Citation: Cai Wenrui, Xiong Renjie, Mao Cong, Xiao Meitian, Liu Yongjun, Kankala Ranjith Kumar, Zhang Xueqin. Preparation of alumina-carbon composites with phloroglucinol-formaldehyde resin and their application in asymmetric hydrogenation[J]. Chinese Chemical Letters, ;2020, 31(5): 1322-1326. doi: 10.1016/j.cclet.2019.09.029 shu

Preparation of alumina-carbon composites with phloroglucinol-formaldehyde resin and their application in asymmetric hydrogenation

College of Chemical Engineering, Huaqiao University, Xiamen 361021, China

xqzhang2009@hqu.edu.cn

Received Date: 20 June 2019
Revised Date: 15 August 2019
Accepted Date: 16 September 2019
Available Online: 18 September 2019

Figures(5)

To overcome the shortcomings of single component carrier supported platinum (Pt)-based catalysts, herein, we demonstrate the fabrication of alumina combined mesoporous carbon to prepare a series of alumina-carbon composites and their corresponding Pt-based catalysts. The alumina-carbon composites Al@PhFC are synthesized by using phloroglucinol-formaldehyde resin as carbon source and aluminum acetylacetone as the aluminum source. Further, the effect of alumina content on the properties of the composites is investigated. The composites and catalysts are characterized by using XRD, XPS, N₂ sorption, and TEM. The Pt/Al@PhFC-1.8 composite with appropriate amounts of alumina, pore diameter, and moderate Pt nanoparticle size, resulted in 99.5% of conversion efficiency and 77.4% of optical selectivity in the asymmetric hydrogenation of ethyl 2-oxo-4-phenylbutanoate (EOPB). Interestingly, this composite can be used more than 20 times without a significant decrease in its performance.
- Phloroglucinol-formaldehyde resin,
- Alumina-carbon composite,
- Asymmetric hydrogenation,
- Pt nanoparticles
1. [1]
  Y. Orito, S. Imai, S. Niwa, J. Chem. Soc. Jpn. (1980) 670-672. doi: 10.1002/chin.198032151
2. [2]
  L.L. Lou, T. Yang, W.J. Yu, et al., Catal. Today 298(2017) 197-202. doi: 10.1016/j.cattod.2017.04.037
3. [3]
  T. Yang, L.L. Lou, W.J. Yu, et al., ChemCatChem 9(2017) 458-464. doi: 10.1002/cctc.201601179
4. [4]
  W.J. Yu, L.L. Lou, K. Yu, et al., RSC Adv. 6(2016) 52500-52508. doi: 10.1039/C6RA06277F
5. [5]
  J.T. Wehrli, A. Baiker, D.M. Monti, et al., J. Mol. Catal. 61(1990) 207-226. doi: 10.1016/0304-5102(90)85156-C
6. [6]
  R. Xing, N. Liu, Y. Liu, et al., Adv. Funct. Mater. 17(2007) 2455-2461. doi: 10.1002/adfm.200600784
7. [7]
  X. Li, Y. Shen, X. Rong, et al., Catal. Lett. 122(2008) 325-329. doi: 10.1007/s10562-007-9381-5
8. [8]
  Q. Li, X.Q. Zhang, M.T. Xiao, et al., Catal. Commun. 42(2013) 68-72. doi: 10.1016/j.catcom.2013.07.044
9. [9]
  X.Q. Zhang, Q. Li, M.T. Xiao, et al., Appl. Catal. A-Gen. 480(2014) 50-57. doi: 10.1016/j.apcata.2014.04.031
10. [10]
  H. Wang, A. Wang, X. Wang, et al., Chem. Commun. (Camb.) 22(2008) 2565-2567. doi: 10.1107/S160053680904344X
11. [11]
  P. Rodriguez, B. Caussat, X. Iltis, et al., Chem. Eng. J. 211-212(2012) 68-76. doi: 10.1016/j.cej.2012.09.048
12. [12]
  E. Miloskovska, C. Friedrichs, D. Hristova-Bogaerds, et al., Macromolecules 48(2015) 1093-1103. doi: 10.1021/ma5020929
13. [13]
  S.D. Gardner, C.S.K. Singamsetty, G.L. Booth, et al., Carbon 33(1995) 587-595. doi: 10.1016/0008-6223(94)00144-O
14. [14]
  B. Li, X.H. Li, H.N. Wang, et al., J. Mol. Catal. A-Chem. 345(2011) 81-89. doi: 10.1016/j.molcata.2011.05.023
15. [15]
  L.H. Nie, J.G. Yu, X.Y. Li, et al., Environ. Sci. Technol. 47(2013) 2777-2783. doi: 10.1021/es3045949
16. [16]
  B.J. Tan, K.J. Klabunde, P.M.A. Sherwood, J. Am. Chem. Soc. 113(1991) 855-861. doi: 10.1021/ja00003a019
17. [17]
  F.A. Marchesini, S. Irusta, C. Querini, et al., Appl. Catal. A-Gen. 348(2008) 60-70. doi: 10.1016/j.apcata.2008.06.026
18. [18]
  J. Stein, L.N. Lewis, Y. Gao, et al., J. Am. Chem. Soc. 121(1999) 3693-3703. doi: 10.1021/ja9825377
19. [19]
  Z. Sun, B. Sun, M. Qiao, et al., J. Am. Chem. Soc. 134(2012) 17653-17660. doi: 10.1021/ja306913x
20. [20]
  D.Y. Murzin, E. Toukoniitty, React. Kinet. Catal. Lett. 90(2007) 19-25. doi: 10.1007/s11144-007-5004-9
21. [21]
  F. Hoxha, N.V. Vegten, A. Urakawa, et al., J. Catal. 261(2009) 224-231. doi: 10.1016/j.jcat.2008.12.002
22. [22]
  H. Du, C.X. Zhao, J. Lin, et al., Chem. Rec. 18(2018) 1365-1372. doi: 10.1002/tcr.201800008
23. [23]
  M.U. Azmat, Y. Guo, Y. Guo, et al., J. Mol. Catal. A-Chem. 336(2011) 42-50. doi: 10.1016/j.molcata.2010.12.008
24. [24]
  M. Bartók, K. Balázsik, G. Szöllösi, et al., J. Catal. 205(2002) 168-176. doi: 10.1006/jcat.2001.3423
25. [25]
  H.N. Wang, X.H. Li, Y.M. Wang, et al., ChemCatChem 2(2010) 1303-1311. doi: 10.1002/cctc.201000081
26. [26]
  K. Balázsik, M. Bartók, J. Mol. Catal. A-Chem. 219(2004) 383-389. doi: 10.1016/j.molcata.2004.05.011
27. [27]
  J. Liu, ChemCatChem 3(2011) 934-948. doi: 10.1002/cctc.201100090
1. [1]
  Pei Cao , Yilan Wang , Lejian Yu , Miao Wang , Liming Zhao , Xu Hou . Dynamic asymmetric mechanical responsive carbon nanotube fiber for ionic logic gate. Chinese Chemical Letters, 2024, 35(6): 109421-. doi: 10.1016/j.cclet.2023.109421
2. [2]
  Shaoming Dong , Yiming Niu , Yinghui Pu , Yongzhao Wang , Bingsen Zhang . Subsurface carbon modification of Ni-Ga for improved selectivity in acetylene hydrogenation reaction. Chinese Chemical Letters, 2024, 35(12): 109525-. doi: 10.1016/j.cclet.2024.109525
3. [3]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
4. [4]
  Jin Long , Xingqun Zheng , Bin Wang , Chenzhong Wu , Qingmei Wang , Lishan Peng . Improving the electrocatalytic performances of Pt-based catalysts for oxygen reduction reaction via strong interactions with single-CoN₄-rich carbon support. Chinese Chemical Letters, 2024, 35(5): 109354-. doi: 10.1016/j.cclet.2023.109354
5. [5]
  Peng Zhang , Yitao Yang , Tian Qin , Xueqiu Wu , Yuechang Wei , Jing Xiong , Xi Liu , Yu Wang , Zhen Zhao , Jinqing Jiao , Liwei Chen . Interface engineering of Pt/CeO₂-{100} catalysts for enhancing catalytic activity in auto-exhaust carbon particles oxidation. Chinese Chemical Letters, 2025, 36(2): 110396-. doi: 10.1016/j.cclet.2024.110396
6. [6]
  Tianyi Yang , Fangxi Su , Dehuan Shi , Shenghong Zhong , Yalin Guo , Zhaohui Liu , Jianfeng Huang . Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix. Chinese Chemical Letters, 2025, 36(2): 110444-. doi: 10.1016/j.cclet.2024.110444
7. [7]
  Ming Huang , Xiuju Cai , Yan Liu , Zhuofeng Ke . Base-controlled NHC-Ru-catalyzed transfer hydrogenation and α-methylation/transfer hydrogenation of ketones using methanol. Chinese Chemical Letters, 2024, 35(7): 109323-. doi: 10.1016/j.cclet.2023.109323
8. [8]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
9. [9]
  Xingxing Jiang , Yuxin Zhao , Yan Kong , Jianju Sun , Shangzhao Feng , Xin Lu , Qi Hu , Hengpan Yang , Chuanxin He . Support effect and confinement effect of porous carbon loaded tin dioxide nanoparticles in high-performance CO₂ electroreduction towards formate. Chinese Chemical Letters, 2025, 36(1): 109555-. doi: 10.1016/j.cclet.2024.109555
10. [10]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
11. [11]
  Rui HUANG , Shengjie LIU , Qingyuan WU , Nanfeng ZHENG . Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 201-212. doi: 10.11862/CJIC.20240356
12. [12]
  Long Jin , Jian Han , Dongmei Fang , Min Wang , Jian Liao . Pd-catalyzed asymmetric carbonyl alkynylation: Synthesis of axial chiral ynones. Chinese Chemical Letters, 2024, 35(6): 109212-. doi: 10.1016/j.cclet.2023.109212
13. [13]
  Lian Sun , Honglei Wang , Ming Ma , Tingting Cao , Leilei Zhang , Xingui Zhou . Shape and composition evolution of Pt and Pt₃M nanocrystals under HCl chemical etching. Chinese Chemical Letters, 2024, 35(9): 109188-. doi: 10.1016/j.cclet.2023.109188
14. [14]
  Zhaoru Chen , Xiaoxu Liu , Haonan Chen , Jialong Li , Xiaofeng Wang , Jianfeng Zhu . Application of epoxy resin in cultural relics protection. Chinese Chemical Letters, 2024, 35(4): 109194-. doi: 10.1016/j.cclet.2023.109194
15. [15]
  Minying Wu , Xueliang Fan , Wenbiao Zhang , Bin Chen , Tong Ye , Qian Zhang , Yuanyuan Fang , Yajun Wang , Yi Tang . Highly dispersed Ru nanospecies on N-doped carbon/MXene composite for highly efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109258-. doi: 10.1016/j.cclet.2023.109258
16. [16]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
17. [17]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
18. [18]
  Jinyuan Cui , Tingting Yang , Teng Xu , Jin Lin , Kunlong Liu , Pengxin Liu . Hydrogen spillover enhances the selective hydrogenation of α,β-unsaturated aldehydes on the Cu-O-Ce interface. Chinese Journal of Structural Chemistry, 2025, 44(1): 100438-100438. doi: 10.1016/j.cjsc.2024.100438
19. [19]
  Naihong Wang , Longkang Zhang , Yejun Guan , Peng Wu , Hao Xu . Pt confined in Sn-ECNU-46 zeolite for efficient alkane dehydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(4): 100248-100248. doi: 10.1016/j.cjsc.2024.100248
20. [20]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(692)
HTML views(77)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142