Citation: Zhang Nan, Yan Luming, Lu Yang, Fan Yizhuo, Guo Sijia, Adimi Samira, Liu Dali, Ruan Shengping. Metal-organic frameworks-derived hierarchical ZnO structures as efficient sensing materials for formaldehyde detection[J]. Chinese Chemical Letters, ;2020, 31(8): 2071-2076. doi: 10.1016/j.cclet.2019.12.014 shu

Metal-organic frameworks-derived hierarchical ZnO structures as efficient sensing materials for formaldehyde detection

State Key Laboratory on Integrated Optoelectronics and College of Electronic Science & Engineering, Jilin University, Changchun 130012, China

ruansp@jlu.edu.cn

Received Date: 20 November 2019
Revised Date: 3 December 2019
Accepted Date: 5 December 2019
Available Online: 5 December 2019

Figures(4)

Semiconducting metal oxides have been considered as effective approach for designing high-performance chemical sensing materials. In this paper, a kind of metal-organic frameworks ZIF-8 was used as sacrificed template to prepare porous ZnO hollow nanocubes for the application in gas sensing. It is found that changing calcination temperature and solvent can greatly influence the morphology of the material, which finally affects the gas sensing performance. Acetylene-sensing properties of the sensors were investigated in detail. It can be clearly seen that the material used methanol as reaction solvent with the decomposition at 350 ℃ for 2 h (ZnO-350-M) showed the optimal formaldehyde-sensing behaviors compared with other materials prepared in this experiment. The dynamic transients of the ZnO-350-M-based sensors demonstrated a high response value (about 10), fast response and recovery rate (4 s and 4 s, respectively) and good selectivity towards 100 ppm (part per million) formaldehyde as well as a low detectable limit (1 ppm). As exemplified for the sensing investigation towards formaldehyde, the porous ZnO hollow nanocubes showed a significantly improved chemical sensitivity due to the highly synergistic effects from the well exposed surfaces, defect states and the robust ZnO.
- Metal-organic framework,
- ZIF-8,
- Formaldehyde sensing,
- Pore-rich structure,
- ZnO nanocubes
1. [1]
  Q. Zhang, H. Zhang, M.K. Xui, Z.R. Shen, Q. Wei, Chin. Chem. Lett. 24(2014) 224-230.
2. [2]
  W. Zhou, Y.P. Wu, J. Zhao, et al., Inorg. Chem. 56(2017) 14111-14117. doi: 10.1021/acs.inorgchem.7b02254
3. [3]
  S. Wicker, M. Guiltat, U. Weimar, A. Hémeryck, N. Barsan, J. Phys. Chem. C 121(2017) 25064-25073. doi: 10.1021/acs.jpcc.7b06253
4. [4]
  W. Sun, G. Sun, B. Qin, Q. Xin, Sens. Actuator. B-Chem. 128(2007) 193-198. doi: 10.1016/j.snb.2007.06.002
5. [5]
  C.Y. Lee, C.M. Chiang, Y.H. Wang, R.H. Ma, Sens. Actuator. B-Chem. 122(2007) 503-510. doi: 10.1016/j.snb.2006.06.018
6. [6]
  I.Y. Zhang, X. Huang, Q.Y. Shen, J.Y. Wang, G.H. Song, Chin. Chem. Lett. 29(2018) 197-200. doi: 10.1016/j.cclet.2017.05.012
7. [7]
  W. Li, X. Wu, N. Han, et al., Sens. Actuator. B-Chem. 225(2016) 158-166. doi: 10.1016/j.snb.2015.11.034
8. [8]
  W. Xia, C. Mei, X. Zeng, et al., ACS Appl. Mater. Inter. 7(2015) 11824-11832. doi: 10.1021/acsami.5b01333
9. [9]
  N. Wei, H. Cui, X. Wang, et al., J. Colloid Interface Sci. 498(2017) 263-270. doi: 10.1016/j.jcis.2017.03.072
10. [10]
  Q.B. Zhu, X.Y. Shen, L.L. Wang, et al., Chin. Chem. Lett. 29(2018) 1310-1312. doi: 10.1016/j.cclet.2017.12.018
11. [11]
  S. Wang, P. Wang, C. Xiao, et al., Mater. Lett. 131(2014) 358-360. doi: 10.1016/j.matlet.2014.06.015
12. [12]
  A. Umar, S.H. Kim, Y.S. Lee, K.S. Nahm, Y.B. Hahn, J. Cryst. Growth 282(2005) 131-136. doi: 10.1016/j.jcrysgro.2005.04.095
13. [13]
  R. Dang, X.L. Jia, P. Wang, et al., Chin. Chem. Lett. 28(2017) 2263-2268. doi: 10.1016/j.cclet.2017.09.064
14. [14]
  X. Lai, J.E. Halpert, D. Wang, et al., Energy Environ. Sci. 5(2012) 5604-5618. doi: 10.1039/C1EE02426D
15. [15]
  Y. Li, X. Wang, C.Y. Xing, et al., Adv. Mater. 30(2019) 1440-1444.
16. [16]
  B. Liu, H. Shioyama, H. Jiang, X. Zhang, Q. Xu, Carbon 48(2010) 456-463. doi: 10.1016/j.carbon.2009.09.061
17. [17]
  F. Zou, X. Hu, Z. Li, et al., Adv. Mater. 26(2014) 6622-6628. doi: 10.1002/adma.201402322
18. [18]
  G.W. Peterson, S.Y. Moon, G.W. Wagner, et al., Inorg. Chem. 54(2015) 9684-9686. doi: 10.1021/acs.inorgchem.5b01867
19. [19]
  J.R. Li, Y. Ma, M.C. McCarthy, et al., Coord. Chem. Rev. 255(2011) 1791-1823. doi: 10.1016/j.ccr.2011.02.012
20. [20]
  P. Horcajada, C. Serre, M. Vallet-Regí, et al., Angew. Chem. 118 (2006) 6120-6124. doi: 10.1002/ange.200601878
21. [21]
  G. Nickerl, I. Senkovska, S. Kaskel, Chem. Commun. 51(2015) 2280-2282. doi: 10.1039/C4CC08136F
22. [22]
  B. Wang, A.P. Cote, H. Furukawa, M. O'Keeffe, O.M. Yaghi, Nature 453(2008) 207-211. doi: 10.1038/nature06900
23. [23]
  D.P. Volanti, A.A. Felix, M.O. Orlandi, et al., Adv. Funct. Mater. 23(2013) 1759-1766. doi: 10.1002/adfm.201202332
24. [24]
  J. Tang, R.R. Salunkhe, J. Liu, et al., J. Am. Chem. Soc. 137(2015) 1572-1580. doi: 10.1021/ja511539a
25. [25]
  R. Wu, D.P. Wang, J. Han, et al., Nanoscale 7(2015) 965-974. doi: 10.1039/C4NR05135A
26. [26]
  F. Qu, C. Feng, C. Li, et al., Int. J. Appl. Ceram. Technol. 11(2014) 619-625. doi: 10.1111/ijac.12160
27. [27]
  L. Li, P. Gao, M. Baumgarten, et al., Adv. Mater. 25(2013) 3419-3425. doi: 10.1002/adma.201301138
28. [28]
  S.H. Yan, S.Y. Ma, W.Q. Li, et al., Sens. Actuator. B-Chem. 221(2015) 88-95.
29. [29]
  W.C. Wang, F.Q. Liu, B. Wang, et al., Chin. Chem. Lett. 30(2019) 1261-1265. doi: 10.1016/j.cclet.2018.12.030
30. [30]
  H. Tian, H. Fan, M. Li, L. Ma, ACS Sens. 1(2015) 243-250.
31. [31]
  C. Gu, Y. Cui, L. Wang, et al., Sens. Actuator. B-Chem. 241(2017) 298-307. doi: 10.1016/j.snb.2016.10.060
32. [32]
  D. Wang, L. Tian, H. Li, et al., ACS Appl. Mater. Inter. 11(2019) 12808-12818. doi: 10.1021/acsami.9b01465
33. [33]
  W. Yang, P. Wan, X. Zhou, et al., Sens. Actuator. B-Chem. 201(2014) 228-233. doi: 10.1016/j.snb.2014.05.003
34. [34]
  N. Zhang, S. Ruan, F. Qu, et al., Sens. Actuator. B-Chem. 298(2019) 126887. doi: 10.1016/j.snb.2019.126887
35. [35]
  X. Chu, T. Chen, W. Zhang, B. Zheng, H. Shui, Sens. Actuator. B-Chem. 142(2009) 49-54. doi: 10.1016/j.snb.2009.07.049
36. [36]
  W.T. Koo, S.J. Choi, J.S. Jang, I.D. Kim, Sci. Rep. 7(2017) 45074. doi: 10.1038/srep45074
37. [37]
  A. Rothschild, Y. Komem, J. Appl. Phys. 95(2004) 6374-6380. doi: 10.1063/1.1728314
38. [38]
  X. Gou, G. Wang, J. Park, H. Liu, J. Yang, Nanotechnology 19(2008) 125606. doi: 10.1088/0957-4484/19/12/125606
39. [39]
  P. Sun, C. Wang, J. Liu, et al., ACS Appl. Mater. Interfaces 7(2015) 19119-19125. doi: 10.1021/acsami.5b04751
1. [1]
  Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490
2. [2]
  Yuxin Wang , Zhengxuan Song , Yutao Liu , Yang Chen , Jinping Li , Libo Li , Jia Yao . Methyl functionalization of trimesic acid in copper-based metal-organic framework for ammonia colorimetric sensing at high relative humidity. Chinese Chemical Letters, 2024, 35(6): 108779-. doi: 10.1016/j.cclet.2023.108779
3. [3]
  Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO₂ nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
4. [4]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
5. [5]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
6. [6]
  Xian-Fa Jiang , Chongyun Shao , Zhongwen Ouyang , Zhao-Bo Hu , Zhenxing Wang , You Song . Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109011-. doi: 10.1016/j.cclet.2023.109011
7. [7]
  Xuying Yu , Jiarong Mi , Yulan Han , Cai Sun , Mingsheng Wang , Guocong Guo . A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109233-. doi: 10.1016/j.cclet.2023.109233
8. [8]
  Jiayu Xu , Meng Li , Baoxia Dong , Ligang Feng . Fully fluorinated hybrid zeolite imidazole/Prussian blue analogs with combined advantages for efficient oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(6): 108798-. doi: 10.1016/j.cclet.2023.108798
9. [9]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
10. [10]
  Ying Gao , Rong Zhou , Qiwen Wang , Shaolong Qi , Yuanyuan Lv , Shuang Liu , Jie Shen , Guocan Yu . Natural killer cell membrane doped supramolecular nanoplatform with immuno-modulatory functions for immuno-enhanced tumor phototherapy. Chinese Chemical Letters, 2024, 35(10): 109521-. doi: 10.1016/j.cclet.2024.109521
11. [11]
  Lei Zhu , Hai-Ruo Li , Yi-Ning Mao , Ruiying Liu , Bo Zhang , Jing Chen , Wengui Xu , Libo Zhang , Cheng-Peng Li . A four-fold interpenetrated MOF for efficient perrhenate/pertechnetate removal from alkaline nuclear effluents. Chinese Chemical Letters, 2024, 35(12): 109921-. doi: 10.1016/j.cclet.2024.109921
12. [12]
  Guizhi Zhu , Junrui Tan , Longfei Tan , Qiong Wu , Xiangling Ren , Changhui Fu , Zhihui Chen , Xianwei Meng . Growth of CeCo-MOF in dendritic mesoporous organosilica as highly efficient antioxidant for enhanced thermal stability of silicone rubber. Chinese Chemical Letters, 2025, 36(1): 109669-. doi: 10.1016/j.cclet.2024.109669
13. [13]
  Zhefei Hu , Jingwen Liao , Jiawen Zhou , Lulu Zhao , Yanjuan Liu , Yuefei Zhang , Wei Chen , Sheng Tang . A new green approach to synthesizing MIP-202@porous silica microspheres for positional isomer/enantiomer/hydrophilic separation. Chinese Chemical Letters, 2025, 36(1): 109985-. doi: 10.1016/j.cclet.2024.109985
14. [14]
  Xudong Zhao , Yuxuan Wang , Xinxin Gao , Xinli Gao , Meihua Wang , Hongliang Huang , Baosheng Liu . Anchoring thiol-rich traps in 1D channel wall of metal-organic framework for efficient removal of mercury ions. Chinese Chemical Letters, 2025, 36(2): 109901-. doi: 10.1016/j.cclet.2024.109901
15. [15]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
16. [16]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
17. [17]
  Xianping Du , Ying Huang , Chen Chen , Zhenhe Feng , Meng Zong . Encapsulating Si particles in multiple carbon shells with pore-rich for constructing free-standing anodes of lithium storage. Chinese Chemical Letters, 2024, 35(12): 109990-. doi: 10.1016/j.cclet.2024.109990
18. [18]
  Xin Zhang , Junyu Chen , Xiang Pei , Linxin Yang , Liang Wang , Luona Chen , Guangmei Yang , Xibo Pei , Qianbing Wan , Jian Wang . Drug-loading ZIF-8 for modification of microporous bone scaffold to promote vascularized bone regeneration. Chinese Chemical Letters, 2024, 35(6): 108889-. doi: 10.1016/j.cclet.2023.108889
19. [19]
  Xuexia Lin , Yihui Zhou , Jiafu Hong , Xiaofeng Wei , Bin Liu , Chong-Chen Wang . Facile preparation of ZIF-8/ZIF-67-derived biomass carbon composites for highly efficient electromagnetic wave absorption. Chinese Chemical Letters, 2024, 35(9): 109835-. doi: 10.1016/j.cclet.2024.109835
20. [20]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(743)
HTML views(52)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142