Citation: Siyun Zhang, Imene Boussouar, Haibing Li. Selective sensing and transport in bionic nanochannel based on macrocyclic host-guest chemistry[J]. Chinese Chemical Letters, ;2021, 32(2): 642-648. doi: 10.1016/j.cclet.2020.06.035 shu

Selective sensing and transport in bionic nanochannel based on macrocyclic host-guest chemistry

Key Laboratory of Pesticide and Chemical Biology (CCNU), Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China

Author Bio: Siyun Zhang is currently a PhD candidate at the Department of Chemistry at Central China Normal University. Her current scientific interest is focused on the fabrication of supermolecular-functionalized nano-channels, and their application on chiral separation.
Imene Boussouar earned her PhD degree at the Department of Chemistry at Central China Normal University in 2016. Her research interest focuses on the design and fabrication of supermolecular-functionalized nanochannels.
Haibing Li received PhD from Department of Chemistry and Molecular Science at Wuhan University. After one-year post doctoral fellowship at CNRS, French in 2003, he backed China to work at Huazhong University of Science and Technology. In 2006, he moved to Central China Normal University in Wuhan as a professor. In 2015, he visited University of Utah for half a year. His research interest focuses on supramolecular chemistry on surfaces. To date, his research records 130 scientific publications and 10 domestic and international patents.

lhbing@mail.ccnu.edu.cn

Received Date: 1 June 2020
Revised Date: 13 June 2020
Accepted Date: 24 June 2020
Available Online: 25 June 2020

Figures(8)

Imitating the signal transduction and transmembrane transport controlled by biological channels in the cell membrane, artificial nanochannels with a similar capability of sensing and transport are constructed as bionic nanochannels. To accomplish selective sensing and transport of biological analyte (as "guest"), the bionic nanochannels are modified with the artificial receptor (as "host"). Based on selective recognition between host and guest, bionic nanochannels translate the stimulus of the guest to electrochemical signal as sensors, and further regulate the transmission of guest as transporters. However, throughout all kinds of guests, the selective sensing and transport of ions and chiral molecules is a challenging problem. And throughout all hosts of ions and chiral molecules, the macrocyclic hosts with multisite of recognition show better selectivity, such as crown ethers, cyclodextrins, calixarenes, and pillararenes. In this article, we highlight recent advances in the macrocyclic host-based nanochannels for the selective sensing and transport of ionic and chiral guests, summarize the similarities and differences of different kinds of macrocyclic host-based nanochannels, and expect the research direction and application prospect.
- Nanochannel,
- Sensing,
- Transport,
- Macrocyclic host,
- Ionic/chiral guest
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