Citation: Ruyun Yue, Fang Xia, Ruijuan Qi, Da Tie, Shanshan Shi, Zhiping Li, Yufeng Zhao, Jiujun Zhang. Trace Nb-doped Na_0.7Ni_0.3Co_0.1Mn_0.6O₂ with suppressed voltage decay and enhanced low temperature performance[J]. Chinese Chemical Letters, ;2021, 32(2): 849-853. doi: 10.1016/j.cclet.2020.05.025 shu

Trace Nb-doped Na_0.7Ni_0.3Co_0.1Mn_0.6O₂ with suppressed voltage decay and enhanced low temperature performance

Ruyun Yue ^a ,
Fang Xia ^a ,
Ruijuan Qi ^c ,
Da Tie ^a ,
Shanshan Shi ^{a, b} ,
Zhiping Li ^a ,
Yufeng Zhao ^{a, b, *,} ,
Jiujun Zhang ^b

a.
Key Laboratory of Applied Chemistry, Yanshan University, Qinhuangdao 066004, China
b.
Institute for Sustainable Energy & College of Sciences, Shanghai University, Shanghai 200444, China
c.
Key Laboratory of Polar Materials and Devices (MOE), Department of Optoelectronics, East China Normal University, Shanghai 200241, China

yufengzhao@shu.edu.cn

Received Date: 23 April 2020
Revised Date: 15 May 2020
Accepted Date: 15 May 2020
Available Online: 26 May 2020

Figures(4)

The P2-type manganese-based Na_0.7MnO₂ cathode materials attract great interest due to their high theoretical capacity. However, these materials suffer from rapid capacity fading, poor rate performance and severe voltage decay resulting from phase transition and sluggish reaction kinetics. In this work we report a novel Nb-doped Na_0.7[Ni_0.3Co_0.1Mn_0.6]_1-xNb_xO₂ with significantly suppressed voltage decay and enhanced cycling stability. The strong Nb-O bond can efficiently stabilize the TMO framework, and the as prepared material demonstrates much lower discharge midpoint voltage decay (0.132 V) than that of pristine one (0.319 V) after 200 cycles. Consequently, a remarkably improved cycling performance with a capacity retention of 87.9% after 200 cycle at 0.5 C is achieved, showing a 2.4 fold improvement as compared to the control sample Na_0.7Ni_0.3Co_0.1Mn_0.6O₂ (~37% rotation). Even at 2 C, a capacity retention of 68.4% is retained after 500 cycles. Remarkably, the as prepared material can be applied at low temperature of −20 ℃, showing a capacity retention of 81% as compared to that at room temperature.
- Manganese-based oxides,
- Sodium ion battery,
- Low temperature,
- Voltage decay,
- Cycling stability
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Trace Nb-doped Na0.7Ni0.3Co0.1Mn0.6O2 with suppressed voltage decay and enhanced low temperature performance

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通讯作者: 陈斌, bchen63@163.com

Trace Nb-doped Na_0.7Ni_0.3Co_0.1Mn_0.6O₂ with suppressed voltage decay and enhanced low temperature performance