Citation: Wang Kaijie, Kong Qing, Chen Xiaoqiang, Yoon Juyoung, Swamy K.M. K., Wang Fang. A bifunctional rhodamine derivative as chemosensor for recognizing Cu²⁺ and Hg²⁺ ions via different spectra[J]. Chinese Chemical Letters, ;2020, 31(5): 1087-1090. doi: 10.1016/j.cclet.2019.11.013 shu

A bifunctional rhodamine derivative as chemosensor for recognizing Cu²⁺ and Hg²⁺ ions via different spectra

a.
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM), Nanjing Tech University, Nanjing 211816, China
b.
Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Republic of Korea
c.
Department of Pharmaceutical Chemistry, V. L. College of Pharmacy, Raichur 584103, India

fangwang@njtech.edu.cn

Received Date: 16 September 2019
Revised Date: 7 November 2019
Accepted Date: 8 November 2019
Available Online: 9 November 2019

Figures(4)

A new simple bifunctional chemosensor 1 based on rhodamine was synthesized by hydrazide and formylformic acid, which could detect Cu²⁺ and Hg²⁺ via different detecting methods in CH₃CN-HEPES buffer solution (20 mmol/L, pH 7.4) (1:9, v/v) respectively. When sensor 1 bound with Cu²⁺, it showed a colorimetric change, while a selective enhancement in fluorescence occurred upon 1 binding with Hg²⁺, resulting from the spirolatam-ring opening process. The binding modes of 1 with Cu²⁺ and Hg²⁺ were investigated based on UV, fluorescence change, ESI-Mass and Job's Plot data. Moreover, sensor 1 could selectively detect target ion in a mixed solution of Cu²⁺ and Hg²⁺, and the two metal ions do not interfere with each other in the process of detecting Cu²⁺ or Hg²⁺ with 1.
- Rhodamine,
- Fluorescent sensor,
- Colorimetric sensor,
- Spirolatam-ring opening,
- Mercury,
- Copper
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A bifunctional rhodamine derivative as chemosensor for recognizing Cu2+ and Hg2+ ions via different spectra

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通讯作者: 陈斌, bchen63@163.com

A bifunctional rhodamine derivative as chemosensor for recognizing Cu²⁺ and Hg²⁺ ions via different spectra