Citation: Yu Liang, Chenhui Li, Lanjun Chen, Jia Huo, Mohammed Loubidi, Yangyang Zhou, Yanbo Liu. Microwave-assisted acid-induced formation of linker vacancies within Zr-based metal organic frameworks with enhanced heterogeneous catalysis[J]. Chinese Chemical Letters, ;2021, 32(2): 787-790. doi: 10.1016/j.cclet.2020.06.042 shu

Microwave-assisted acid-induced formation of linker vacancies within Zr-based metal organic frameworks with enhanced heterogeneous catalysis

Yu Liang ^a ,
Chenhui Li ^a ,
Lanjun Chen ^a ,
Jia Huo ^{a, b, *,} ,
Mohammed Loubidi ^a ,
Yangyang Zhou ^a ,
Yanbo Liu ^a

a.
State Key Laboratory of Chem/Bio-sensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
b.
Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, Hunan University of Science and Technology, Xiangtan 411201, China

jiahuo@hnu.edu.cn

Received Date: 8 April 2020
Revised Date: 11 June 2020
Accepted Date: 30 June 2020
Available Online: 1 July 2020

Figures(4)

Herein, we report a microwave-assisted acid-induced post-treatment method for the formation of linker vacancies within Zr-based metal organic frameworks (Zr-MOFs). The number of linker vacancies can be easily regulated with this method by changing the concentration of the HCl solution and the duration of microwave irradiation. The optimized defective UiO-66 showed higher linker defects with a higher specific surface area and thermal stability. The results of the catalytic cyclization of citronella showed that the Zr-MOFs with more defects exhibited enhanced catalytic performance. This work may provide a new method for the creation of defective MOFs with high activity and stability.
- Metal-organic frameworks,
- Microwave,
- Acid etching,
- Linker vacancy,
- Stability,
- Heterogeneous catalysis
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