Citation: Xie Di, Hu Fang, Yu Xin, Cui Fuhan, Song Guihong, Zhu Kai. High-performance Na_1.25V₃O₈ nanosheets for aqueous zinc-ion battery by electrochemical induced de-sodium at high voltage[J]. Chinese Chemical Letters, ;2020, 31(9): 2268-2274. doi: 10.1016/j.cclet.2020.02.052 shu

High-performance Na_1.25V₃O₈ nanosheets for aqueous zinc-ion battery by electrochemical induced de-sodium at high voltage

Xie Di ^a ,
Hu Fang ^a,*, ,
Yu Xin ^a ,
Cui Fuhan ^a ,
Song Guihong ^a ,
Zhu Kai ^b,c,*,

a.
School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China
b.
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150010, China
c.
Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hong Kong, China

hufang25@sut.edu.cn

kzhu@hrbeu.edu.cn

Received Date: 29 January 2020
Revised Date: 22 February 2020
Accepted Date: 27 February 2020
Available Online: 28 February 2020

Figures(4)

Aqueous rechargeable zinc-ion batteries (ARZIBs) are expected to replace organic electrolyte batteries owing to its low price, safe and environmentally friendly characteristics. Herein, we fabricated vanadium-based Na_1.25V₃O₈ nanosheets as a cathode material for ARZIBs, which present a high performance by electrochemical de-sodium at high voltage to form Na₂V₆O₁₆ phase in the first cycle: high capacity of 390 mAh/g at 0.1 A/g, high rate performance (162 mAh/g at 10 A/g) and superior cycle stability (179 mAh/g with a high capacity retention of 88.2% of the maximum capacity after 2000 cycles). In addition, the cell exhibits a high energy density of 416.9 Wh/kg at 143.6 W/kg, suggesting great potential of the as-prepared Na_1.25V₃O₈ nanosheets for ARZIBs.
- Na_1.25V₃O₈ nanosheets,
- Aqueous rechargeable zinc-ion batteries,
- Electrochemical de-sodium,
- Cycle stability,
- High energy density
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High-performance Na1.25V3O8 nanosheets for aqueous zinc-ion battery by electrochemical induced de-sodium at high voltage

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通讯作者: 陈斌, bchen63@163.com

High-performance Na_1.25V₃O₈ nanosheets for aqueous zinc-ion battery by electrochemical induced de-sodium at high voltage