Citation: Liu Yangyang, Wang Tao, Fang Xiaozhong, Deng Yue, Cheng Hanyun, Fu Hongbo, Zhang Liwu. Impact of greenhouse gas CO₂ on the heterogeneous reaction of SO₂ on alpha-Al₂O₃[J]. Chinese Chemical Letters, ;2020, 31(10): 2712-2716. doi: 10.1016/j.cclet.2020.04.037 shu

Impact of greenhouse gas CO₂ on the heterogeneous reaction of SO₂ on alpha-Al₂O₃

Liu Yangyang ^a ,
Wang Tao ^a ,
Fang Xiaozhong ^a ,
Deng Yue ^a ,
Cheng Hanyun ^a ,
Fu Hongbo ^a ,
Zhang Liwu ^a,b,*,

a.
Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433 China
b.
Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092 China

zhanglw@fudan.edu.cn

Received Date: 5 March 2020
Revised Date: 1 April 2020
Accepted Date: 19 April 2020
Available Online: 30 April 2020

Figures(2)

The heterogeneous reaction of SO₂ on mineral dust surfaces is generally considered as an important chemical pathway for secondary sulfate formation in the troposphere. To this day, there are no reported studies that assess the impact of atmospheric CO₂ in sulfate production on mineral dust surfaces. In this work, we investigate the impact of CO₂ on SO₂ uptake on dust proxy aluminum oxide particles using a diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). CO₂ is demonstrated to suppress the heterogeneous oxidation of SO₂ on alpha-Al₂O₃. Compared to that measured in the CO₂-free case, the uptake coefficient is decreased by nearly 57% when Al₂O₃ particles are exposed to the gas flow with atmospheric CO₂ at a relative humidity (RH) of 25%. It is also found that there is a balance between the yield of active moiety —OH provided by Al(OH)₃(CO)(OH)₂ clusters and the loss of basic hydroxyl group on aluminum oxide surfaces blocked by CO₂-derived (bi)carbonate species. This work, for the first time, reveals a negative effect of atmospheric CO₂ on the sulfate formation, which potentially decreases solar-radiation scattering and further exacerbates global warming.
- Atmospheric CO₂,
- Sulfate,
- Alpha-Al₂O₃,
- Mineral dust,
- Heterogeneous reaction
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沈阳化工大学材料科学与工程学院沈阳 110142

Impact of greenhouse gas CO2 on the heterogeneous reaction of SO2 on alpha-Al2O3

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通讯作者: 陈斌, bchen63@163.com

Impact of greenhouse gas CO₂ on the heterogeneous reaction of SO₂ on alpha-Al₂O₃