Citation: Liu Jiang, Fang Zhongjin, Liu Xin, Dou Yandong, Jiang Jianze, Zhang Fangfang, Qu Jiaojiao, Zhu Qing. Diastereoselective 2, 3-diazidation of indoles via copper(Ⅱ)-catalyzed dearomatization[J]. Chinese Chemical Letters, ;2020, 31(5): 1332-1336. doi: 10.1016/j.cclet.2019.10.035 shu

Diastereoselective 2, 3-diazidation of indoles via copper(Ⅱ)-catalyzed dearomatization

Liu Jiang ^a,1 ,
Fang Zhongjin ^b,1 ,
Liu Xin ^a ,
Dou Yandong ^a ,
Jiang Jianze ^a ,
Zhang Fangfang ^a ,
Qu Jiaojiao ^a ,
Zhu Qing ^a,*,

a.
Key Laboratory of Bioorganic Synthesis of Zhejiang Province, College of Biotechnology and Bioengineering, Zhejiang University of Technology, Hangzhou 310014, China
b.
Zhejiang Zhong Cheng Medicine Co., Ltd., Hangzhou 310012, China

zhuq@zjut.edu.cn, 2359776318@qq.com

Received Date: 14 September 2019
Revised Date: 15 October 2019
Accepted Date: 28 October 2019
Available Online: 1 November 2019

Figures(8)

The copper-catalyzed directed dearomatization of indoles with the assistance of directing groups has been developed for the synthesis of 2, 3-diazido indolines with good yields and excellent diastereoselectivities in aqueous solution. The resultant 2, 3-diazides can be smoothly converted to other functional groups, including vicinal diamines, triazoles and benzotriazoles, in a single step.
- Indole,
- Diastereoselective,
- Dearomatization,
- 2, 3-Diazidation,
- Indoline
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