Citation: Li Zhang, Dandan Wu, Gaowei Wang, Yongtai Xu, Hongxia Li, Xingbin Yan. An aqueous zinc-ion hybrid super-capacitor for achieving ultrahigh-volumetric energy density[J]. Chinese Chemical Letters, ;2021, 32(2): 926-931. doi: 10.1016/j.cclet.2020.06.037 shu

An aqueous zinc-ion hybrid super-capacitor for achieving ultrahigh-volumetric energy density

Li Zhang ^{a, b, *,} ,
Dandan Wu ^{a, b, 1} ,
Gaowei Wang ^{a, b} ,
Yongtai Xu ^{b, c} ,
Hongxia Li ^d ,
Xingbin Yan ^{b, e, *,}

a.
Department of Physics, School of Science, Lanzhou University of Technology, Lanzhou 730050, China
b.
Laboratory of Clean Energy Chemistry and Materials, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
c.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100080, China
d.
School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China
e.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116000, China

zhangli@lut.edu.cn

xbyan@licp.cas.cn

Received Date: 22 April 2020
Revised Date: 9 June 2020
Accepted Date: 28 June 2020
Available Online: 29 June 2020

Figures(4)

Zinc-ion hybrid super-capacitors are regarded as promising safe energy storage systems. However, the relatively low volumetric energy density has become the main bottlenecks in practical applications of portable electronic devices. In this work, the zinc-ion hybrid super-capacitor with high volumetric energy density and superb cycle stability had been constructed which employing the high-density three-dimensional graphene hydrogel as cathode and Zn foil used as anode in 1 mol/L ZnSO₄ electrolyte. Benefiting from the abundant ion transport paths and the abundant active sites for graphene hydrogel with high density and porous structure, the zinc-ion hybrid super-capacitor exhibited an extremely high volumetric energy density of 118.42 Wh/L and a superb power density of 24.00 kW/L, as well as an excellent long cycle life (80% retention after 30,000 cycles at 10 A/g), which was superior to the volumetric energy density of the reported zinc-ion hybrid super-capacitors. This device, based on the fast ion adsorption/desorption on the capacitor-type graphene cathode and reversible Zn²⁺ plating/stripping on the battery-type Zn anode, which will inspire the development of zinc-ion hybrid super-capacitor in miniaturized devices.
- Zinc-ion hybrid super-capacitors,
- Volumetric energy density,
- Dense three-dimensional grapheme,
- Ultralong cycle stability,
- Energy storage mechanism
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