Citation: Miao Yang, Qiuli Ning, Chaoying Fan, Xinglong Wu. Large-scale Ni-MOF derived Ni₃S₂ nanocrystals embedded in N-doped porous carbon nanoparticles for high-rate Na⁺ storage[J]. Chinese Chemical Letters, ;2021, 32(2): 895-899. doi: 10.1016/j.cclet.2020.07.014 shu

Large-scale Ni-MOF derived Ni₃S₂ nanocrystals embedded in N-doped porous carbon nanoparticles for high-rate Na⁺ storage

Miao Yang ^{a, 1} ,
Qiuli Ning ^{a, 1} ,
Chaoying Fan ^{b, *,} ,
Xinglong Wu ^{a, b, *,}

a.
National & Local United Engineering Lab for Power Battery, Department of Chemistry, Northeast Normal University, Changchun 130024, China
b.
Key Laboratory for UV Light-Emitting Materials and Technology of Ministry of Education, Northeast Normal University, Changchun 130024, China

fancy242@nenu.edu.cn

xinglong@nenu.edu.cn

Received Date: 14 June 2020
Revised Date: 5 July 2020
Accepted Date: 7 July 2020
Available Online: 7 July 2020

Figures(4)

Metal organic framework (MOF) has been confirmed as the promising precursor to develop the conversion-typed anode materials of sodium-ion batteries (SIBs) because of the tunable structure design and simple functional modification. Here, we prepare the ultrasmall Ni₃S₂ nanocrystals embedded into N-doped porous carbon nanoparticles using the scalable Ni-MOF as precursor (denoted as Ni₃S₂@NPC). The ultrasmall size of Ni₃S₂ can work for accelerated electron/ion transfer to facilitate the electrochemical reaction kinetics. Moreover, the robust conductivity network originated from N-doped porous carbon nanoparticles can not only improve the electron conductivity, but also enhance the electrode integrity and stability of the electrode/electrolyte interface. In addition, the N heteroatoms provide extra Na storage sites. Accordingly, the electrode delivers the obviously competitive capacities and high-power output with respect to the currently reported Ni₃S₂/C composites. This study provides a scalable and universal strategy to develop the advanced transition metal sulfides for practically feasible SIBs.
- Sodium-ion batteries,
- Metal organic framework,
- Large-scale preparation,
- Ni₃S₂ nanocrystals,
- N-doped porous carbon
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Large-scale Ni-MOF derived Ni3S2 nanocrystals embedded in N-doped porous carbon nanoparticles for high-rate Na+ storage

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通讯作者: 陈斌, bchen63@163.com

Large-scale Ni-MOF derived Ni₃S₂ nanocrystals embedded in N-doped porous carbon nanoparticles for high-rate Na⁺ storage