Citation: Chen Ye, Yangguang Zhu, Hongyan Sun, Feiyue Chen, Huifang Sun, Wen Dai, Qiuping Wei, Li Fu, Aimin Yu, Shiyu Du, Minghui Yang, Liang-Feng Huang, Jinhong Yu, Nan Jiang, Cheng-Te Lin. Layer-by-layer stacked graphene nanocoatings by Marangoni self-assembly for corrosion protection of stainless steel[J]. Chinese Chemical Letters, ;2021, 32(1): 501-505. doi: 10.1016/j.cclet.2020.03.013 shu

Layer-by-layer stacked graphene nanocoatings by Marangoni self-assembly for corrosion protection of stainless steel

Chen Ye ^{a, b} ,
Yangguang Zhu ^{a, c} ,
Hongyan Sun ^{a, d} ,
Feiyue Chen ^{a, e} ,
Huifang Sun ^{a, f} ,
Wen Dai ^{a, b} ,
Qiuping Wei ^g ,
Li Fu ^h ,
Aimin Yu ⁱ ,
Shiyu Du ^j ,
Minghui Yang ^j ,
Liang-Feng Huang ^{a, b} ,
Jinhong Yu ^{a, b, *,} ,
Nan Jiang ^{a, b, *,} ,
Cheng-Te Lin ^{a, b, *,}

a.
Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences, Ningbo 315201, China
b.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
c.
Laboratory of Environmental Biotechnology, School of Environmental and Civil Engineering, Jiangnan University, Wuxi 214122, China
d.
Bionic Sensing and Intelligence Center (BSIC), Institute of Biomedical and Health Engineering, Shenzhen Institutes of Advanced Technology, Chinese Academy of Science, Shenzhen 518055, China
e.
College of Science, Henan University of Technology, Zhengzhou 450001, China
f.
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
g.
School of Materials Science and Engineering, Central South University, Changsha 410083, China
h.
College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
i.
Department of Chemistry and Biotechnology, Faculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn VIC 3122, Australia
j.
Ningbo Institute of Materials Technology and Engineering (NIMTE), Chinese Academy of Sciences, Ningbo 315201, China

yujinhong@nimte.ac.cn

jiangnan@nimte.ac.cn

linzhengde@nimte.ac.cn

Received Date: 30 December 2019
Revised Date: 17 February 2020
Accepted Date: 5 March 2020
Available Online: 6 March 2020

Figures(4)

Graphene nanosheets are widely used in anti-corrosion polymeric coating as filler, owing to the excellent electrochemical inertness and barrier property. However, as the arrangement of graphene nanosheets is difficult to form a perfect layered structure, polymeric coating with graphene nanosheets usually needs micron-scale thickness to ensure the enhancement of corrosion protection. In this work, layer-by-layer stacked graphene nanocoatings were fabricated on stainless steel by self-assembly based on Marangoni effect. The anti-corrosion property of graphene coatings were studied through Tafel polarization curves, electrochemical impedance spectroscopy and accelerated corrosion test with extra applied voltage. The self corrosion current density of optimized three-layered graphene coated sample was one quarter of that of bare stainless steel. And the self corrosion potential of optimized sample is increased to -0.045 V. According to the results, graphene nanocoatings composed of layered nanosheets exhibits good anti-corrosion property. Besides, the self-assembly method provide a promising approach to make layered-structure coating for other researches about 2D material nanosheets.
- Self-assembly,
- Graphene nanosheets,
- Layer-by-layer stacking,
- Electrochemical corrosion,
- Anti-corrosion coating
1. [1]
  K.S. Novoselov, A.K. Geim, S.V. Morozov, et al., Science 306(2004) 666-669. doi: 10.1126/science.1102896
2. [2]
  A.A. Balandin, S. Ghosh, W. Bao, et al., Nano Lett. 8(2008) 902-907. doi: 10.1021/nl0731872
3. [3]
  H. Chen, M.B. Müller, K.J. Gilmore, G.G. Wallace, D. Li, Adv. Mater. 20(2008) 3557-3561. doi: 10.1002/adma.200800757
4. [4]
  K.I. Bolotin, K.J. Sikes, Z. Jiang, et al., Solid State Commun. 146(2008) 351-355. doi: 10.1016/j.ssc.2008.02.024
5. [5]
  M.D. Stoller, S. Park, Y. Zhu, J. An, R.S. Ruoff, Nano Lett. 8(2008) 3498-3502. doi: 10.1021/nl802558y
6. [6]
  C. Lee, X. Wei, J.W. Kysar, J. Hone, Science 321(2008) 385-388. doi: 10.1126/science.1157996
7. [7]
  J.S. Bunch, S.S. Verbridge, J.S. Alden, et al., Nano Lett. 8(2008) 2458-2462. doi: 10.1021/nl801457b
8. [8]
  O. Leenaerts, B. Partoens, F.M. Peeters, Appl. Phys. Lett. 93(2008) 193107. doi: 10.1063/1.3021413
9. [9]
  L. Liu, S. Ryu, M.R. Tomasik, et al., Nano Lett. 8(2008) 1965-1970. doi: 10.1021/nl0808684
10. [10]
  K.S. Novoselov, V.I. Fal, L. Colombo, et al., Nature 490(2012) 192-200. doi: 10.1038/nature11458
11. [11]
  X. Li, W. Cai, J. An, et al., Science 324(2009) 1312-1314. doi: 10.1126/science.1171245
12. [12]
  S. Yin, X. Zhang, C. Xu, et al., Mater. Lett. 215(2018) 259-262. doi: 10.1016/j.matlet.2017.12.121
13. [13]
  S. Chen, L. Brown, M. Levendorf, et al., ACS Nano 5(2011) 1321-1327. doi: 10.1021/nn103028d
14. [14]
  M. Topsakal, H. Şahin, S. Ciraci, Phys. Rev. B 85(2012) 155445. doi: 10.1103/PhysRevB.85.155445
15. [15]
  M. Schriver, W. Regan, W.J. Gannett, et al., ACS Nano 7(2013) 5763-5768. doi: 10.1021/nn4014356
16. [16]
  D. Prasai, J.C. Tuberquia, R.R. Harl, G.K. Jennings, K.I. Bolotin, ACS Nano 6(2012) 1102-1108. doi: 10.1021/nn203507y
17. [17]
  N.T. Kirkland, T. Schiller, N. Medhekar, N. Birbilis, Corros. Sci. 56(2012) 1-4. doi: 10.1016/j.corsci.2011.12.003
18. [18]
  R.S. Raman, P.C. Banerjee, D.E. Lobo, et al., Carbon 50(2012) 4040-4045. doi: 10.1016/j.carbon.2012.04.048
19. [19]
  G. Mittal, V. Dhand, K.Y. Rhee, S.J. Park, W.R. Lee, J. Ind, Eng. Chem. 21(2015)11-25. doi: 10.1016/j.jiec.2014.03.022
20. [20]
  S. Böhm, Nat. Nanotechnol. 9(2014) 741. doi: 10.1038/nnano.2014.220
21. [21]
  Y.H. Yu, Y.Y. Lin, C.H. Lin, C.C. Chan, Y.C. Huang, Polym. Chem. 5(2014) 535-550. doi: 10.1039/C3PY00825H
22. [22]
  K.C. Chang, M.H. Hsu, H.I. Lu, Carbon 66(2014) 144-153. doi: 10.1016/j.carbon.2013.08.052
23. [23]
  C.H. Chang, T.C. Huang, C.W. Peng, Carbon 50(2012) 5044-5051. doi: 10.1016/j.carbon.2012.06.043
24. [24]
  N. Liu, J. Zhang, Y. Chen, et al., J. Am. Chem. Soc. 141(2019) 4016-4025. doi: 10.1021/jacs.8b13038
25. [25]
  Y. Chen, Y. Wang, S. Zhu, et al., Mater. Today 24(2019) 26-32. doi: 10.1016/j.mattod.2018.09.001
26. [26]
  Y. Wang, Y. Chen, S.D. Lacey, et al., Mater. Today 21(2018) 186-192. doi: 10.1016/j.mattod.2017.10.008
27. [27]
  Y. Chen, K. Fu, S. Zhu, et al., Nano Lett. 16(2016) 3616-3623. doi: 10.1021/acs.nanolett.6b00743
28. [28]
  C.A. Sternling, L.E. Scriven, AIChE J. 5(1959) 514-523. doi: 10.1002/aic.690050421
29. [29]
  X. Li, T. Yang, Y. Yang, Adv. Funct. Mater. 26(2016) 1322-1329. doi: 10.1002/adfm.201504717
30. [30]
  D. Yang, A. Velamakanni, G. Bozoklu, Carbon 47(2009) 145-152. doi: 10.1016/j.carbon.2008.09.045
31. [31]
  S. Qiu, W. Li, W. Zheng, H. Zhao, L. Wang, ACS Appl. Mater. Interfaces 9(2017) 34294-34304. doi: 10.1021/acsami.7b08325
32. [32]
  S. Pourhashem, M.R. Vaezi, A. Rashidi, M.R. Bagherzadeh, Corros. Sci. 115(2017) 78-92. doi: 10.1016/j.corsci.2016.11.008
1. [1]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
2. [2]
  Yuwen Zhu , Xiang Deng , Yan Wu , Baode Shen , Lingyu Hang , Yuye Xue , Hailong Yuan . Formation mechanism of herpetrione self-assembled nanoparticles based on pH-driven method. Chinese Chemical Letters, 2025, 36(1): 109733-. doi: 10.1016/j.cclet.2024.109733
3. [3]
  Jingqi Xin , Shupeng Han , Meichen Zheng , Chenfeng Xu , Zhongxi Huang , Bin Wang , Changmin Yu , Feifei An , Yu Ren . A nitroreductase-responsive nanoprobe with homogeneous composition and high loading for preoperative non-invasive tumor imaging and intraoperative guidance. Chinese Chemical Letters, 2024, 35(7): 109165-. doi: 10.1016/j.cclet.2023.109165
4. [4]
  Keyang Li , Yanan Wang , Yatao Xu , Guohua Shi , Sixian Wei , Xue Zhang , Baomei Zhang , Qiang Jia , Huanhua Xu , Liangmin Yu , Jun Wu , Zhiyu He . Flash nanocomplexation (FNC): A new microvolume mixing method for nanomedicine formulation. Chinese Chemical Letters, 2024, 35(10): 109511-. doi: 10.1016/j.cclet.2024.109511
5. [5]
  Xuanyu Wang , Zhao Gao , Wei Tian . Supramolecular confinement effect enabling light-harvesting system for photocatalytic α-oxyamination reaction. Chinese Chemical Letters, 2024, 35(11): 109757-. doi: 10.1016/j.cclet.2024.109757
6. [6]
  Xian Yan , Huawei Xie , Gao Wu , Fang-Xing Xiao . Boosted solar water oxidation steered by atomically precise alloy nanocluster. Chinese Chemical Letters, 2025, 36(1): 110279-. doi: 10.1016/j.cclet.2024.110279
7. [7]
  Bing Niu , Honggao Huang , Liwei Luo , Li Zhang , Jianbo Tan . Coating colloidal particles with a well-defined polymer layer by surface-initiated photoinduced polymerization-induced self-assembly and the subsequent seeded polymerization. Chinese Chemical Letters, 2025, 36(2): 110431-. doi: 10.1016/j.cclet.2024.110431
8. [8]
  Wenhao Yan , Shuaiya Xue , Xuerui Zhao , Wei Zhang , Jian Li . Hexagonal boron nitride based slippery liquid infused porous surface with anti-corrosion, anti-contaminant and anti-icing properties for protecting magnesium alloy. Chinese Chemical Letters, 2024, 35(4): 109224-. doi: 10.1016/j.cclet.2023.109224
9. [9]
  Hao Zhang , Haonan Qu , Ehsan Bahojb Noruzi , Haibing Li , Feng Liang . A nanocomposite film with layer-by-layer self-assembled gold nanospheres driven by cucurbit[7]uril for the selective transport of L-tryptophan and lysozyme. Chinese Chemical Letters, 2025, 36(1): 109731-. doi: 10.1016/j.cclet.2024.109731
10. [10]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
11. [11]
  Cheng-Yan Wu , Yi-Nan Gao , Zi-Han Zhang , Rui Liu , Quan Tang , Zhong-Lin Lu . Enhancing self-assembly efficiency of macrocyclic compound into nanotubes by introducing double peptide linkages. Chinese Chemical Letters, 2024, 35(11): 109649-. doi: 10.1016/j.cclet.2024.109649
12. [12]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
13. [13]
  Zengchao Guo , Weiwei Liu , Tengfei Liu , Jinpeng Wang , Hui Jiang , Xiaohui Liu , Yossi Weizmann , Xuemei Wang . Engineered exosome hybrid copper nanoscale antibiotics facilitate simultaneous self-assembly imaging and elimination of intracellular multidrug-resistant superbugs. Chinese Chemical Letters, 2024, 35(7): 109060-. doi: 10.1016/j.cclet.2023.109060
14. [14]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
15. [15]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
16. [16]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
17. [17]
  Changhui Yu , Peng Shang , Huihui Hu , Yuening Zhang , Xujin Qin , Linyu Han , Caihe Liu , Xiaohan Liu , Minghua Liu , Yuan Guo , Zhen Zhang . Evolution of template-assisted two-dimensional porphyrin chiral grating structure by directed self-assembly using chiral second harmonic generation microscopy. Chinese Chemical Letters, 2024, 35(10): 109805-. doi: 10.1016/j.cclet.2024.109805
18. [18]
  Yi Zhou , Wei Zhang , Rong Fu , Jiaxin Dong , Yuxuan Liu , Zihang Song , Han Han , Kang Cai . Self-assembly of two pairs of homochiral M₂L₄ coordination capsules with varied confined space using Tröger's base ligands. Chinese Chemical Letters, 2025, 36(2): 109865-. doi: 10.1016/j.cclet.2024.109865
19. [19]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
20. [20]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(872)
HTML views(116)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142