Citation: Liu Yueli, Sang Binghua, Wang Haoran, Wu Zijing, Wang Yuxuan, Wang Ziwei, Peng Zhuoyin, Chen Wen. High ammonia sensitive ability of novel Cu₁₂Sb₄S₁₃ quantum dots@reduced graphene oxide nanosheet composites at room temperature[J]. Chinese Chemical Letters, ;2020, 31(8): 2109-2114. doi: 10.1016/j.cclet.2019.12.030 shu

High ammonia sensitive ability of novel Cu₁₂Sb₄S₁₃ quantum dots@reduced graphene oxide nanosheet composites at room temperature

Liu Yueli ^a ,
Sang Binghua ^a ,
Wang Haoran ^a ,
Wu Zijing ^a ,
Wang Yuxuan ^a ,
Wang Ziwei ^a ,
Peng Zhuoyin ^c,*, ,
Chen Wen ^b,*,

a.
State Key Laboratory of Silicate Materials for Architectures, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
b.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
c.
The Key Laboratory of Efficient & Clean Energy Utilization, School of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410111, China

joeypengzy@outlook.com

chenw@whut.edu.cn

Received Date: 10 October 2019
Revised Date: 4 December 2019
Accepted Date: 24 December 2019
Available Online: 24 December 2019

Figures(4)

In the work, rGO nanosheet is synthesized using the typical Hummer's method, then Cu₁₂Sb₄S₁₃ quantum dots@rGO composites are prepared by solvent thermal method, and Cu₁₂Sb₄S₁₃ quantum dots with the average size of 5 nm are densely distributed on the surface of rGO sheet. NH₃ gas response of Cu₁₂Sb₄S₁₃ quantum dots@rGO nanosheet composites at room temperature of 25 ℃ is enhanced compared with the pure Cu₁₂Sb₄S₁₃ quantum dots and rGO nanosheet, and the composites possess an excellent stability during the humidity range of 45%-80% with a low detection limit of 1 ppm, which is related with the intrinsic hydrophobicity characteristic of Cu₁₂Sb₄S₁₃ quantum dots. It also proves that Cu₁₂Sb₄S₁₃ quantum dots@rGO nanosheet composites have a quite high selectivity towards ammonia compared with ethanol, methanol, acetone, toluene, hydrogen sulfide and nitrogen dioxide at room temperature. The gas sensing mechanism of the composites is discussed primarily.
- Cu₁₂Sb₄S₁₃ quantum dots@rGO nanosheet,
- Composites,
- NH₃,
- Room temperature,
- Gas response
1. [1]
  J. Bai, B.X. Zhou, Chem. Rev. 114(2014) 10131-10176. doi: 10.1021/cr400625j
2. [2]
  Y.K. Li, J.J. Zhang, Z.J. Bian, et al., Chin. Chem. Lett. 27(2016) 518-522. doi: 10.1016/j.cclet.2016.01.056
3. [3]
  L.Liu, X.M.Yu, B.Zhang, S.X.Meng, Y.Q.Feng, Chin.Chem.Lett.28(2017)765-770. doi: 10.1016/j.cclet.2017.03.011
4. [4]
  B. Timmer, W. Olthuis, A. Van Den Berg, Sens. Actuator. B-Chem. 107(2005) 666-677. doi: 10.1016/j.snb.2004.11.054
5. [5]
  Y. Li, X. Wang, C.Y. Xing, et al., Chin. Chem. Lett. 30(2019) 1440-1444. doi: 10.1016/j.cclet.2019.03.014
6. [6]
  W.C. Wang, F.Q. Liu, B. Wang, Y.D. Wang, Chin. Chem. Lett. 30(2019) 1261-1265. doi: 10.1016/j.cclet.2018.12.030
7. [7]
  V. Modafferi, G. Panzera, A. Donato, et al., Sens. Actuator. B-Chem. 163(2012) 61-68. doi: 10.1016/j.snb.2012.01.007
8. [8]
  K. Xu, N. Li, D.W. Zeng, et al., ACS Appl. Mater. Interfaces 7(2015) 11359-11368. doi: 10.1021/acsami.5b01856
9. [9]
  J. Wang, P. Yang, X.W. Wei, ACS Appl. Mater. Interfaces 7(2015) 3816-3824. doi: 10.1021/am508807a
10. [10]
  A.K. Prasad, D.J. Kubinski, P.I. Gouma, Sens. Actuator. B-Chem. 93(2003) 25-30. doi: 10.1016/S0925-4005(03)00336-8
11. [11]
  Q. Zhang, H. Zhang, M.K. Xu, Z.R. Shen, Q. Wei, Chin. Chem. Lett. 30(2019) 1261-1265. doi: 10.1016/j.cclet.2018.12.030
12. [12]
  H. Liu, M. Li, O. Voznyy, et al., Adv. Mater. 26(2014) 2718-2724. doi: 10.1002/adma.201304366
13. [13]
  M. Epifani, E. Comini, R. Díaz, et al., ACS Appl. Mater. Interfaces 6(2014) 16808-16816. doi: 10.1021/am504158r
14. [14]
  A. Rothschild, Y. Komem, J. Appl. Phys. 95(2004) 6374-6380. doi: 10.1063/1.1728314
15. [15]
  B.H. Zhang, M. Li, Z.L. Song, et al., Sens. Actuators B-Chem. 249(2017) 558-563. doi: 10.1016/j.snb.2017.03.098
16. [16]
  J.P. Du, R.H. Zhao, Y.J. Xie, J.P. Li, Appl. Surf. Sci. 346(2015) 256-262. doi: 10.1016/j.apsusc.2015.04.011
17. [17]
  M. Li, J.T. Luo, C. Fu, et al., Sens. Actuator. B-Chem. 256(2018) 1045-1056. doi: 10.1016/j.snb.2017.10.047
18. [18]
  L. Wang, B. Yang, Z. Xia, et al., Sol. Energy Mater. Sol. Cells 144(2016) 33-39. doi: 10.1016/j.solmat.2015.08.016
19. [19]
  K.Q. Chen, J. Zhou, W. Chen, et al., Part. Part. Syst. Charact. 32(2015) 999-1005. doi: 10.1002/ppsc.201500088
20. [20]
  K.Q. Chen, J. Zhou, W. Chen, et al., Nanoscale 8(2016) 5146-5152. doi: 10.1039/C5NR09097K
21. [21]
  M. Thripuranthaka, N. Sharma, T. Das, et al., Adv. Mater. Interfaces 5(2018) 1701492. doi: 10.1002/admi.201701492
22. [22]
  Z. Song, Z. Wei, B. Wang, et al., Chem. Mater. 28(2016) 1205-1212. doi: 10.1021/acs.chemmater.5b04850
23. [23]
  L. Zhou, F. Shen, X. Tian, et al., Nanoscale 5(2013) 1564-1569. doi: 10.1039/c2nr33164k
24. [24]
  R.K. Mishra, S.B. Upadhyay, A. Kushwaha, et al., Nanoscale 7(2015) 11971-11979. doi: 10.1039/C5NR02837J
25. [25]
  Y.L.Liu, H.R. Wang, S. Yang, et al., Sens. Actuator. B-Chem. 255(2018) 2979-2987. doi: 10.1016/j.snb.2017.09.120
26. [26]
  Y.L. Liu, H.R. Wang, K.Q. Chen, et al., ACS Appl. Mater. Interfaces 11(2019) 9573-9588. doi: 10.1021/acsami.8b20830
27. [27]
  K.Q. Chen, J. Zhou, W. Chen, et al., Nanoscale 9(2017) 12470-12478. doi: 10.1039/C7NR03576D
28. [28]
  Y.L.Liu, L.L. Wang, H.R. Wang, etal., Sens. Actuator. B-Chem.236(2016)529-536. doi: 10.1016/j.snb.2016.06.037
29. [29]
  L. Zhang, Y. Li, X. Li, et al., Nano Energy 28(2016) 135-142. doi: 10.1016/j.nanoen.2016.08.036
30. [30]
  L. Dou, H. Zhang, J. Mater. Chem. A 4(2016) 18990-19002. doi: 10.1039/C6TA08313G
31. [31]
  G. Lee, M.R. Jo, K. Zhang, Y. Kang, J. Mater. Chem. A 5(2017) 3683-3690. doi: 10.1039/C6TA09967J
32. [32]
  R. Ghosh, A. Midya, S. Santra, S.K. Ray, P.K. Guha, ACS Appl. Mater. Interfaces 5(2013) 7599-7603. doi: 10.1021/am4019109
33. [33]
  W. Chen, F. Li, P.C. Ooi, et al., Sens. Actuator. B-Chem. 222(2016) 763-768. doi: 10.1016/j.snb.2015.09.002
34. [34]
  J.N. Gavgani, A. Hasani, M. Nouri, M. Mahyari, A. Salehi, Sens. Actuator. B-Chem. 229(2016) 239-248. doi: 10.1016/j.snb.2016.01.086
35. [35]
  J. Fan, P. Ning, Z. Song, et al., Chem. Eng. J. 334(2018) 855-863. doi: 10.1016/j.cej.2017.10.011
36. [36]
  Y. Chen, Z. Zhang, L. Liu, L. Mi, X. Wang, Appl. Surf. Sci. 366(2016) 139-147. doi: 10.1016/j.apsusc.2016.01.052
37. [37]
  A. Rothschild, Y. Komem, J. Appl. Phys. 95(2004) 6374-6380. doi: 10.1063/1.1728314
38. [38]
  Y.L. Liu, Q. Chen, A.H. Mei, et al., Sustain. Energy Fuels 3(2019) 831-840. doi: 10.1039/C9SE00003H
39. [39]
  J. Zhang, X.H. Liu, G. Neri, N. Pinna, Adv. Mater. 28(2016) 795-831. doi: 10.1002/adma.201503825
40. [40]
  J.H. Lee, A. Katoch, S.W. Choi, et al., ACS Appl. Mater. Interfaces 7(2015) 3101-3109. doi: 10.1021/am5071656
1. [1]
  Hao Deng , Yuxin Hui , Chao Zhang , Qi Zhou , Qiang Li , Hao Du , Derek Hao , Guoxiang Yang , Qi Wang . MXene−derived quantum dots based photocatalysts: Synthesis, application, prospects, and challenges. Chinese Chemical Letters, 2024, 35(6): 109078-. doi: 10.1016/j.cclet.2023.109078
2. [2]
  Jia Fu , Shilong Zhang , Lirong Liang , Chunyu Du , Zhenqiang Ye , Guangming Chen . PEDOT-based thermoelectric composites: Preparation, mechanism and applications. Chinese Chemical Letters, 2024, 35(9): 109804-. doi: 10.1016/j.cclet.2024.109804
3. [3]
  Cuiwu MO , Gangmin ZHANG , Chao WU , Zhipeng HUANG , Chi ZHANG . A(NH₂SO₃) (A=Li, Na): Two ultraviolet transparent sulfamates exhibiting second harmonic generation response. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1387-1396. doi: 10.11862/CJIC.20240045
4. [4]
  Yan Wang , Si-Meng Zhai , Peng Luo , Xi-Yan Dong , Jia-Yin Wang , Zhen Han , Shuang-Quan Zang . Vapor- and temperature-triggered reversible optical switching for multi-response Cu₈ cluster supercrystals. Chinese Chemical Letters, 2024, 35(11): 109493-. doi: 10.1016/j.cclet.2024.109493
5. [5]
  Dian-Xue Ma , Yu-Wu Zhong . Achieving highly-efficient room-temperature phosphorescence with a nylon matrix. Chinese Journal of Structural Chemistry, 2024, 43(9): 100391-100391. doi: 10.1016/j.cjsc.2024.100391
6. [6]
  Xiao-Tong Sun , Hao-Fei Ni , Yi Zhang , Da-Wei Fu . Hybrid perovskite shows temperature-dependent photoluminescence and dielectric response triggered by halogen substitution. Chinese Journal of Structural Chemistry, 2024, 43(6): 100212-100212. doi: 10.1016/j.cjsc.2024.100212
7. [7]
  Kun Zhang , Ni Dan , Dan-Dan Ren , Ruo-Yu Zhang , Xiaoyan Lu , Ya-Pan Wu , Li-Lei Zhang , Hong-Ru Fu , Dong-Sheng Li . A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(3): 100244-100244. doi: 10.1016/j.cjsc.2024.100244
8. [8]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
9. [9]
  Jianmei Guo , Yupeng Zhao , Lei Ma , Yongtao Wang . Ultra-long room temperature phosphorescence, intrinsic mechanisms and application based on host-guest doping systems. Chinese Journal of Structural Chemistry, 2024, 43(9): 100335-100335. doi: 10.1016/j.cjsc.2023.100335
10. [10]
  Jiayin Zhou , Depeng Liu , Longqiang Li , Min Qi , Guangqiang Yin , Tao Chen . Responsive organic room-temperature phosphorescence materials for spatial-time-resolved anti-counterfeiting. Chinese Chemical Letters, 2024, 35(11): 109929-. doi: 10.1016/j.cclet.2024.109929
11. [11]
  Shuai Zhu , Mingjie Chen , Haichao Shen , Hanming Ding , Wenbo Li , Junliang Zhang . Palladium/Xu-Phos-catalyzed enantioselective arylalkoxylation reaction of γ-hydroxyalkenes at room temperature. Chinese Chemical Letters, 2024, 35(11): 109879-. doi: 10.1016/j.cclet.2024.109879
12. [12]
  Qian Wang , Ting Gao , Xiwen Lu , Hangchao Wang , Minggui Xu , Longtao Ren , Zheng Chang , Wen Liu . Nanophase separated, grafted alternate copolymer styrene-maleic anhydride as an efficient room temperature solid state lithium ion conductor. Chinese Chemical Letters, 2024, 35(7): 108887-. doi: 10.1016/j.cclet.2023.108887
13. [13]
  Xin Li , Ling Zhang , Yunyan Fan , Shaojing Lin , Yong Lin , Yongsheng Ying , Meijiao Hu , Haiying Gao , Xianri Xu , Zhongbiao Xia , Xinchuan Lin , Junjie Lu , Xiang Han . Carbon interconnected microsized Si film toward high energy room temperature solid-state lithium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109776-. doi: 10.1016/j.cclet.2024.109776
14. [14]
  Tao Tang , Chen Li , Sipu Li , Zhong Qiu , Tianqi Yang , Beirong Ye , Shaojun Shi , Chunyang Wu , Feng Cao , Xinhui Xia , Minghua Chen , Xinqi Liang , Xinping He , Xin Liu , Yongqi Zhang . One-step constructing advanced N-doped carbon@metal nitride as ultra-stable electrocatalysts via urea plasma under room temperature. Chinese Chemical Letters, 2024, 35(11): 109887-. doi: 10.1016/j.cclet.2024.109887
15. [15]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
16. [16]
  Xiongbo Song , Jinwen Xiao , Juan Wu , Li Sun , Long Chen . Decellularized amniotic membrane promotes the anti-inflammatory response of macrophages via PI3K/AKT/HIF-1α pathway. Chinese Chemical Letters, 2025, 36(1): 109844-. doi: 10.1016/j.cclet.2024.109844
17. [17]
  Feifei Wang , Hang Yao , Xinyue Wu , Yijian Tang , Yang Bai , Hui Chong , Huan Pang . Metal–organic framework and its composites modulate macrophage polarization in the treatment of inflammatory diseases. Chinese Chemical Letters, 2024, 35(5): 108821-. doi: 10.1016/j.cclet.2023.108821
18. [18]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
19. [19]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
20. [20]
  Deqi Fan , Yicheng Tang , Yemei Liao , Yan Mi , Yi Lu , Xiaofei Yang . Two birds with one stone: Functionalized wood composites for efficient photocatalytic hydrogen production and solar water evaporation. Chinese Chemical Letters, 2024, 35(9): 109441-. doi: 10.1016/j.cclet.2023.109441

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(687)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

High ammonia sensitive ability of novel Cu12Sb4S13 quantum dots@reduced graphene oxide nanosheet composites at room temperature

Metrics

通讯作者: 陈斌, bchen63@163.com

High ammonia sensitive ability of novel Cu₁₂Sb₄S₁₃ quantum dots@reduced graphene oxide nanosheet composites at room temperature