Citation: Yuan Mingli, Peng Xiaoxu, Ge Fen, Zhao Mingyue, Li Qing, Wang Zheng. Ultrasensitive determination of mercury by solution anode glow discharge atomic emission spectrometry coupled with hydride generation[J]. Chinese Chemical Letters, ;2020, 31(10): 2814-2818. doi: 10.1016/j.cclet.2020.03.055 shu

Ultrasensitive determination of mercury by solution anode glow discharge atomic emission spectrometry coupled with hydride generation

Yuan Mingli ^a,c ,
Peng Xiaoxu ^a ,
Ge Fen ^a,c ,
Zhao Mingyue ^a ,
Li Qing ^a ,
Wang Zheng ^a,b,*,

a.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
b.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
c.
School of Material Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China

wangzheng@mail.sic.ac.cn

Received Date: 16 January 2020
Revised Date: 6 March 2020
Accepted Date: 16 March 2020
Available Online: 20 March 2020

Figures(4)

An innovative method for the ultrasensitive detection of mercury by solution anode glow discharge atomic emission spectroscopy (SAGD-AES) coupled with hydride generation (HG) was first investigated. In this method, the mercury vapor generated by the HG was transmitted to the SAGD through the miniature hollow tungsten tube for excitation and detected by a miniaturized spectrograph. A thorough parametric evaluation of the HG and SAGD system was performed, including the type and concentration of carrier acid, He flow rate, concentrations of NaBH₄, discharge current and discharge gap. Under optimal operating conditions, the detection limit for Hg²⁺ achieved 0.03 μg/L, with a relative standard deviation of 1.1% at the Hg²⁺ concentration of 5 μg/L. Moreover, the correlation coefficient of the calibration curve was 0.9996 in the range between 0.1 and 10 μg/L. The accuracy and practicability of HG-SAGD-AES were verified by measuring GBW09101b (human hair), GBW10029 (fish), soil and rice samples. The results showed good agreement with the certified values and values from direct mercury analyzer (DMA).
- Solution anode glow discharge,
- Hydride generation,
- Atomic emission spectroscopy,
- Mercury
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