Citation: Hao Fu, Shuyu Zhou, Xi Fan, Lei Zhang, Jian Zhang. Assembly and packing models of [Ti₆Co₁₂] ring based on the titanium-capped cobalt clathrochelates[J]. Chinese Chemical Letters, ;2021, 32(2): 923-925. doi: 10.1016/j.cclet.2020.04.004 shu

Assembly and packing models of [Ti₆Co₁₂] ring based on the titanium-capped cobalt clathrochelates

Hao Fu ^{a, b, c} ,
Shuyu Zhou ^{a, b, c} ,
Xi Fan ^a ,
Lei Zhang ^{a, *,} ,
Jian Zhang ^{a, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
School of Physical Science and Technology, Shanghai Tech University, Shanghai 201210, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

LZhang@fjirsm.ac.cn

zhj@fjirsm.ac.cn

Received Date: 8 March 2020
Revised Date: 31 March 2020
Accepted Date: 3 April 2020
Available Online: 18 April 2020

Figures(4)

In this work, titanium-capped cobalt clathrochelates have been applied as secondary building units (SBUs) for the construction of supramolecular rings. Two heterometallic wheel-like [Ti₆Co₁₂] complexes based on cobalt clathrochelates, [C₆H₁₅N₄]₂[TiCo₂(μ₂-Oipr)(Oipr)₂(Dmg)₃]₆ (2, Dmg=dimethylglyoxime) and H₆[TiCo₂(μ₂-Oipr)(Oipr)₂(Dmg)₃]₆ (3), have been successfully synthesized and characterized. The supramolecular stacking modes of these wheels are largely dependent on the applied synthetic conditions, which further impact their gas adsorption properties.
- Titanium-oxo clusters,
- Wheel-like molecule,
- Coordination self-assembly,
- Heterometallic complexes,
- Clathrochelates
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通讯作者: 陈斌, bchen63@163.com

Assembly and packing models of [Ti₆Co₁₂] ring based on the titanium-capped cobalt clathrochelates