Citation: Yang Bin, Li Longtai, Jia Ziye, Liu Xiping, Zhang Chunjie, Guo Limin. Comparative study of CO₂ hydrogenation to methanol on cubic bixbyite-type and rhombohedral corundum-type indium oxide[J]. Chinese Chemical Letters, ;2020, 31(10): 2627-2633. doi: 10.1016/j.cclet.2020.05.031 shu

Comparative study of CO₂ hydrogenation to methanol on cubic bixbyite-type and rhombohedral corundum-type indium oxide

Yang Bin ^a ,
Li Longtai ^a ,
Jia Ziye ^a ,
Liu Xiping ^b ,
Zhang Chunjie ^b ,
Guo Limin ^a,*,

a.
School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.
Research Institute of Air Purification Equipment, Shanxi Xinhua Chemical Co., LTD, Taiyuan 03008, China

lmguo@hust.edu.cn

Received Date: 15 April 2020
Revised Date: 9 May 2020
Accepted Date: 21 May 2020
Available Online: 23 May 2020

Figures(4)

Hydrogenation of CO₂ to value-added chemicals has attracted much attention all through the world. In₂O₃ with cubic bixbyite-type (denoted as c-In₂O₃) is well known for its high CO₂ hydrogenation activity and CH₃OH selectivity at high temperature. However, the other structure of In₂O₃ with rhombohedral corundum-type (denoted as rh-In₂O₃) rarely been investigated as catalyst. Herein, c-In₂O₃ and rh-In₂O₃ were prepared and comparatively studied for CO₂ hydrogenation. The results indicated that c-In₂O₃ showed higher CO₂ conversion activity than rh-In₂O₃ due to the impressive reducibility and reactivity. Whereas rh-In₂O₃ had higher CH₃OH selectivity due to weaker CH₃OH and stronger CO adsorption on rh-In₂O₃. Although c-In₂O₃ and rh-In₂O₃ catalysts showed different CO₂ hydrogenation performance, in-situ diffuse reflectance infrared Fourier transform spectroscopy showed CO₂ can be reduced to CO through redox cycling and hydrogenation to CH₃OH through formate path.
- CO₂ hydrogenation,
- In₂O₃,
- Methanol,
- Structure effect
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Comparative study of CO2 hydrogenation to methanol on cubic bixbyite-type and rhombohedral corundum-type indium oxide

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通讯作者: 陈斌, bchen63@163.com

Comparative study of CO₂ hydrogenation to methanol on cubic bixbyite-type and rhombohedral corundum-type indium oxide