Citation: Song Zhaoxia, Liu Wei, Wei Xiaofei, Zhou Quan, Liu Hongda, Zhang Zheng, Liu Guichang, Zhao Zhongfu. Charge storage mechanism of copper hexacyanoferrate nanocubes for supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(5): 1213-1216. doi: 10.1016/j.cclet.2019.07.022 shu

Charge storage mechanism of copper hexacyanoferrate nanocubes for supercapacitors

Song Zhaoxia ^a ,
Liu Wei ^b,*, ,
Wei Xiaofei ^a ,
Zhou Quan ^a ,
Liu Hongda ^b ,
Zhang Zheng ^b ,
Liu Guichang ^b ,
Zhao Zhongfu ^b,*,

a.
Department of Chemical Engineering, College of Life Science, Dalian Minzu University, Dalian 116600, China
b.
School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

liuwei08@dlut.edu.cn

zfzhao@dlut.edu.cn

Received Date: 12 June 2019
Revised Date: 6 July 2019
Accepted Date: 9 July 2019
Available Online: 9 July 2019

Figures(3)

The widely accepted theory concerning the electrochemical energy storage mechanism of copper hexacyanoferrate (CuHCF) for supercapacitors is that CuHCF stores charge by the reversible redox processes of Fe³⁺/Fe²⁺ couple and Cu cations are electrochemically inactive. In this work, CuHCF nanocubes (CuHCF-NC) were synthesized in the presence of potassium citrate and its electrochemical properties were tentatively studied in 1 mol/L Na₂SO₄ aqueous electrolyte. Good supercapacitive performance was exhibited. The combined analyses of cyclic voltammogram (CV) and X-ray photoelectron spectroscopy (XPS) disclosed that the CuHCF nanocubes underwent the redox reactions of Fe³⁺/Fe²⁺ and Cu²⁺/Cu⁺ couples to store charges. The Cu²⁺/Cu⁺ redox couple was activated due to the strong coordination interaction between the carboxylate groups of citrate ions and surface Cu cations.
- Copper hexacyanoferrate,
- Supercapacitor,
- Electrode material,
- Charge storage mechanism,
- Redox couple
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