Citation: Zhu Zhigao, Zhong Lingling, Wang Yu, Zeng Gaofeng, Wang Wei. Mechanically durable biomimetic fibrous membrane with superhydrophobicity and superoleophilicity for aqueous oil separation[J]. Chinese Chemical Letters, ;2020, 31(10): 2619-2622. doi: 10.1016/j.cclet.2020.01.038 shu

Mechanically durable biomimetic fibrous membrane with superhydrophobicity and superoleophilicity for aqueous oil separation

Zhu Zhigao ^a ,
Zhong Lingling ^b ,
Wang Yu ^c ,
Zeng Gaofeng ^d ,
Wang Wei ^b,*,

a.
Key Laboratory of New Membrane Materials, Ministry of Industry and Information Technology, School of Environment and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
b.
State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, China
c.
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
d.
CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China

wangweirs@hit.edu.cn

Received Date: 17 December 2019
Revised Date: 10 January 2020
Accepted Date: 17 January 2020
Available Online: 22 January 2020

Figures(4)

Developing an effective and mechanically durable biomimetic membrane for the separation of highly emulsified aqueous oil is significant but challenging owing to its low water flux and serious membrane fouling. In this work, a biomimetic membrane with superhydrophobicity and superoleophilicity was rationally developed via co-electrospinning of polysulfonamide/polyacrylonitrile (PSA/PAN) emulsion solution, followed by decorating of α-Fe₂O₃ nanowire onto the membrane surface to create membrane roughness, and grafting of 1H, 1H, 2H, 2H-perfluorododecyltrichlorosilane (FTCS) to lower membrane surface free energy. Benefiting from the nanowire-wrapped rough membrane structure and the low surface free energy FTCS, the resultant membrane showed superhydrophobicity with a high water contact angle (WCA) of 156°, superoleophilicity with a low oil contact angle (OCA) of 0°, which can separate the highly emulsified aqueous oil with an ultrahigh permeation flux over 7000 L m^-2 h^-1 and high separation efficiency of about 99%. Significantly, the biomimetic membrane also displayed robust stability for long-term separation owing to its advantage of antifouling property, showing great potential applications in large-scale aqueous oil treatment.
- Emulsion electrospinning,
- High-strength fibrous membrane,
- Polysulfonamide/polyacrylonitrile,
- α-Fe₂O₃ nanowire,
- Aqueous oil separation
1. [1]
  X. Li, G. Chen, H. Zhu, Process Saf. Environ. Prot. 103 (2016) 163-173. doi: 10.1016/j.psep.2016.06.006
2. [2]
  G.V. Chilingar, B. Endres, Environ. Geol. 47 (2004) 302-317.
3. [3]
  S. Gao, J. Sun, P. Liu, et al., Adv. Mater. 28 (2016) 5307-5314. doi: 10.1002/adma.201600417
4. [4]
  J. Wu, N. Wang, L. Wang, et al., ACS Appl. Mater. Interfaces 4 (2012) 3207-3212. doi: 10.1021/am300544d
5. [5]
  H. Chakibi, I. Hénaut, A. Salonen, D. Langevin, J.F. Argillier, Energy. Fuel. 32 (2018) 4049-4056. doi: 10.1021/acs.energyfuels.7b04053
6. [6]
  A.L. Ahmad, S. Ismail, S. Bhatia, Environ. Sci. Technol. 39 (2005) 2828-2834. doi: 10.1021/es0498080
7. [7]
  Y. Peng, T. Liu, H. Gong, X. Zhang, Appl. Petrochem. Res. 6 (2016) 389-395. doi: 10.1007/s13203-016-0165-y
8. [8]
  J. Lin, F. Lin, R. Liu, et al., Sep. Purif. Technol. 231 (2020) 115898. doi: 10.1016/j.seppur.2019.115898
9. [9]
  S. Gao, Y. Zhu, J. Wang, et al., Adv. Funct. Mater. 28 (2018) 1801944. doi: 10.1002/adfm.201801944
10. [10]
  G.M. Shi, M.H.D.A. Farahani, J.Y. Liu, T.S. Chung, J. Membr. Sci. 588 (2019) 117202. doi: 10.1016/j.memsci.2019.117202
11. [11]
  J. Ge, D. Zong, Q. Jin, J. Yu, B. Ding, Adv. Funct. Mater. 28 (2018) 1705051. doi: 10.1002/adfm.201705051
12. [12]
  D. Li, X. Gou, D. Wu, Z. Guo, Nanoscale 10 (2018) 6695-6703. doi: 10.1039/C8NR01274A
13. [13]
  S. Zhang, G. Jiang, S. Gao, et al., ACS Nano 12 (2018) 795-803. doi: 10.1021/acsnano.7b08121
14. [14]
  Z. Zhu, Z. Li, L. Zhong, et al., J. Membr. Sci. 572 (2019) 73-81. doi: 10.1016/j.memsci.2018.10.071
15. [15]
  L. Feng, Z. Zhang, Z. Mai, et al., Angew. Chem. Int. Ed. 116 (2004) 2046-2048. doi: 10.1002/ange.200353381
16. [16]
  W. Zhang, Z. Shi, F. Zhang, et al., Adv. Mater. 25 (2013) 2071-2076. doi: 10.1002/adma.201204520
17. [17]
  W. Zhang, Y. Zhu, X. Liu, et al., Angew Chem. Int. Ed. 53 (2014) 856-860. doi: 10.1002/anie.201308183
18. [18]
  N. Wang, Y. Zhai, Y. Yang, X. Yang, Z. Zhu, Chem. Eng. J. 354 (2018) 463-472. doi: 10.1016/j.cej.2018.08.019
19. [19]
  J. Ge, J. Zhang, F. Wang, et al., J. Mater. Chem. A 5 (2017) 497-502. doi: 10.1039/C6TA07652A
20. [20]
  X. Tang, Y. Si, J. Ge, et al., Nanoscale 5 (2013) 11657-11664. doi: 10.1039/c3nr03937d
21. [21]
  K.Y. Hua, C.M. Deng, C. He, et al., Chin. Chem. Lett. 24 (2013) 643-646. doi: 10.1016/j.cclet.2013.04.033
22. [22]
  Z. Zhu, Y. Liu, H. Hou, et al., Environ. Sci. Technol. 52 (2018) 3027-3036. doi: 10.1021/acs.est.7b06227
23. [23]
  Z. Zhu, L. Zhong, Z. Zhang, et al., J. Mater. Chem. A 5 (2017) 25266-25275. doi: 10.1039/C7TA08529J
24. [24]
  N. Wang, Z. Zhu, J. Sheng, et al., J. Colloid Interface Sci. 428 (2014) 41-48. doi: 10.1016/j.jcis.2014.04.026
25. [25]
  L. Zhong, Z. Zhu, Y. Han, et al., Environ. Sci. Nano 6 (2019) 2553-2564. doi: 10.1039/C9EN00450E
26. [26]
  M. Huang, Y. Si, X. Tang, et al., J. Mater. Chem. A 1 (2013) 14071-14074. doi: 10.1039/c3ta13385k
27. [27]
  A. Raza, B. Ding, G. Zainab, et al., J. Mater. Chem. A 2 (2014) 10137-10145. doi: 10.1039/C4TA00806E
28. [28]
  Y. Xu, J. Ma, Y. Han, et al., ACS Sustain. Chem. Eng. 7 (2019) 5476-5485. doi: 10.1021/acssuschemeng.8b06679
29. [29]
  Y. Li, M. Li, J. Zhang, X. Xu, Chin. Chem. Lett. 30 (2019) 762-766. doi: 10.1016/j.cclet.2018.11.005
30. [30]
  W. Chen, B. Xin, X. Wu, J. Ind. Text. 44 (2014) 159-179. doi: 10.1177/1528083713481834
31. [31]
  Q. Xu, Q. Kong, Z. Liu, et al., ACS Sustain. Chem. Eng. 2 (2013) 194-199.
32. [32]
  Z. Zhu, W. Wang, D. Qi, et al., Adv. Mater. 30 (2018) 1801870. doi: 10.1002/adma.201801870
33. [33]
  L. Sabantina, M. Rodríguez-Cano, M. Klöcker, et al., Polymers 10 (2018) 735. doi: 10.3390/polym10070735
34. [34]
  T.D. Deshpande, Y.R. Singh, S. Patil, Y.M. Joshi, A. Sharma, Soft Matter 14 (2018) 7829-7838. doi: 10.1039/C8SM01271G
35. [35]
  Y. Li, Z. Zhu, J. Yu, B. Ding, ACS Appl. Mater. Interfaces 7 (2015) 13538-13546. doi: 10.1021/acsami.5b02848
36. [36]
  A. Greiner, J.H. Wendorff, Angew. Chem. Int. Ed. 46 (2007) 5670-5703. doi: 10.1002/anie.200604646
37. [37]
  Z. Zhu, Z. Liu, L. Zhong, et al., J. Membr. Sci. 563 (2018) 602-609. doi: 10.1016/j.memsci.2018.06.028
38. [38]
  Z. Zhu, P. Wu, G. Liu, et al., Chem. Eng. J. 313 (2017) 957-966. doi: 10.1016/j.cej.2016.10.145
39. [39]
  R.N. Wenzel, Ind. Eng. Chem. Res. 28 (1936) 988-994. doi: 10.1021/ie50320a024
40. [40]
  A. Cassie, S. Baxter, Trans. Faraday Soc. 40 (1944) 546-551. doi: 10.1039/tf9444000546
41. [41]
  X. Bao, Q. Wu, W. Shi, et al., Water Res. 153 (2019) 1-10. doi: 10.1016/j.watres.2018.12.067
42. [42]
  Y. Zheng, Y. Cheng, Y. Wang, et al., J. Phys. Chem. B 110 (2006) 3093-3097.
43. [43]
  Q. Liu, C. Chen, G. Yuan, et al., J. Alloys. Compd. 715 (2017) 230-236. doi: 10.1016/j.jallcom.2017.04.213
44. [44]
  J.J. Cras, C.A. Rowetaitt, D.A. Nivens, F.S. Ligler, Biosens. Bioelectron. 14 (1999) 683-688. doi: 10.1016/S0956-5663(99)00043-3
45. [45]
  M.K.K. Oo, Y. Yang, Y. Hu, et al., ACS Nano 6 (2012) 1939-1947. doi: 10.1021/nn300327c
46. [46]
  Z. Zhu, G. Li, G. Zeng, et al., J. Mater. Chem. A 3 (2015) 22000-22004. doi: 10.1039/C5TA06310H
1. [1]
  Yan Zou , Yin-Shuang Hu , Deng-Hui Tian , Hong Wu , Xiaoshu Lv , Guangming Jiang , Yu-Xi Huang . Tuning the membrane rejection behavior by surface wettability engineering for an effective water-in-oil emulsion separation. Chinese Chemical Letters, 2024, 35(6): 109090-. doi: 10.1016/j.cclet.2023.109090
2. [2]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820
3. [3]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
4. [4]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
5. [5]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
6. [6]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
7. [7]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
8. [8]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
9. [9]
  Tsegaye Tadesse Tsega , Jiantao Zai , Chin Wei Lai , Xin-Hao Li , Xuefeng Qian . Earth-abundant CuFeS2 nanocrystals@graphite felt electrode for high performance aqueous polysulfide/iodide redox flow batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100192-100192. doi: 10.1016/j.cjsc.2024.100192
10. [10]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
11. [11]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
12. [12]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
13. [13]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
14. [14]
  Yuan CONG , Yunhao WANG , Wanping LI , Zhicheng ZHANG , Shuo LIU , Huiyuan GUO , Hongyu YUAN , Zhiping ZHOU . Construction and photocatalytic properties toward rhodamine B of CdS/Fe₃O₄ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2241-2249. doi: 10.11862/CJIC.20240219
15. [15]
  Yujuan Zhao , Zaiwang Zhao . Monolayer mesoporous nanosheets with surface asymmetry via a dual-emulsion-directed monomicelle assembly. Chinese Journal of Structural Chemistry, 2024, 43(2): 100238-100238. doi: 10.1016/j.cjsc.2024.100238
16. [16]
  Xiujuan Wang , Yijie Wang , Luyun Cui , Wenqiang Gao , Xiao Li , Hong Liu , Weijia Zhou , Jingang Wang . Coordination-based synthesis of Fe single-atom anchored nitrogen-doped carbon nanofibrous membrane for CO₂ electroreduction with nearly 100% CO selectivity. Chinese Chemical Letters, 2024, 35(12): 110031-. doi: 10.1016/j.cclet.2024.110031
17. [17]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
18. [18]
  Xiaoxing Ji , Xiaojuan Li , Chenggang Wang , Gang Zhao , Hongxia Bu , Xijin Xu . Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery. Chinese Chemical Letters, 2024, 35(10): 109388-. doi: 10.1016/j.cclet.2023.109388
19. [19]
  Lingjiang Kou , Yong Wang , Jiajia Song , Taotao Ai , Wenhu Li , Mohammad Yeganeh Ghotbi , Panya Wattanapaphawong , Koji Kajiyoshi . Mini review: Strategies for enhancing stability of high-voltage cathode materials in aqueous zinc-ion batteries. Chinese Chemical Letters, 2025, 36(1): 110368-. doi: 10.1016/j.cclet.2024.110368
20. [20]
  Xiaobo Li , Qunyan Wu , Congzhi Wang , Jianhui Lan , Meng Zhang , Weiqun Shi . Theoretical perspectives on the reduction of Pu(Ⅳ) and Np(Ⅵ) by methylhydrazine in HNO₃ solution: Implications for Np/Pu separation. Chinese Chemical Letters, 2024, 35(7): 109359-. doi: 10.1016/j.cclet.2023.109359

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(613)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142