Citation: Jin Ling, Li Xiaxia, Liu Chunsen, Pang Huan. Nanoreactors derived from silica-protection-assisted metal-organic framework[J]. Chinese Chemical Letters, ;2020, 31(9): 2207-2210. doi: 10.1016/j.cclet.2019.08.044 shu

Nanoreactors derived from silica-protection-assisted metal-organic framework

Jin Ling ^a ,
Li Xiaxia ^a ,
Liu Chunsen ^b ,
Pang Huan ^a,*,

a.
School of Chemistry and Chemical Engineering, Guangling College, Yangzhou University, Yangzhou 225009, China
b.
Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002, China

huanpangchem@hotmail.com

panghuan@yzu.edu.cn

Received Date: 19 July 2019
Revised Date: 20 August 2019
Accepted Date: 23 August 2019
Available Online: 26 August 2019

Figures(4)

The construction of highly stable and regular nanoreactors is a major challenge. In this work, we use a facile template protection method to obtain ZIF-67@SiO₂ (JS) and to encapsulate metal oxide nanoparticles (Co₃O₄) into nanoreactors (SiO₂). ZIF-67 crystals provide a cobalt species; SiO₂ was first used as a protective layer of ZIF-67 and then as a nanoreactor for metastable metal oxide nanoparticles. On this basis, Co₃O₄@SiO₂ with dodecahedron morphology were synthesized by calcining JS at different temperatures, followed by a hydrothermal reaction to obtain Co₃(OH)₄Si₂O₅. Subsequently, CoS_x and CoPSiO₂ were fabricated through sulfuration and phosphorization. The results in this work show that nanoreactors derived from metal-organic frameworks (MOFs) with a rational structure have broad development prospects.
- Core-shell structure,
- Metal oxide nanoparticles,
- Co₃(OH)₄Si₂O₅,
- Nanoreactors,
- Silicon shell
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