Citation: Huang Mingjie, Xiang Wei, Wang Chen, Zhou Tao, Mao Juan, Wu Xiaohui, Zhang Fugang, Li Dan, Lu Xiejuan. Ultrafast O₂ activation by copper oxide for 2, 4-dichlorophenol degradation: The size-dependent surface reactivity[J]. Chinese Chemical Letters, ;2020, 31(10): 2769-2773. doi: 10.1016/j.cclet.2020.06.040 shu

Ultrafast O₂ activation by copper oxide for 2, 4-dichlorophenol degradation: The size-dependent surface reactivity

Huang Mingjie ^a ,
Xiang Wei ^a,b ,
Wang Chen ^a,b ,
Zhou Tao ^a,*, ,
Mao Juan ^a,b ,
Wu Xiaohui ^a,b ,
Zhang Fugang ^c ,
Li Dan ^c ,
Lu Xiejuan ^a,b,*,

a.
School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.
Key Laboratory of Water and Wastewater Treatment(HUST), MOHURD, Wuhan 430074, China
c.
Three Gorges Base Development Co. Ltd., Yichang 443002, China

zhoutao@hust.edu.cn

xiejuan_lu@hust.edu.cn

Received Date: 15 May 2020
Revised Date: 18 June 2020
Accepted Date: 29 June 2020
Available Online: 30 June 2020

Figures(5)

This study demonstrated interesting ultrafast activation of molecular O₂ by copper oxide (CuO) particles and very rapid elimination of aqueous 2, 4-dichlorophenol (2, 4-DCP) within reaction time of 30 s. Electron paramagnetic resonance (EPR) characterization indicated that ^·OH, Cu³⁺, ¹O₂ and O₂^·- were generated in the CuO/O₂ systems, wherein O₂^·- would be the main reactive species responsible for 2, 4-DCP degradation. It was further found that the catalytic ability of CuO for O₂ activation was highly size dependent and nano-CuO was far reactive than micro-CuO. H₂ temperature-programmed reduction (H₂-TPR), X-ray photoelectron spectroscopy (XPS) and vibrating sample magnetometer (VSM) analyses revealed that both the quantity and the reactivity of the surface reaction sites (surface Cu⁺ and O₂) could determine the catalytic ability of CuO affecting efficient Cu⁺-based molecular oxygen activation. Moreover, the O₂ activation ability of CuO would depend on not only the dimension, but also crystalline factors, for example, the exposed facets.
- Copper oxide,
- O₂ activation,
- 2, 4-Dichlorophenol,
- Size-dependent,
- Surface reactivity
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ultrafast O2 activation by copper oxide for 2, 4-dichlorophenol degradation: The size-dependent surface reactivity

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通讯作者: 陈斌, bchen63@163.com

Ultrafast O₂ activation by copper oxide for 2, 4-dichlorophenol degradation: The size-dependent surface reactivity