Citation: Guo Ruonan, Nengzi Li-Chao, Chen Ying, Song Qingqing, Gou Jianfeng, Cheng Xiuwen. Construction of high-efficient visible photoelectrocatalytic system for carbamazepine degradation: Kinetics, degradation pathway and mechanism[J]. Chinese Chemical Letters, ;2020, 31(10): 2661-2667. doi: 10.1016/j.cclet.2020.03.068 shu

Construction of high-efficient visible photoelectrocatalytic system for carbamazepine degradation: Kinetics, degradation pathway and mechanism

a.
Key Laboratory of Western China's Environmental Systems(Ministry of Education) and Key Laboratory for Environmental Pollution Prediction and Control, Gansu Province, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, China
b.
Academy of Economics and Environmental Sciences, Xichang University, Xichang 615000, China

chengxw@lzu.edu.cn

Received Date: 11 February 2020
Revised Date: 8 March 2020
Accepted Date: 25 March 2020
Available Online: 29 April 2020

Figures(4)

This study aimed to construct a photoelectrocatalytic (PEC) reaction system based on the self-made reduced TiO₂ NTAs (r-TNAs) photoanode and activated carbon/Polytetrafluoroethylene (AC/PTFE) cathode. It would be observed clearly that the degradation rate constant of carbamazepine (CBZ) over r-TNAs_(photoanode)-AC/PTFE_(cathode) PEC system (0.04961 min^-1) was even higher than that of r-TNAs_(photoanode)-Pt_(cathode) PEC system (0.04602 min^-1) with the assistance of visible light irradiation and +0.4 V external potential. Besides, in order to obtain optimized conditions, the influence of key parameters such as pH value, electric current density and electrolyte concentration were studied. Most importantly, photoelectrochemical (PECH) properties, reactive oxide species contribution, ^·OH formation rate and CBZ degradation pathway were determined. The results illustrated that the excellent PEC degradation performance depended on the excellent photocatalytic property of r-TNAs photoanode and electron transfer property of photoelectrodes in r-TNAs_(photoanode)-AC/PTFE_(cathode) PEC system. Therefore, the study demonstrated that the r-TNAs_(photoanode)-AC/PTFE_(cathode) PEC system could be expected to replace metal-catalyzed cathodes depending on its excellent PEC performance activity and low cost as well as the reaction system possessed objective and practical application prospect.
- Photoelectrocatalytic system,
- r-TNAs photoanode,
- AC/PTFE cathode,
- Carbamazepine degradation pathway
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沈阳化工大学材料科学与工程学院沈阳 110142