Citation: Cai Yan, Wang Yang, Wang Chenwei, Long Renhua, Cao Leyu, Chen Yanmei, Yao Yong. Hierarchical self-assembly of 3D amphiphilic discrete organoplatinum (II) metallacage in water[J]. Chinese Chemical Letters, ;2020, 31(3): 689-692. doi: 10.1016/j.cclet.2019.08.036 shu

Hierarchical self-assembly of 3D amphiphilic discrete organoplatinum (II) metallacage in water

College of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China

yaoyong1986@ntu.edu.cn

Received Date: 9 June 2019
Accepted Date: 22 August 2019
Available Online: 23 August 2019

Figures(7)

Here we described the design and synthesis of a discrete 3D amphiphilic metallacage 4, in which the tetragonal prismatic frameworks act as the hydrophobic cores and the poly(ethylene glycol) (PEG) chains as the hydrophilic tails. The structure of 4 was characterized by ¹H NMR, ³¹P NMR and electrospray ionization time-of-flight mass spectrometry (ESI-TOF-MS). Notably, 4 with its long PEG tails was subsequently ordered into micelles at a low concentration (1.20 ×10^-6 mol/L) in water. As the concentration and cultivation time increased, the micelles can further self-assembly into nanofibers and nanoribbons. Considering the dynamic property of the coordination bond, these structures show reversible transformation under external stimuli.
- Self-assembly,
- Matellacage,
- Micelles,
- Nanotubes,
- Dynamic property
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