Citation: Zhang Dan, Zhang Yuqin, Fan Yu, Luo Na, Cheng Zhixuan, Xu Jiaqiang. Micro-spherical ZnSnO₃ material prepared by microwave-assisted method and its ethanol sensing properties[J]. Chinese Chemical Letters, ;2020, 31(8): 2087-2090. doi: 10.1016/j.cclet.2020.01.004 shu

Micro-spherical ZnSnO₃ material prepared by microwave-assisted method and its ethanol sensing properties

NEST Lab, Department of Physics, Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, China

zxcheng@shu.edu.cn

xujiaqiang@shu.edu.cn

Received Date: 27 November 2019
Revised Date: 25 December 2019
Accepted Date: 2 January 2020
Available Online: 3 January 2020

Figures(5)

Monodispersed ZnSnO₃ microspheres are successfully prepared via a facile microwave-assisted method together with subsequently calcination treatment. Powder X-ray diffraction (PXRD) results indicate that the structure of the products shifted from crystalline to amorphous under high-temperature treatments. Field emission scanning electron microscope (FESEM) and the transmission electron microscope (TEM) observations demonstrate that the as-obtained products are composed of uniform microspheres with rough surfaces and the mean diameter is measured as ~700 nm. Moreover, the morphology of ZnSnO₃ microspheres can be well controlled by adjusting the ratio of Zn²⁺ and Sn⁴⁺. The gas sensing properties of ZnSnO₃ microspheres with different ratios of Zn²⁺/Sn⁴⁺ are investigated. Our results indicate that the ZnSnO₃ microspheres exhibit good selectivity and high sensitivity towards ethanol at the optimum working temperature of 230 ℃. When the sensor is exposed 50 ppm ethanol, the value of response is 47 and the response/recovery times are 11 s and 12 s, respectively.
- ZnSnO₃ microspheres,
- Microwave synthesis,
- Morphology,
- Ethanol,
- Gas sensor
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Micro-spherical ZnSnO3 material prepared by microwave-assisted method and its ethanol sensing properties

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Micro-spherical ZnSnO₃ material prepared by microwave-assisted method and its ethanol sensing properties