Citation: Zhang Na, Li Xin, Hou Tianyi, Guo Jinze, Fan Anran, Jin Shibo, Sun Xiaohong, Cai Shu, Zheng Chunming. MnS hollow microspheres combined with carbon nanotubes for enhanced performance sodium-ion battery anode[J]. Chinese Chemical Letters, ;2020, 31(5): 1221-1225. doi: 10.1016/j.cclet.2019.09.050 shu

MnS hollow microspheres combined with carbon nanotubes for enhanced performance sodium-ion battery anode

Zhang Na ^a ,
Li Xin ^a ,
Hou Tianyi ^a ,
Guo Jinze ^a ,
Fan Anran ^a ,
Jin Shibo ^a ,
Sun Xiaohong ^a,*, ,
Cai Shu ^a ,
Zheng Chunming ^b,*,

a.
School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, China
b.
State Key Laboratory of Hollow-fiber Membrane Materials and Membrane Processes, School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, China

sunxh@tju.edu.cn

zhengchunming@tjpu.edu.cn

Received Date: 20 August 2019
Revised Date: 18 September 2019
Accepted Date: 26 September 2019
Available Online: 27 September 2019

Figures(4)

MnS as anode material for sodium-ion batteries (SIBs) has recently attracted great attention because of the high theoretical capacity, great natural abundance, and low cost. However, it suffers from inferior electrical conductivity and large volume expansion during the charge/discharge process, leading to tremendous damage of electrodes and subsequently fast capacity fading. To mitigate these issues, herein, a three-dimensional (3D) interlaced carbon nanotubes (CNTs) threaded into or between MnS hollow microspheres (hollow MnS/CNTs composite) has been designed and synthesized as an enhanced anode material. It can effectively improve the electrical conductivity, buffer the volume change, and maintain the integrity of the electrode during the charging and discharging process based on the synergistic interaction and the integrative structure. Therefore, when evaluated as anode for SIBs, the hollow MnS/CNTs electrode displays enhanced reversible capacity (275 mAh/g at 100 mA/g after 100 cycles), which is much better than that of pure MnS electrode (25 mAh/g at 100 mA/g after 100 cycles) prepared without the addition of CNTs. Even increasing the current density to 500 mA/g, the hollow MnS/CNTs electrode still delivers a five times higher reversible capacity than that of the pure MnS electrode. The rate performance of the hollow MnS/CNTs electrode is also superior to that of pure MnS electrode at various current densities from 50 mA/g to 1000 mA/g.
- MnS,
- CNTs,
- Hollow microspheres,
- Anode,
- Sodium-ion battery
1. [1]
  J.Y. Hwang, S.T. Myung, Y.K. Sun, Chem. Soc. Rev. 46(2017) 3529-3614. doi: 10.1039/C6CS00776G
2. [2]
  X. Zhang, X. Rui, D. Chen, et al., Nanoscale 11(2019) 2556-2576. doi: 10.1039/C8NR09391A
3. [3]
  X. Pu, H. Wang, D. Zhao, et al., Small (2019) 1805427.
4. [4]
  G.L. Xu, R. Amine, A. Abouimrane, et al., Adv. Energy Mater. 8(2018) 1702403. doi: 10.1002/aenm.201702403
5. [5]
  F. Xie, L. Zhang, C. Ye, et al., Adv. Mater. (2018) 1800492.
6. [6]
  Z. Hu, Q. Liu, S.L. Chou, et al., Adv. Mater. 29(2017) 1700606. doi: 10.1002/adma.201700606
7. [7]
  M. Tang, H. Li, E. Wang, et al., Chin. Chem. Lett. 29(2018) 232-244. doi: 10.1016/j.cclet.2017.09.005
8. [8]
  X. Wei, X. Wang, X. Tan, et al., Adv. Funct. Mater. 28(2018) 1804458. doi: 10.1002/adfm.201804458
9. [9]
  H. Yuan, L. Kong, T. Li, et al., Chin. Chem. Lett. 28(2017) 2180-2194. doi: 10.1016/j.cclet.2017.11.038
10. [10]
  Y. Liu, L. Li, J. Zhu, et al., ACS Appl. Mater. Interfaces 10(2018) 27911-27919. doi: 10.1021/acsami.8b05688
11. [11]
  Y. Hao, C. Chen, X. Yang, et al., J. Power Sources 338(2017) 9-16. doi: 10.1016/j.jpowsour.2016.11.032
12. [12]
  G. Li, B. He, M. Zhou, et al., ChemElectroChem 4(2017) 81-89. doi: 10.1002/celc.201600327
13. [13]
  D. Xu, R. Jiao, Y. Sun, et al., Nanoscale Res. Lett. 11(2016) 444. doi: 10.1186/s11671-016-1664-6
14. [14]
  B. Liu, Z. Liu, D. Li, et al., Appl. Surf. Sci. 416(2017) 858-867. doi: 10.1016/j.apsusc.2017.04.230
15. [15]
  R. Wang, B. Li, L. Lai, et al., Chem. Eng. J. 355(2019) 752-759. doi: 10.1016/j.cej.2018.08.136
16. [16]
  L. Zhang, L. Zhou, H.B. Wu, et al., Angew. Chem. Int. Ed. 51(2012) 7267-7270. doi: 10.1002/anie.201202877
17. [17]
  D. Chen, H. Quan, G.S. Wang, et al., ChemPlusChem 78(2013) 843-851. doi: 10.1002/cplu.201300141
18. [18]
  S.M. Lee, J.K. Lee, Y.C. Kang, Chem. -Asian J. 9(2014) 590-595. doi: 10.1002/asia.201301261
19. [19]
  X. Xu, S. Ji, M. Gu, et al., ACS Appl. Mater. Interfaces 7(2015) 20957-20964. doi: 10.1021/acsami.5b06590
20. [20]
  D.H. Liu, W.H. Li, Y.P. Zheng, et al., Adv. Mater. 30(2018)1706317. doi: 10.1002/adma.201706317
21. [21]
  X. Gao, X. Zhang, J. Jiang, et al., Mater. Lett. 228(2018) 42-45. doi: 10.1016/j.matlet.2018.05.077
22. [22]
  B.H. Hou, Y.Y. Wang, D.S. Liu, et al., Adv. Funct. Mater. 28(2018) 1805444. doi: 10.1002/adfm.201805444
23. [23]
  X. Gao, B. Wang, Y. Zhang, et al., Energy Storage Mater. 16(2019) 46-55. doi: 10.1016/j.ensm.2018.04.027
24. [24]
  X. Li, X. Sun, Z. Gao, et al., ChemSusChem 11(2018) 1549-1557. doi: 10.1002/cssc.201800073
25. [25]
  W. Chen, X. Zhang, L. Mi, et al., Adv. Mater. 31(2019) 1806664. doi: 10.1002/adma.201806664
26. [26]
  S. Gao, G. Chen, Y. Dall'Agnese, et al., Chem. -Eur. J. 24(2018) 13535-13539. doi: 10.1002/chem.201801979
27. [27]
  H.H. Fan, H.H. Li, K.C. Huang, et al., ACS Appl. Mater. Interfaces 9(2017) 10708-10716. doi: 10.1021/acsami.7b00578
28. [28]
  Y. Chen, X. Hu, B. Evanko, et al., Nano Energy 46(2018) 117-127. doi: 10.1016/j.nanoen.2018.01.039
29. [29]
  Z. Shadike, M.H. Cao, F. Ding, et al., Chem. Commun. (Camb.) 51(2015) 10486-10489. doi: 10.1039/C5CC02564H
30. [30]
  L. Wang, J. Yuan, Q. Zhao, et al., Electrochim. Acta 308(2019) 174-184. doi: 10.1016/j.electacta.2019.04.019
31. [31]
  Y. Chen, B. Wang, T. Hou, et al., Chin. Chem. Lett. 29(2018) 187-190. doi: 10.1016/j.cclet.2017.06.019
32. [32]
  S.H. Yang, S.K. Park, Y.C. Kang, Chem. Eng. J. 370(2019) 1008-1018. doi: 10.1016/j.cej.2019.03.263
33. [33]
  D. Ma, Y. Li, H. Mi, et al., Angew. Chem. Int. Ed. 57(2018) 8901-8905. doi: 10.1002/anie.201802672
34. [34]
  D. Wang, D. Cai, B. Qu, et al., CrystEngComm 18(2016) 6200-6204. doi: 10.1039/C6CE01045H
35. [35]
  R. Tan, J. Yang, J. Hu, et al., Chem. Commun. (Camb.) 52(2016) 986-989. doi: 10.1039/C5CC08002A
36. [36]
  B.H. Hou, Y.Y. Wang, Q.L. Ning, et al., Adv. Mater. (2019) 1903125.
37. [37]
  G. Huang, F. Zhang, X. Du, et al., ACS Nano 9(2015) 1592-1599. doi: 10.1021/nn506252u
1. [1]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
2. [2]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
3. [3]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
4. [4]
  Caili Yang , Tao Long , Ruotong Li , Chunyang Wu , Yuan-Li Ding . Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors. Chinese Chemical Letters, 2025, 36(2): 109675-. doi: 10.1016/j.cclet.2024.109675
5. [5]
  Li Lin , Song-Lin Tian , Zhen-Yu Hu , Yu Zhang , Li-Min Chang , Jia-Jun Wang , Wan-Qiang Liu , Qing-Shuang Wang , Fang Wang . Molecular crowding electrolytes for stabilizing Zn metal anode in rechargeable aqueous batteries. Chinese Chemical Letters, 2024, 35(7): 109802-. doi: 10.1016/j.cclet.2024.109802
6. [6]
  Bin Feng , Tao Long , Ruotong Li , Yuan-Li Ding . Rationally constructing metallic Sn-ZnO heterostructure via in-situ Mn doping for high-rate Na-ion batteries. Chinese Chemical Letters, 2025, 36(2): 110273-. doi: 10.1016/j.cclet.2024.110273
7. [7]
  Junhan Luo , Qi Qing , Liqin Huang , Zhe Wang , Shuang Liu , Jing Chen , Yuexiang Lu . Non-contact gaseous microplasma electrode as anode for electrodeposition of metal and metal alloy in molten salt. Chinese Chemical Letters, 2024, 35(4): 108483-. doi: 10.1016/j.cclet.2023.108483
8. [8]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
9. [9]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
10. [10]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
11. [11]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
12. [12]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
13. [13]
  Jie Zhou , Quanyu Li , Xiaomeng Hu , Weifeng Wei , Xiaobo Ji , Guichao Kuang , Liangjun Zhou , Libao Chen , Yuejiao Chen . Water molecules regulation for reversible Zn anode in aqueous zinc ion battery: Mini-review. Chinese Chemical Letters, 2024, 35(8): 109143-. doi: 10.1016/j.cclet.2023.109143
14. [14]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
15. [15]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
16. [16]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
17. [17]
  Haiying Lu , Weijie Li . The electrolyte solvation and interfacial chemistry for anode-free sodium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(11): 100334-100334. doi: 10.1016/j.cjsc.2024.100334
18. [18]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
19. [19]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
20. [20]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(677)
HTML views(59)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142