Citation: Ke Chen, Shaofeng Deng, Yun Lu, Mingxing Gong, Yezhou Hu, Tonghui Zhao, Tao Shen, Deli Wang. Molybdenum-doped titanium dioxide supported low-Pt electrocatalyst for highly efficient and stable hydrogen evolution reaction[J]. Chinese Chemical Letters, ;2021, 32(2): 765-769. doi: 10.1016/j.cclet.2020.05.030 shu

Molybdenum-doped titanium dioxide supported low-Pt electrocatalyst for highly efficient and stable hydrogen evolution reaction

Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

wangdl81125@hust.edu.cn

Received Date: 11 April 2020
Revised Date: 6 May 2020
Accepted Date: 21 May 2020
Available Online: 23 May 2020

Figures(6)

The Platinum (Pt)-based catalysts exhibit excellent catalytic performance for the hydrogen evolution reaction (HER) while suffering from poor stability due to the weak interaction between the carbon support and Pt. Herein, a molybdenum-doped titanium dioxide (Ti_0.9Mo_0.1O₂) supported low-Pt electrocatalyst with stronger interaction between catalyst and support is applied to tune the electrocatalytic performance of Pt. The Ti_0.9Mo_0.1O₂ support can not only tolerate the corrosion environment in the catalytic system, but also generate strong metal-support interaction (SMSI) between the oxide and catalyst. A facile solvothermal method is used to prepare Ti_0.9Mo_0.1O₂ as support to anchor Pt nanoparticles. The 5% Pt supported on Ti_0.9Mo_0.1O₂ catalyst exhibits 4.4-fold mass activity (MA) at an overpotential of 50 mV and higher stability than 20% Pt/C with only 1/4 Pt loading. The SMSI between the Ti_0.9Mo_0.1O₂ and Pt prevents the Pt aggregation to achieve excellent stability, and hydrogen spillover effect in the interface between Pt and support benefits the hydrogen production process. This work presents a novel sight for the fabrication and design of oxide supported catalysts in various catalytic system by reasonably employing support effect.
- Low-Pt electrocatalyst,
- Oxide support,
- Strong metal-support interaction,
- Hydrogen spillover effect,
- Hydrogen evolution reaction
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