Citation: Yanwei Cao, Huan Zheng, Gangli Zhu, Haihong Wu, Lin He. Ceria supported Ru⁰-Ru^δ+ clusters as efficient catalyst for arenes hydrogenation[J]. Chinese Chemical Letters, ;2021, 32(2): 770-774. doi: 10.1016/j.cclet.2020.05.045 shu

Ceria supported Ru⁰-Ru^δ+ clusters as efficient catalyst for arenes hydrogenation

Yanwei Cao ^{a, b} ,
Huan Zheng ^{a, b} ,
Gangli Zhu ^{a, *,} ,
Haihong Wu ^{c, *,} ,
Lin He ^{a, *,}

a.
State Key Laboratory for Oxo Synthesis and Selective Oxidation (OSSO), Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences (CAS), Lanzhou 730000, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Henan Province Key Laboratory of New Opto-Electronic Functional Materials, College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, China

zhugl@licp.cas.cn

sailor99600@126.com

helin@licp.cas.cn

Received Date: 27 April 2020
Revised Date: 15 May 2020
Accepted Date: 30 May 2020
Available Online: 1 June 2020

Figures(3)

Selective hydrogenation of aromatic amines, especially chemicals such as aniline and bis(4-aminocyclohexyl)methane for non-yellowing polyurethane, is of particular interests due to the extensive applications. To conquer the existing difficulties in selective hydrogenation, the Ru⁰-Ru^δ+/CeO₂ catalyst with solid frustrated Lewis pairs was developed for aromatic amines hydrogenation with excellent activity and selectivity under relative milder conditions. The morphology, electronic and chemical properties, especially the Ru⁰-Ru^δ+ clusters and reducible ceria were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electronic microscopy (SEM), X-ray photoelectron spectroscopy (XPS), CO₂ temperature programmed desorption (CO₂-TPD), H₂ temperature programmed reduction (H₂-TPR), H₂ diffuse reflectance Fourier transform infrared spectroscopy (H₂-DRIFT), Raman, etc. The 2% Ru/CeO₂ catalyst exhibited good conversion of 95% and selectivity greater than 99% toward cyclohexylamine. The volcano curve describing the activity and Ru state was found. Owning to the "acidic site isolation" by surrounding alkaline sites, condensation between the neighboring amine molecules could be effectively suppressed. The catalyst also showed good stability and applicability for other aromatic amines and heteroarenes containing different functional groups.
- Ceria,
- Ruthenium,
- Clusters,
- Amines,
- Hydrogenation
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通讯作者: 陈斌, bchen63@163.com

Ceria supported Ru⁰-Ru^δ+ clusters as efficient catalyst for arenes hydrogenation