altered the primary product from CO to CH₄. The Z-scheme electron transfer from SnS₂ combining with the holes in SrTiO₃ occurred under full spectrum photoexcitation, which improved the excitation and utilization of photogenerated electrons for CO₂ multi-electrons reduction. As a result, (SnS₂)₃/3DOM-SrTiO₃ catalyst exhibits higher activity for photocatalytic CO₂ reduction to CH₄ compared with single SnS₂ or 3DOM-SrTiO₃, i.e., its yield and selectivity of CH₄ are 12.5 μmol g^-1 h^-1 and 74.9%, respectively. The present work proposed the theoretical foundation of Z-scheme heterojunction construction for enhancing photocatalytic activity and selectivity for CO₂ conversion.
- 3DOM-SrTiO₃,
- SnS₂,
- Z-scheme heterojunction,
- CO₂ conversion,
- CH₄ selectivity
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Z-scheme heterojunction of SnS2-decorated 3DOM-SrTiO3 for selectively photocatalytic CO2 reduction into CH4

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Z-scheme heterojunction of SnS₂-decorated 3DOM-SrTiO₃ for selectively photocatalytic CO₂ reduction into CH₄