Citation: Zhihui Wang, Lei Wang, Zhiming Wang, Pinhua Li, Yicheng Zhang. A practical synthesis of α-bromo/iodo/chloroketones from olefins under visible-light irradiation conditions[J]. Chinese Chemical Letters, ;2021, 32(1): 429-432. doi: 10.1016/j.cclet.2020.02.022 shu

A practical synthesis of α-bromo/iodo/chloroketones from olefins under visible-light irradiation conditions

Zhihui Wang ^{a, b} ,
Lei Wang ^{a, b, c, *} ,
Zhiming Wang ^{a, c} ,
Pinhua Li ^{b, c} ,
Yicheng Zhang ^{b, c, **}

a.
Advanced Research Institute and Department of Chemistry, Taizhou University, Taizhou 318000, China
b.
Department of Chemistry, Huaibei Normal University, Huaibei 235000, China
c.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 200032, China

^**

leiwang@chnu.edu.cn

lbqzhych@163.com

Received Date: 24 December 2019
Revised Date: 30 January 2020
Accepted Date: 13 February 2020
Available Online: 14 February 2020

Figures(6)

A practical synthesis of α-bromo/iodo/chloroketones from olefins under visible-light irradiation conditions has been developed. In the presence of PhI(OAc)₂ as promoter and under ambient conditions, the reactions of styrenes and triiodomethane undergo the transformation smoothly to deliver the corresponding α-iodoketones without additional photocatalyst in good yields under sunlight irradiation. Meanwhile, the reactions of styrenes with tribromomethane and trichloromethane generate the desired α-bromoketones and α-chloroketones in high yields by using Ru(bpy)₃Cl₂ as a photocatalyst under blue LED (450–455 nm) irradiation.
- α-Bromoketones,
- α-Iodoketones,
- α-Chloroketones,
- Olefins,
- Visible-light irradiation
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