Citation: Xueguo Zhang, Peigen Wang, Liangwei Zhu, Baohua Chen. Rhodium(III)-catalyzed chemodivergent annulations between phenyloxazoles and diazos via C–H activation[J]. Chinese Chemical Letters, ;2021, 32(2): 695-699. doi: 10.1016/j.cclet.2020.06.011 shu

Rhodium(III)-catalyzed chemodivergent annulations between phenyloxazoles and diazos via C–H activation

State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

chbh@lzu.edu.cn

Received Date: 23 April 2020
Revised Date: 30 May 2020
Accepted Date: 8 June 2020
Available Online: 9 June 2020

Figures(6)

Acid-controlled, chemodivergent and redox-neutral annulations for the synthesis of isocoumarins and isoquinolinones have been realized via Rh(III)-catalyzed C—H activation. Diazo compounds act as a carbene precursor, and coupling occurs in one-pot process, where adipic acid and trimethylacetic acid promote chemodivergent cyclizations.
- Rhodium(III)-catalyzed,
- C—H activation,
- Acid-controlled,
- Isocoumarin,
- One-pot process,
- Ring opening/ring closure
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