Citation: Bohua Deng, Ning Yue, Haoyang Dong, Qiuyue Gui, Liang Xiao, Jinping Liu. Surface-assembled highly flexible Na₃(VOPO₄)₂F nanocube cathode for high-rate binder-free Na-ion batteries[J]. Chinese Chemical Letters, ;2021, 32(2): 826-829. doi: 10.1016/j.cclet.2020.04.054 shu

Surface-assembled highly flexible Na₃(VOPO₄)₂F nanocube cathode for high-rate binder-free Na-ion batteries

Bohua Deng ^a ,
Ning Yue ^a ,
Haoyang Dong ^a ,
Qiuyue Gui ^a ,
Liang Xiao ^a ,
Jinping Liu ^{a, b, c, *,}

a.
School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, Wuhan 430070, China
b.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
c.
Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

liujp@whut.edu.cn

Received Date: 7 April 2020
Revised Date: 25 April 2020
Accepted Date: 28 April 2020
Available Online: 6 May 2020

Figures(4)

Flexible Na-ion storage cathodes are still very few due to the challenge in achieving both reliable mechanical flexibility and excellent electrochemical performances. Herein, a new type of flexible Na₃(VOPO₄)₂F cathode with nanocubes tightly assembled on carbon cloth is fabricated by a facile solvothermal method for the first time. The cathode is able to exhibit superior rate capability and stable cycling performance up to 1000 cycles, due to the surface-assembling of crystalline nanocubes on carbon fibers. In addition, it shows good mechanical flexibility, nearly no capacity decay is observed after continuous bending of 500 times. With this novel cathode and a directly-grown Na₂Ti₂O₅ anode, a fully binder-free Na-ion battery is assembled. It can deliver a high working voltage and increased gravimetric energy/power densities (maximum values: 220.2 Wh/kg; 5674.7 W/kg), and can power a LED indicator at bending angles from 0° to 180°.
- Flexible cathode,
- Na₃(VOPO₄)₂F,
- Nanocube,
- Surface-assembling,
- Sodium-ion battery
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Surface-assembled highly flexible Na3(VOPO4)2F nanocube cathode for high-rate binder-free Na-ion batteries

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通讯作者: 陈斌, bchen63@163.com

Surface-assembled highly flexible Na₃(VOPO₄)₂F nanocube cathode for high-rate binder-free Na-ion batteries