Citation: Zhang Zishu, Gao Ying, Li Peng, Qu Binhong, Mu Zhiyuan, Liu Yang, Qu Yang, Kong Degui, Chang Qing, Jing Liqiang. Highly sensitive fluorescence detection of chloride ion in aqueous solution with Ag-modified porous g-C₃N₄ nanosheets[J]. Chinese Chemical Letters, ;2020, 31(10): 2725-2729. doi: 10.1016/j.cclet.2020.05.024 shu

Highly sensitive fluorescence detection of chloride ion in aqueous solution with Ag-modified porous g-C₃N₄ nanosheets

Zhang Zishu ^a,b ,
Gao Ying ^a ,
Li Peng ^b,c,**, ,
Qu Binhong ^b ,
Mu Zhiyuan ^b ,
Liu Yang ^b ,
Qu Yang ^b ,
Kong Degui ^a ,
Chang Qing ^a,d,***, ,
Jing Liqiang ^b,*,

a.
College of Electronic Engineering, Heilongjiang University, Harbin 150080, China
b.
Key Laboratory of Functional Inorganic Materials Chemistry(Ministry of Education), International Joint Research Center for Catalytic Technology, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
c.
College of Physical Science and Technology, Heilongjiang University, Harbin 150080, China
d.
College of Media Engineering, Communication University of Zhejiang, Hangzhou 310018, China

^**

^***

lipenghit@126.com

15846017711@139.com

Jinglq@hlju.edu.cn

Received Date: 21 April 2020
Revised Date: 2 May 2020
Accepted Date: 18 May 2020
Available Online: 26 May 2020

Figures(4)

The porous g-C₃N₄ (PCN) nanosheets are successfully synthesized and further modified with nano-sized Ag by a simple wet-chemical process. Interestingly, the Ag-modified porous g-C₃N₄ (Ag-PCN) nanosheets exhibit competitive fluorescence detection performance of chloride ion (Cl^-) in aqueous solution. Under the optimized conditions, the concentration of Cl^- could be quantitative analyzed with the Ag-PCN in a wide detection range from 0.5 mmol/L to 0.1 mol/L, with a low detection limitation of 0.06 mmol/L. It is confirmed that the fluorescence of PCN could be effectively decayed by the photoinduced charge transfer via the adsorbed Cl^- for trapping holes, mainly by means of the time-resolved fluorescence and surface photovoltage spectra. The porous structure and modified Ag promote the adsorption of Cl^- on resulting Ag-PCN, leading to excellent fluorescence detection for Cl^-. This work provides a feasible route to develop a fluorescence detection of Cl^- with g-C₃N₄ nanosheets in environment water.
- g-C₃N₄,
- Ag-modification,
- Chloride ion,
- Fluorescence detection,
- Photoinduced charge transfer
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Highly sensitive fluorescence detection of chloride ion in aqueous solution with Ag-modified porous g-C3N4 nanosheets

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通讯作者: 陈斌, bchen63@163.com

Highly sensitive fluorescence detection of chloride ion in aqueous solution with Ag-modified porous g-C₃N₄ nanosheets