Citation: Wenxiu Yang, Guoqing Xu, Jingjing Shu, Mozhen Wang, Xuewu Ge. Preparation and adsorption property of novel inverse-opal hierarchical porous N-doped carbon microspheres[J]. Chinese Chemical Letters, ;2021, 32(2): 866-869. doi: 10.1016/j.cclet.2020.06.004 shu

Preparation and adsorption property of novel inverse-opal hierarchical porous N-doped carbon microspheres

CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China

pstwmz@ustc.edu.cn

xwge@ustc.edu.cn

Received Date: 19 April 2020
Revised Date: 5 May 2020
Accepted Date: 2 June 2020
Available Online: 3 June 2020

Figures(3)

The design of pore structure is the key factor for the performance of porous carbon spheres. In this work, novel micron-sized colloidal crystal microspheres consisting of fibrous silica (F-SiO₂) nanoparticles are firstly prepared by water-evaporation-induced self-assembly of F-SiO₂ nanoparticles in the droplets of an inverse emulsion system to be used as sacrificial templates. Acrylonitrile (AN) was infiltrated in the voids of the F-SiO₂ colloidal crystal microspheres, and in-situ induced by ⁶⁰Co γ-ray to polymerize into polyacrylonitrile (PAN). After the PAN-infiltrated F-SiO₂ colloidal crystal microspheres were carbonized and etched with HF solution, novel micron-sized inverse-opal N-doped carbon (IO-NC) microspheres consisting of hollow carbon nanoparticles with a hierarchical macro/meso-porous inner surface were obtained. The IO-NC microspheres have a specific surface area as high as 266.4 m²/g and a molar ratio of C/N of 5. They have a good dispersibility in water, and show a high adsorption capacity towards rhodamine B (RhB) up to 137.28 mg/(g microsphere). This work offers a way to obtain novel micron-sized hierarchical macro/meso-porous N-doped carbon microspheres, which opens a new idea to prepare high-performance hierarchical porous carbon materials.
- Inverse-opal carbon microspheres,
- N doping,
- Colloidal crystal microsphere,
- Fibrous silica nanoparticles,
- Adsorption
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