Citation: Xiong Sun, Congqing Zhu. Synthesis, characterization and reactivity of a neutral antimony(III) complex[J]. Chinese Chemical Letters, ;2021, 32(2): 717-720. doi: 10.1016/j.cclet.2020.07.006 shu

Synthesis, characterization and reactivity of a neutral antimony(III) complex

Xiong Sun ,
Congqing Zhu ^*,

State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

zcq@nju.edu.cn

Received Date: 18 May 2020
Revised Date: 29 June 2020
Accepted Date: 4 July 2020
Available Online: 4 July 2020

Figures(8)

Pincer complexes are widely used in organometallic and coordination chemistry. The role of antimony as a central donor atom in pincer ligands has been extensively explored in recent years. Although phenylenediamine derived PXP (X = B, Al, C, Si, Ge, Sn, N) type ligands exhibit diverse reactivity, analogues species based on antimony have been reported less frequently. Herein, we report a new PSbP complex and evaluate its reactivity. These species will broaden the family of phenylenediamine derived pincer complexes.
- Pincer ligand,
- Antimony,
- Phenylenediamine,
- Coordination
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