Citation: Yachao Zhang, Liang-Liang Mao, Sifan Hu, Yi Luan, Huan Cong. Photo-induced anti-Markovnikov hydroalkylation of unactivated alkenes employing a dual-component initiator[J]. Chinese Chemical Letters, ;2021, 32(2): 681-684. doi: 10.1016/j.cclet.2020.06.026 shu

Photo-induced anti-Markovnikov hydroalkylation of unactivated alkenes employing a dual-component initiator

Yachao Zhang ^a ,
Liang-Liang Mao ^b ,
Sifan Hu ^a ,
Yi Luan ^{a, **,} ,
Huan Cong ^{b, c, *,}

a.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
b.
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
c.
School of Future Technology, University of Chinese Academy of Sciences, Beijing 100190, China

^**

yiluan@ustb.edu.cn

hcong@mail.ipc.ac.cn

Received Date: 4 May 2020
Revised Date: 10 June 2020
Accepted Date: 19 June 2020
Available Online: 22 June 2020

Figures(5)

Metal-free anti-Markovnikov hydroalkylation of unactivated alkenes with cyanoacetate has been developed, featuring the use of a dual-component initiator containing an organic photocatalyst and a radical precursor. When combined, the two components can undergo visible light-induced single-electron transfer, and serve as a versatile and effective alkyl radical generator.
- Photocatalysis,
- Anti-Markovnikov,
- Alkene hydroalkylation,
- Single-electron transfer,
- Radical
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