Citation: Tao Rui, Guo-Ping Lu, Xin Zhao, Xun Cao, Zhong Chen. The synergistic catalysis on Co nanoparticles and CoN_x sites of aniline-modified ZIF derived Co@NCs for oxidative esterification of HMF[J]. Chinese Chemical Letters, ;2021, 32(2): 685-690. doi: 10.1016/j.cclet.2020.06.027 shu

The synergistic catalysis on Co nanoparticles and CoN_x sites of aniline-modified ZIF derived Co@NCs for oxidative esterification of HMF

Tao Rui ^a ,
Guo-Ping Lu ^{a, b, *,} ,
Xin Zhao ^b ,
Xun Cao ^b ,
Zhong Chen ^{b, *,}

a.
School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China
b.
School of Materials Science & Engineering, Nanyang Technological University, Singapore 639798, Singapore

glu@njust.edu.cn

ASZChen@ntu.edu.sg

Received Date: 7 May 2020
Revised Date: 13 June 2020
Accepted Date: 19 June 2020
Available Online: 22 June 2020

Figures(9)

An efficient, sustainable and scalable strategy for the synthesis of porous cobalt/nitrogen co-doped carbons (Co@NCs) via pyrolysis of aniline-modified ZIFs, has been demonstrated. Aniline can coordinate and absorb on the surface of ZIF (ZIF-CoZn3-PhA), accelerate the precipitation of ZIFs, thus resulting in smaller ZIF particle size. Meanwhile, the aniline on the surface of ZIF-CoZn3-PhA promotes the formation of the protective carbon shell and smaller Co nanoparticles, and increases nitrogen content of the catalyst. Because of these properties of Co@NC-PhA-3, the oxidative esterification of 5-hydroxyme-thylfurfural can be carried out under ambient conditions. According to our experimental and computational results, a synergistic catalytic effect between CoN_x sites and Co nanoparticles has been established, in which both Co nanoparticles and CoN_x can activate O₂ while Co nanoparticles bind and oxidize HMF. Moreover, the formation and release of active oxygen species in CoN_x sites are reinforced by the electronic interaction between Co nanoparticles and CoN_x.
- Aniline-modified ZIF,
- Porous cobalt/nitrogen co-doped carbon,
- Synergistic catalysis on CoN_x sites and Co,
- nanoparticles,
- Oxidative esterification,
- 5-Hydroxymethylfurfural
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沈阳化工大学材料科学与工程学院沈阳 110142

The synergistic catalysis on Co nanoparticles and CoNx sites of aniline-modified ZIF derived Co@NCs for oxidative esterification of HMF

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通讯作者: 陈斌, bchen63@163.com

The synergistic catalysis on Co nanoparticles and CoN_x sites of aniline-modified ZIF derived Co@NCs for oxidative esterification of HMF