Citation: Ruyun Yue, Fang Xia, Ruijuan Qi, Da Tie, Shanshan Shi, Zhiping Li, Yufeng Zhao, Jiujun Zhang. Trace Nb-doped Na_0.7Ni_0.3Co_0.1Mn_0.6O₂ with suppressed voltage decay and enhanced low temperature performance[J]. Chinese Chemical Letters, ;2021, 32(2): 849-853. doi: 10.1016/j.cclet.2020.05.025 shu

Trace Nb-doped Na_0.7Ni_0.3Co_0.1Mn_0.6O₂ with suppressed voltage decay and enhanced low temperature performance

Ruyun Yue ^a ,
Fang Xia ^a ,
Ruijuan Qi ^c ,
Da Tie ^a ,
Shanshan Shi ^{a, b} ,
Zhiping Li ^a ,
Yufeng Zhao ^{a, b, *,} ,
Jiujun Zhang ^b

a.
Key Laboratory of Applied Chemistry, Yanshan University, Qinhuangdao 066004, China
b.
Institute for Sustainable Energy & College of Sciences, Shanghai University, Shanghai 200444, China
c.
Key Laboratory of Polar Materials and Devices (MOE), Department of Optoelectronics, East China Normal University, Shanghai 200241, China

yufengzhao@shu.edu.cn

Received Date: 23 April 2020
Revised Date: 15 May 2020
Accepted Date: 15 May 2020
Available Online: 26 May 2020

Figures(4)

The P2-type manganese-based Na_0.7MnO₂ cathode materials attract great interest due to their high theoretical capacity. However, these materials suffer from rapid capacity fading, poor rate performance and severe voltage decay resulting from phase transition and sluggish reaction kinetics. In this work we report a novel Nb-doped Na_0.7[Ni_0.3Co_0.1Mn_0.6]_1-xNb_xO₂ with significantly suppressed voltage decay and enhanced cycling stability. The strong Nb-O bond can efficiently stabilize the TMO framework, and the as prepared material demonstrates much lower discharge midpoint voltage decay (0.132 V) than that of pristine one (0.319 V) after 200 cycles. Consequently, a remarkably improved cycling performance with a capacity retention of 87.9% after 200 cycle at 0.5 C is achieved, showing a 2.4 fold improvement as compared to the control sample Na_0.7Ni_0.3Co_0.1Mn_0.6O₂ (~37% rotation). Even at 2 C, a capacity retention of 68.4% is retained after 500 cycles. Remarkably, the as prepared material can be applied at low temperature of −20 ℃, showing a capacity retention of 81% as compared to that at room temperature.
- Manganese-based oxides,
- Sodium ion battery,
- Low temperature,
- Voltage decay,
- Cycling stability
1. [1]
  X. Yin, S. Sarkar, S. Shi, Adv. Funct. Mater. 30 (2020) 1908445. doi: 10.1002/adfm.201908445
2. [2]
  S. Shi, Z. Li, Y. Sun, et al., Nano Energy 48 (2018) 510-517. doi: 10.1016/j.nanoen.2018.04.001
3. [3]
  S. Shi, C. Sun, X. Yin, et al., Adv. Funct. Mater. 30 (2020) 1909283. doi: 10.1002/adfm.201909283
4. [4]
  B. Xu, S. Qi, M. Jin, et al., Chin. Chem. Lett. 30 (2019) 2053-2064. doi: 10.1016/j.cclet.2019.10.028
5. [5]
  Z. Wei, B. Ding, H. Dou, et al., Chin. Chem. Lett. 30 (2019) 2110-2122. doi: 10.1016/j.cclet.2019.11.022
6. [6]
  S. Shi, Z. Li, L. Shen, et al., Energy Storage Mater. 29 (2020) 78-83. doi: 10.1016/j.ensm.2020.03.029
7. [7]
  S. Huang, Z. Li, B. Wang, et al., Adv. Funct. Mater. 28 (2018) 1706294. doi: 10.1002/adfm.201706294
8. [8]
  S. Huang, M. Wang, P. Jia, et al., Energy Storage Mater. 20 (2019) 225-233. doi: 10.1016/j.ensm.2018.11.024
9. [9]
  Y. Wang, R. Xiao, Y.S. Hu, et al., Nat. Commun. 6 (2015) 6954. doi: 10.1038/ncomms7954
10. [10]
  H. Gao, J.B. Goodenough, Angew. Chem. Int. Ed. 55 (2016) 12768-12772. doi: 10.1002/anie.201606508
11. [11]
  J. Song, L. Wang, Y. Lu, J. Am. Chem. Soc. 137 (2015) 2658-2664. doi: 10.1021/ja512383b
12. [12]
  G. Gao, D. Tie, H. Ma, J. Mater. Chem. A 6 (2018) 6675-6684. doi: 10.1039/C8TA00206A
13. [13]
  C. Delmas, C. Fouassier, P. Hagenmuller, Phys. B+C 99 (1980) 81-85. doi: 10.1016/0378-4363(80)90214-4
14. [14]
  C. Delmas, Adv. Energy Mater. 8 (2018) 1703137. doi: 10.1002/aenm.201703137
15. [15]
  Y. Li, Y. Lu, C. Zhao, et al., Energy Storage Mater. 7 (2017) 130-151. doi: 10.1016/j.ensm.2017.01.002
16. [16]
  R.J. Clément, P.G. Bruce, C.P. Grey, J. Electrochem. Soc. 162 (2015) A2589-A2604. doi: 10.1149/2.0201514jes
17. [17]
  P. Wang, Y. You, Y. Yin, Adv. Energy Mater. 8 (2018) 1701912. doi: 10.1002/aenm.201701912
18. [18]
  S. Kumakura, Y. Tahara, S. Sato, Chem. Mater. 29 (2017) 8958-8962. doi: 10.1021/acs.chemmater.7b02772
19. [19]
  D. Carlier, J. Cheng, R. Berthelot, Dalton Trans. 40 (2011) 9306-9312. doi: 10.1039/c1dt10798d
20. [20]
  A. Gupta, C.B. Mullins, J.B. Goodenough, J. Power Sources 243 (2013) 817-821. doi: 10.1016/j.jpowsour.2013.06.073
21. [21]
  L. Yang, X. Li, J. Liu, et al., J. Am. Chem. Soc. 141 (2019) 6680-6689. doi: 10.1021/jacs.9b01855
22. [22]
  D. Tie, G. Gao, F. Xia, R. Yue, ACS Appl. Mater. Interfaces 11 (2019) 6978-6985. doi: 10.1021/acsami.8b19134
23. [23]
  I. Hasa, S. Passerini, J. Hassoun, J. Mater. Chem. A 5 (2017) 4467-4477. doi: 10.1039/C6TA08667E
24. [24]
  N. Sabi, A. Sarapulova, S. Indris, ACS Appl. Mater. Interfaces 9 (2017) 37778-37785. doi: 10.1021/acsami.7b11636
25. [25]
  X. Li, H. Guan, Z. Ma, et al., J. Energy Chem. 48 (2020) 195-202. doi: 10.1016/j.jechem.2020.01.021
26. [26]
  S. Xu, J. Wu, E. Hu, et al., J. Mater. Chem. A 6 (2018) 20795-20803. doi: 10.1039/C8TA07933A
27. [27]
  J.N. Zhang, Q. Li, C. Ouyang, et al., Nat. Energy 4 (2019) 594-603.
28. [28]
  H.P. Loock, B. Simard, S. Wallin, C. Linton, J. Chem, J. Chem. Phys. 109 (1998) 8980-8992. doi: 10.1063/1.477568
29. [29]
  M. Sathiya, A.M. Abakumov, D. Foix, et al., Nat. Mater. 14 (2014) 230-238.
30. [30]
  J. Yang, L. Xiao, W. He, et al., ACS Appl. Mater. Interfaces 8 (2016) 18867-18877. doi: 10.1021/acsami.6b04849
31. [31]
  N. Li, S. Hwang, M. Sun, et al., Adv. Energy Mater. 9 (2019) 1902258. doi: 10.1002/aenm.201902258
32. [32]
  Z. Yu, F. Ning, B. Li, et al., J. Phys. Chem. C 123 (2019) 18870-18876. doi: 10.1021/acs.jpcc.9b05683
33. [33]
  M. Sathiya, A.M. Abakumov, D. Foix, et al., Nat. Mater. 14 (2014) 230-238.
34. [34]
  J. Yang, L. Xiao, W. He, et al., ACS Appl. Mater. Interfaces 8 (2016) 18867-18877. doi: 10.1021/acsami.6b04849
35. [35]
  N. Li, S. Hwang, M. Sun, et al., Adv. Energy Mater. 9 (2019) 1902258. doi: 10.1002/aenm.201902258
36. [36]
  Z. Yu, F. Ning, B. Li, et al., J. Phys. Chem. C 123 (2019) 18870-18876. doi: 10.1021/acs.jpcc.9b05683
37. [37]
  H. Konishi, M. Yoshikawa, T. Hirano, J. Power Sources 244 (2013) 23-28. doi: 10.1016/j.jpowsour.2013.05.004
38. [38]
  W. Sun, M. Xie, X. Shi, L. Zhang, Mater. Res. Bull. 61 (2015) 287-291. doi: 10.1016/j.materresbull.2014.10.044
39. [39]
  Y. Zhang, E. Zhou, D. Song, Phys. Chem. Chem. Phys. 16 (2014) 17792-17798. doi: 10.1039/C4CP01897D
40. [40]
  J. Wu, H. Liu, X. Ye, et al., J. Alloy. Compd. 644 (2015) 223-227. doi: 10.1016/j.jallcom.2015.04.166
41. [41]
  D. Yuan, X. Hu, J. Qian, et al., Electrochim. Acta 116 (2014) 300-305. doi: 10.1016/j.electacta.2013.10.211
42. [42]
  X. Chen, X. Zhou, M. Hu, et al., J. Mater. Chem. A 3 (2015) 20708-20714. doi: 10.1039/C5TA05205J
43. [43]
  R. Muruganantham, M. Sivakumar, R. Subadevi, Ionics 24 (2018) 989-999. doi: 10.1007/s11581-017-2264-x
44. [44]
  D.H. Lee, X. Jing, S.M. Ying, Phys. Chem. Chem. Phys. 15 (2013) 3304-3312. doi: 10.1039/c2cp44467d
45. [45]
  D. Buchholz, L.G. Chagas, M. Winter, S. Passerini, Electrochim. Acta 110 (2013) 208-213. doi: 10.1016/j.electacta.2013.02.109
46. [46]
  D. Yuan, W. He, F. Pei, J. Mater, Chemistry A 1 (2013) 3895-3899.
47. [47]
  Z.Y. Li, R. Gao, L. Sun, et al., J. Mater. Chem. A 3 (2015) 16272-16278. doi: 10.1039/C5TA02450A
1. [1]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
2. [2]
  Junhua Wang , Xin Lian , Xichuan Cao , Qiao Zhao , Baiyan Li , Xian-He Bu . Dual polarization strategy to enhance CH₄ uptake in covalent organic frameworks for coal-bed methane purification. Chinese Chemical Letters, 2024, 35(8): 109180-. doi: 10.1016/j.cclet.2023.109180
3. [3]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
4. [4]
  Jingxuan Liu , Shiqi Zhao , Xiang Wu . Flexible electrochemical capacitor based NiMoSSe electrode material with superior cycling and structural stability. Chinese Chemical Letters, 2024, 35(7): 109059-. doi: 10.1016/j.cclet.2023.109059
5. [5]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
6. [6]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123
7. [7]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
8. [8]
  Yifan LIU , Zhan ZHANG , Rongmei ZHU , Ziming QIU , Huan PANG . A three-dimensional flower-like Cu-based composite and its low-temperature calcination derivatives for efficient oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 979-990. doi: 10.11862/CJIC.20240008
9. [9]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
10. [10]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
11. [11]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
12. [12]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
13. [13]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
14. [14]
  Linjing Li , Wenlai Xu , Jianyong Ning , Yaping Zhong , Chuyue Zhang , Jiane Zuo , Zhicheng Pan . Revealing the intrinsic mechanisms for accelerating nitrogen removal efficiency in the Anammox reactor by adding Fe(II) at low temperature. Chinese Chemical Letters, 2024, 35(8): 109243-. doi: 10.1016/j.cclet.2023.109243
15. [15]
  Dong Sui , Jiayi Liu . Constriction-susceptible lithium support for fast cycling of solid-state lithium metal battery. Chinese Chemical Letters, 2025, 36(2): 110417-. doi: 10.1016/j.cclet.2024.110417
16. [16]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
17. [17]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
18. [18]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
19. [19]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
20. [20]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1118)
HTML views(144)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Trace Nb-doped Na0.7Ni0.3Co0.1Mn0.6O2 with suppressed voltage decay and enhanced low temperature performance

Metrics

通讯作者: 陈斌, bchen63@163.com

Trace Nb-doped Na_0.7Ni_0.3Co_0.1Mn_0.6O₂ with suppressed voltage decay and enhanced low temperature performance