Citation: Zhang Minxian, He Jie, Chen Yibo, Liao Pei-Yu, Liu Zhao-Qing, Zhu Mingshan. Visible light-assisted peroxydisulfate activation via hollow copper tungstate spheres for removal of antibiotic sulfamethoxazole[J]. Chinese Chemical Letters, ;2020, 31(10): 2721-2724. doi: 10.1016/j.cclet.2020.05.001 shu

Visible light-assisted peroxydisulfate activation via hollow copper tungstate spheres for removal of antibiotic sulfamethoxazole

Zhang Minxian ^a ,
He Jie ^a ,
Chen Yibo ^b,c,*, ,
Liao Pei-Yu ^b ,
Liu Zhao-Qing ^b ,
Zhu Mingshan ^a,*,

a.
School of Environment, Jinan University, Guangzhou 510632, China
b.
School of Chemistry and Chemical Engineering, Guangzhou Key Laboratory for Clean Energy and Materials, Guangzhou University, Guangzhou 510006, China
c.
Department of Chemistry, University of California, Riverside, CA 92521, United States

^**

chenyibo@gzhu.edu.cn

zhumingshan@jnu.edu.cn

Received Date: 14 February 2020
Revised Date: 16 April 2020
Accepted Date: 3 May 2020
Available Online: 8 May 2020

Figures(5)

The contamination of antibiotics in aqueous environment causes increasing concerns recently. Light-assisted activation of peroxydisulfate (PDS) has been demonstrated as an efficient technology for removal of contamination in water. Herein, a hollow sphere of CuWO₄ (h-CuWO₄) was employed as a visible light-activated photocatalyst for the activation of PDS, and following with high removal efficiency (98%) of antibiotic sulfamethoxazole (SMX). Under visible light irradiation, the degradation rate on hollow structures system is nearly 2 times higher than the traditional solid CuWO₄ spheres. Furthermore, the underlying mechanism and detailed pathway of SMX degradation were proposed based on density functional theory (DFT) calculations and liquid chromatography-mass spectrometry (LC–MS). This work provides a new feasible way for advanced oxidation processes to remove antibiotics SMX in heterogeneous system, and open up new application possibilities of CuWO₄-based materials.
- Copper tungstate,
- Peroxydisulfate,
- Sulfamethoxazole,
- Visible light,
- Hollow spheres
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