Citation: Guo Jiaojiao, Tsega Tsegaye Tadesse, Islam Ibrahim Ul, Iqbal Asma, Zai Jiantao, Qian Xuefeng. Fe doping promoted electrocatalytic N₂ reduction reaction of 2H MoS₂[J]. Chinese Chemical Letters, ;2020, 31(9): 2487-2490. doi: 10.1016/j.cclet.2020.02.019 shu

Fe doping promoted electrocatalytic N₂ reduction reaction of 2H MoS₂

School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China

zaijiantao@sjtu.edu.cn

xfqian@sjtu.edu.cn

Received Date: 22 November 2019
Revised Date: 13 January 2020
Accepted Date: 9 February 2020
Available Online: 13 February 2020

Figures(4)

Electrocatalytic N₂ reduction to ammonia is a fascinating alternative to Haber-Bosch process and also considered as an energy storage method. This work, Fe doped MoS₂/carbon cloth (CC) has been studied on the electro-catalysis fix nitrogen indicating the doped Fe can indeed enhance the MoS₂ material ability. Compared with MoS₂/CC, Fe-Mo-S-3/CC not only increases 10 times in the rate of production ammonia, but also 5 times in Faraday efficiency.
- 2H MoS₂,
- Electrocatalytic,
- N₂ reduction reaction (NRR),
- Fe doping,
- Ammonia
1. [1]
  X. Chen, N. Li, Z. Kong, et al., Mater. Horiz. 5(2018) 9-27. doi: 10.1039/C7MH00557A
2. [2]
  X. Cui, C. Tang, Q. Zhang, Adv. Energy Mater. 8(2018) 1800369. doi: 10.1002/aenm.201800369
3. [3]
  S.L. Foster, S.I.P. Bakovic, R.D. Duda, et al., Nat. Catal. 1(2018) 490-500. doi: 10.1038/s41929-018-0092-7
4. [4]
  K. Ithisuphalap, H. Zhang, L. Guo, et al., Small Method. 3(2018) 1800352.
5. [5]
  D. Yan, H. Li, C. Chen, et al., Small Method. 3(2018)1800331.
6. [6]
  P. Wang, F. Chang, W. Gao, et al., Nat. Chem. 9(2017) 64-70. doi: 10.1038/nchem.2595
7. [7]
  M. Kitano, Y. Inoue, Y. Yamazaki, et al., Nat. Chem. 4(2012) 934-940. doi: 10.1038/nchem.1476
8. [8]
  D. Bao, Q. Zhang, F.L. Meng, et al., Adv. Mater. 29(2017) 1700001. doi: 10.1002/adma.201700001
9. [9]
  Y. Gong, J. Wu, M. Kitano, et al., Nat. Catal. 1(2018) 178-185. doi: 10.1038/s41929-017-0022-0
10. [10]
  L. Han, X. Liu, J. Chen, et al., Angew. Chem. Int. Ed. 58(2019) 2321-2325. doi: 10.1002/anie.201811728
11. [11]
  B.M. Hoffman, D. Lukoyanov, Z.Y. Yang, et al., Chem. Rev.114(2014) 4041-4062. doi: 10.1021/cr400641x
12. [12]
  J.S. Anderson, J. Rittle, J.C. Peters, Nature 501(2013) 84-87. doi: 10.1038/nature12435
13. [13]
  G. Ung, J.C. Peters, Angew. Chem. Int. Ed. 54(2015) 532-535.
14. [14]
  R.B. Yelle, J.L. Crossland, N.K. Szymczak, D.R. Tyler, Inorg. Chem. Front. 48(2008) 861-871.
15. [15]
  K.C. MacLeod, P.L. Holland, Nat. Chem. 5(2013) 559-565. doi: 10.1038/nchem.1620
16. [16]
  J. Liu, M.S. Kelley, W. Wu, et al., P. Natl. Acad. Sci. U. S. A. 113(2016) 5530-5535. doi: 10.1073/pnas.1605512113
17. [17]
  A. Banerjee, B.D. Yuhas, E.A. Margulies, et al., J. Am. Chem. Soc. 137(2015) 2030-2034. doi: 10.1021/ja512491v
18. [18]
  K.A. Brown, D.F. Harris, M.B. Wilker, et al., Science 352(2016) 448-450. doi: 10.1126/science.aaf2091
19. [19]
  X. Guo, H. Du, F. Qu, J. Li, J. Mater, Chem. A 7(2019) 3531-3543.
20. [20]
  Z. Lei, J. Zhan, L. Tang, et al., Adv. Energy Mater. 8(2018) 1703482. doi: 10.1002/aenm.201703482
21. [21]
  L. Zhang, X. Ji, X. Ren, et al., Adv. Mater. 30(2018) 1800191. doi: 10.1002/adma.201800191
22. [22]
  S. Sun, X. Li, W. Wang, et al., App. Catal. B -Environ. 200(2017) 323-329. doi: 10.1016/j.apcatb.2016.07.025
23. [23]
  L.M. S.C.H. Azofra, L. Cavallo, D.R. Macfarlane, Chem. Eur. J. 23(2017) 8275-8279. doi: 10.1002/chem.201701113
24. [24]
  S. Liu, M. Wang, T. Qian, et al., Nat. Commun. 10(2019) 3898. doi: 10.1038/s41467-019-11846-x
25. [25]
  S.Z. Andersen, V. Colic, S. Yang, et al., Nature 570(2019) 504-508. doi: 10.1038/s41586-019-1260-x
26. [26]
  B. Hu, M. Hu, L. Seefeldt, T.L. Liu, ACS Energy Lett. 4(2019) 1053-1054. doi: 10.1021/acsenergylett.9b00648
27. [27]
  P. Chen, W. Xu, Y. Gao, et al., ACS Appl. Nano Mater. 1(2018) 6976-6988. doi: 10.1021/acsanm.8b01792
28. [28]
  H. Dong, Y. Xu, C. Zhang, et al., Inorg. Chem. Front. 5(2018) 3099-3105. doi: 10.1039/C8QI00969D
29. [29]
  Z. He, R. Zhao, X. Chen, et al., ACS Appl. Mater. Interfaces 10(2018) 42524-42533. doi: 10.1021/acsami.8b17145
30. [30]
  L. Zhang, M. Li, A. Zou, et al., ACS Appl. Energy Mater. 2(2018) 493-502.
31. [31]
  W. Jia, X. Zhou, Y. Huang, et al., ChemCatChem 11(2018) 707-714.
1. [1]
  Sajid Mahmood , Haiyan Wang , Fang Chen , Yijun Zhong , Yong Hu . Recent progress and prospects of electrolytes for electrocatalytic nitrogen reduction toward ammonia. Chinese Chemical Letters, 2024, 35(4): 108550-. doi: 10.1016/j.cclet.2023.108550
2. [2]
  Hong-Rui Li , Xia Kang , Rui Gao , Miao-Miao Shi , Bo Bi , Ze-Yu Chen , Jun-Min Yan . Interfacial interactions of Cu/MnOOH enhance ammonia synthesis from electrochemical nitrate reduction. Chinese Chemical Letters, 2025, 36(2): 109958-. doi: 10.1016/j.cclet.2024.109958
3. [3]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
4. [4]
  Haijiao Liu , Qiao Feng , Yu Huang , Feng Wu , Yali Liu , Minxia Shen , Xiao Guo , Wenting Dai , Weining Qi , Yifan Zhang , Lu Li , Qiyuan Wang , Bianhong Zhou , Jianjun Li . Composition and size distribution of wintertime inorganic aerosols at ground and alpine regions of northwest China. Chinese Chemical Letters, 2024, 35(11): 109636-. doi: 10.1016/j.cclet.2024.109636
5. [5]
  Ting Xie , Xun He , Lang He , Kai Dong , Yongchao Yao , Zhengwei Cai , Xuwei Liu , Xiaoya Fan , Tengyue Li , Dongdong Zheng , Shengjun Sun , Luming Li , Wei Chu , Asmaa Farouk , Mohamed S. Hamdy , Chenggang Xu , Qingquan Kong , Xuping Sun . CoSe₂ nanowire array enabled highly efficient electrocatalytic reduction of nitrate for ammonia synthesis. Chinese Chemical Letters, 2024, 35(11): 110005-. doi: 10.1016/j.cclet.2024.110005
6. [6]
  Junan Pan , Xinyi Liu , Huachao Ji , Yanwei Zhu , Yanling Zhuang , Kang Chen , Ning Sun , Yongqi Liu , Yunchao Lei , Kun Wang , Bao Zang , Longlu Wang . The strategies to improve TMDs represented by MoS₂ electrocatalytic oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(11): 109515-. doi: 10.1016/j.cclet.2024.109515
7. [7]
  Ying Chen , Xingyuan Xia , Lei Tian , Mengying Yin , Ling-Ling Zheng , Qian Fu , Daishe Wu , Jian-Ping Zou . Constructing built-in electric field via CuO/NiO heterojunction for electrocatalytic reduction of nitrate at low concentrations to ammonia. Chinese Chemical Letters, 2024, 35(12): 109789-. doi: 10.1016/j.cclet.2024.109789
8. [8]
  Jiayu Huang , Kuan Chang , Qi Liu , Yameng Xie , Zhijia Song , Zhiping Zheng , Qin Kuang . Fe-N-C nanostick derived from 1D Fe-ZIFs for Electrocatalytic oxygen reduction. Chinese Journal of Structural Chemistry, 2023, 42(10): 100097-100097. doi: 10.1016/j.cjsc.2023.100097
9. [9]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
10. [10]
  Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS₂/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054
11. [11]
  Xiangyu Chen , Aihao Xu , Dong Wei , Fang Huang , Junjie Ma , Huibing He , Jing Xu . Atomic cerium-doped CuO_x catalysts for efficient electrocatalytic CO₂ reduction to CH₄. Chinese Chemical Letters, 2025, 36(1): 110175-. doi: 10.1016/j.cclet.2024.110175
12. [12]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
13. [13]
  Jingtai Bi , Yupeng Cheng , Mengmeng Sun , Xiaofu Guo , Shizhao Wang , Yingying Zhao . Efficient and selective photocatalytic nitrite reduction to N₂ through CO₂ anion radical by eco-friendly tartaric acid activation. Chinese Chemical Letters, 2024, 35(11): 109639-. doi: 10.1016/j.cclet.2024.109639
14. [14]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
15. [15]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
16. [16]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
17. [17]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
18. [18]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
19. [19]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
20. [20]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(1051)
HTML views(119)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fe doping promoted electrocatalytic N2 reduction reaction of 2H MoS2

Metrics

通讯作者: 陈斌, bchen63@163.com

Fe doping promoted electrocatalytic N₂ reduction reaction of 2H MoS₂