Citation: Zhou Ronghui, Lu Xiaomei, Yang Qin, Wu Peng. Nanocrystals for large Stokes shift-based optosensing[J]. Chinese Chemical Letters, ;2019, 30(10): 1843-1848. doi: 10.1016/j.cclet.2019.07.062 shu

Nanocrystals for large Stokes shift-based optosensing

Zhou Ronghui ^a ,
Lu Xiaomei ^b ,
Yang Qin ^c,*, ,
Wu Peng ^b,*,

a.
State Key Laboratory of Oral Diseases, West China Hospital of Stomatology, Sichuan University, Chengdu 610041, China
b.
Analytical & Testing Center, Sichuan University, Chengdu 610064, China
c.
College of Light Industry and Textile and Food Engineering, Sichuan University, Chengdu 610065, China

yangqin@scu.edu.cn

wupeng@scu.edu.cn

Received Date: 4 July 2019
Revised Date: 27 July 2019
Accepted Date: 30 July 2019
Available Online: 31 October 2019

Figures(8)

Stokes shift is an important feature of fluorescence, which reveals the energy loss between the excitation and the emission. For most fluorescent materials (e.g., organic dyes and proteins), the large overlap between the absorption and emission spectra endow them a small Stokes shift that induced reabsorption by fluorophore itself. Although the self-absorption can be effectively reduced due to the emergence of fluorescent nanomaterials, fluorescence attenuation is still observed in aggregated or concentrated nanocrystals, causing reduced sensitivity of biosensors. Therefore, increasing the Stokes shift can effectively improve the performance of nano-agents based biosensing. In this critical review, through understanding the Stokes shift from the viewpoint of self-absorption, the influence of Stokes shift on fluorescence properties are discussed. Based on the principle of changing the Stokes shift of fluorescent nanomaterials, we described the methods for constructing various optically large Stokes shift-based nanomaterials, and the application of these nanocrystals in biosensing is especially concerned in this review.
- Stokes shift,
- Self-absorption,
- Band gap,
- Optical nanocrystals,
- Biosensing
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